Sharif Digital Repository

In this dissertation, some computational operators are designed and simulated using plasmonic metastructures. Superiority of graphene over its plasmonics counterparts in terms of exceptional features such as tunability, thinness, and also highly confined graphene plasmons intrigued us to employ graphene-based meta-transmit-array for designing efficient devices in the infrared regime. First off, we propose a transmit-array of metasurfaces containing subwavelength graphene ribbons and evaluate the structure capability in full controlling over amplitude and phase of the impinging wave locally. By considering optics nanocircuits concept, an equivalent admittance is assigned to each metasurface... 

Existing face forgery detection methods mainly focus on certain features of images, such as features related to image noise, local textures or frequency statistics of images for forgery detection. This makes the extracted representations and the final decision depend on the data in the database and makes it difficult to detect forgery with unknown manipulation methods. Solving this challenge, which is called the generalization challenge in artificial intelligence literature, has become the main goal of researchers in this field. In this thesis, the focus is on extracting effective features for success in forgery detection and preventing the performance of the forgery detection network from... 

One of the most important problems in machine learning is investigating the performance of the learning algorithms, and especially deep neural networks, on adversarial examples, which are generated by imperceptibly perturbing input images, so that cause the model make a wrong prediction. Not only this line of research is important for making deep neural networks dependable, but also can help with understanding the fundamental limitations of deep neural networks, and the nature of their operation, which can in turn provide researchers with valuable insights into artificial intelligence. In this research work, we have tried to approach the topic with a mainly theoretical mindset. The method we... 

We are interested in the relation between entanglement and quantum phase transitions. We have presented a formulation on how the entanglement of a very large the system is related to the entanglement of a small part of system. The renormalization of entanglement is an indicator of the critical behavior of the models. The framework of our approach is introduced about the Ising model. In particular, we show that derivative of entanglement developes a minimum close to the critical point. We further clarify that this minimum point approaches to the exact critical point of the system as the system becomes thermodynamic. This phenomenon is governed by an exponent that is closely related to the... 

In this study, pitting corrosion of 304, 316 and 316L stainless steels in 3.5% NaCl solution at different temperatures (25, 40, and 70°C), were studied by electrochemical methods such as Cyclic Potentiodynamic Polarization, Electrochemical Impedance Spectroscopy and Immersion tests. Also, the effects of different concentrations of polyethyleneimine with two molecular weights (2000 and 60000 g/mol) on pitting corrosion of these steels were investigated. Finally, the adsorption behavior of inhibitors on surface of alloys was investigated by Atomic Force Microscopy (AFM) and Attenuated Total Reflectance Fourier transform spectroscopy (ATR-FTIR). It was found that both inhibitors prevent... 

The anisotropic Heisenberg ferrimagnet which is composed of two different kind of spins is studied. We have found the exact (factorized) ground state of a general class of ferrimagnets in the presence of a magnetic field which includes the frustrated, anisotropic and long range interactions for arbitrary dimensional space. The factorized ground state is a product of single particle kets on a bipartite lattice composed of two different spins (σ, ρ) which is characterized by two angles, a bi-angle state. The spin waves analysis around the exact ground state show two branch of excitations which is the origin of two dynamics of the model. The signature of these dynamics is addressed as a peak... 

In this thesis, we consider the Kondo-necklace model to investigate the quantum phase transition between the Kondo-singlet and antiferromagnetic phases. There is no exact solution for this model. We would like to study the quantum critical behaviour of this model on one, two and three dimensional spaces in addition to ladder geometry. In this respect, we looked for a proper method which can give us some information for our model on any spaces mentioned above. Therefore, we implemented the perturbation continuous unitary transformation (PCUT) for the Kondo-necklace model. By using this method, we can not only calculate the ground state energy for 1, 2, 3 dimension and n-leg ladder... 

Entanglement spectrum is the set of eigenvalues of reduced density matrix for a definite state. It contains more information than the entanglement entropy. This spectrum can show entanglement measure, quantum phase transition and topological order in a system. In recent years, the entanglement spectrum for several models has been studied. The entanglement spectrum shows a correspondence to the energy spectrum within some specific regions, which are related to the edge state of the system; It has been verified for the Heisenberg ladder [1] and fractional quantum Hall effect [3]. Moreover, the topological order can be seen in the entanglement spectrum. There exists an acceptable adaption... 

Metallic implants are useful in dental and orthopedic applications. Bio coating is necessary to improve bio-compatibility and bio-activation of metallic implants. For this goal, HA is the most important material. In this research, the goal is to improve bio-compatibility of St. St 316 by coating HA, HA-ZrO2, HA-TiO2, HA-ZrO2-TiO2 using combination of electrodeposition and electrophoretic methods. To form HA, calcium and phosphor salt solution was used then ZrO2- TiO2 nanoparticles was added to solution. In order to analyst the coatings different tests were done. Thickness analysis, XRD, FT-IR, FE-SEM and EDS, bonding Strength, Polarization test, bio-compatibility and surface roughness... 

In this study, linear polarization resistance (LPR) of cathodic pulse electrodeposited graphene- Nickel-Molybdenum coating is optimized by design of experiments approach (central composite design). Applied current density (i), cathodic pulse durations (Ton) and total electrodeposition time (Ttotal) are selected as the substantial factors. The best prediction model proposes a definitive linear relation without any significant interaction of the LPR by analysis of variance. The best value of LPR is achieved equal to 1406KΩ.cm2, obtaining at i of 137.5 A/cm2, Ton of 45.5 ms and Ttotal equal to 315 s. Polarization test is carried out to determine corrosion behavior of the coating. It shows... 

With the increase in the average age of the world's population, osteoporosis is a worldwide incidence. This disease, along with natural disasters, are important factors in the occurrence of fractures in various bones of the body. One of the methods for solving this problem and replacing with broken body bones is the use of metal implants with hydroxyapatite-based coatings. One of the common problems with using implants in the body is the infection in the adjacent parts of the implant. To overcome this problem, several studies have been carried out on the use of hydroxyapatite coatings with metal ions or antibacterial oxide compounds. In the present study, the influence of factors such as the... 

The aim of this thesis is to review the spin systems with cluster-type inter-actions. We restrict our attention to one dimentional and exactly solvable models. By "exactly solvable models",we mean the systems which can be mapped to free fermionic systems by Jordan-Wigner transformation.In 2nd chapter we introduce one of the simplest spin systems with cluster-type intraction, the cluster Ising model, and completely derive its statis-tics[10].In chapter 3, we present a classification of topologic phases which can oc-cur in free fermionic gapped systems. This classification is based on sym-metries. Also we'll see that with the help of topological invariants, one can diagnose different... 

Smart coatings which prevent corrosion by several mechanisms recently have been carefully planned. One of these mechanisms is the use of ion exchangers like Layered Double Hydroxide (LDH) in the coating network. In this study, the LDH containing a kind of green inhibitor (sodium molybdate) was synthesized and utilized in a Poly-Vinyl Alcohol (PVA) base coating applied on the aluminium (5054 series) surface. After evaluating the LDH performance, the inhibitor release from the LDH crystals was examined by changing significant parameters like MII/MIII (the molar ratio of divalent ions into trivalent ions), pH, aging time and temperature. Considering the LDH morphology or the thickness of the... 

316L stainless steel is used in implants under load in orthopedics and dentistry due to its high strength and corrosion resistance. Therefore, to improve their biocompatibility properties, bioceramic coatings with more suitable biocompatibility properties are used. Therefore, in the present study, to improve the biocompatibility and corrosion properties on 316 L metal implants, HAp / TiO2 / Al2O3 nanocomposite coating was created using the cost-effective sol-gel method. Titanium + alumina by weight percentage in these coatings were 20, 30, and 40% by weight. In this study, FTIR, XRD, DSC / TG, FE-SEM EDS, DLS tests were performed to investigate the chemical bases in nanocomposites,... 

In this research Feasibility of application of oxide compounds of bismuth, molybdenum and tin as biocide was studied. So some epoxy paints with different ratio of these compounds were formulated. Afterward some tests were performed to assessment paints properties such as leaching rate, antifouling activity, adhesion, corrosion resistance and impact resistance. Results of leaching rate test showed that increase in the ratio of bismuth oxide from 10% to 60%, led to increase leaching rate from 0.029mg.day-1.cm-2 to 0.126mg.day-1.cm-2. beside that Microscopic results showed proved that the ratio of bismuth oxide in the cured coating is 25% of the paint formulate. In similar ratio of biocides,... 

In this thesis, we study the effect of quantum fluctuations by means of a transverse magnetic field () on the ground state of frustrated antiferromagnetic Ising models on the checkerboard and square lattices with nearest neigbor couplings J1 and next-to-nearest neighbor couplings J2. At zero field, such models have exponentially large degenerate classical ground states at J2 ... J1 for the checkerboard lattice and at J2 = 0:5J1 for the square lattice. Quantum fluctuations can have a major role to lift the degeneracies toward a unique quantum ground states. We consider two types of quantum fluctuations, harmonic ones by using linear spin wave theory (LSWT) with single-spin flip excitations... 

The aim of this thesis was creating Titania/RGO coating with electrophoretic method to evaluate the corrosion resistance of stainless steel 316. At first Graphene Oxide were synthesized with modified Hammers method and their physical, chemical and morphological properties have been investigated using XRD, FTIR, EDX, TGA, UV-Vis and Raman analysis. then Graphene Oxide was added to the bath of titanium and was deposited on 316 stainless steel substrates. Moreover, corrosion protection of coating has been examined using Poarization test and Electrochemical Impedance Spectrometry. The effect of deposition parameters on corrosion properties of composite coatings were examined. The key variables... 

Thermalizing quantum systems are conventionally described by statistical mechanics at equilibrium. In contrast, the interplay of disorder and interactions leads to manybody localization (MBL) which avoids thermalization in a closed quantum system.This phenomenon is the only known generic mechanism in which the “eigenstate thermalization hypothesis” is violated. In this vein, localization can protect quantum order even in finite temperature and create emergent nonergodic phases (e.g., time crystal), having no equilibrium counterpart. Yet in the conventional wisdom, the presence of disorder along with the excellent isolation from thermal bath are both necessary for the appearance of the MBL.In... 

Strongly correlated materials are kind of materials in which novel electric and magnetic properties will appear as a result of strong correlations among their electrons like “heavy fermion materials”. Kondo lattice model is a model to describe heavy fermion materials. If we are merely interested in the magnetic properties of heavy fermions we can replace the Kondo lattice Model with the simpler model called the Kondo-necklace model which consists of the interactions only among the spins of the itinerant (conduction) and localized electrons (magnetic impurities) and also the interactions between the spins of the itinerant electrons. In this thesis we investigate the properties of the one...