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Toward a comprehensive microextraction/determination unit: A chip silicon rubber polyaniline-based system and its direct coupling with gas chromatography and mass spectrometry
, Article Journal of Separation Science ; Volume 39, Issue 21 , 2016 , Pages 4227-4233 ; 16159306 (ISSN) ; Allahdadlalouni, M ; Zamani, C ; Sharif University of Technology
Wiley-VCH Verlag
2016
Abstract
An inexpensive silicon rubber-based chip was constructed by fabricating a triangle-shaped microcanal with a 135 μm width and 234 μm depth by laser ablation technique. The fabricated groove was sealed by a thin glass cover while two pieces of stainless-steel tubing were connected to each side of the canal. Then, a thin polyaniline film was synthesized on the walls of the canal by chemical oxidation using a syringe pump to deliver the relevant reagents. The microfluidic system was eventually connected to a gas chromatography-mass spectrometry. To evaluate the capability of the constructed microfluidic system, it was implemented to the analysis of submilliliter volumes of environmental samples...
A magnetic multifunctional dendrimeric coating on a steel fiber for solid phase microextraction of chlorophenols
, Article Microchimica Acta ; Volume 184, Issue 7 , 2017 , Pages 2201-2209 ; 00263672 (ISSN) ; Manouchehri, M ; Allahdadlalouni, M ; Sharif University of Technology
Springer-Verlag Wien
2017
Abstract
A polyamidoamine dendrimer was synthesized, placed on magnetite nanoparticles, and the resulting material was then employed as a fiber coating for use in solid phase microextraction of chlorophenols. The polyamidoamine was expected to be an efficient extracting medium due to the presence of multipolar groups and its inner porosity. A thin stainless steel wire was coated with the dendritic polyamidoamine polymer via electrolysis and chemical reactions. The coated fiber was investigated in terms of headspace solid phase microextraction of chlorophenols from aqueous samples followed by GC-MS quantitation. The calibration plots are linear in the 2–1000 ng⋅L−1 chlorophenol concentration ranges....
Reduced graphene oxide–melamine formaldehyde as a highly efficient platform for needle trap microextraction of volatile organic compounds
, Article Microchemical Journal ; Volume 157 , 2020 ; Allahdadlalouni, M ; Baktash, M. Y ; Bagheri, H ; Sharif University of Technology
Elsevier Inc
2020
Abstract
A superhydrophobic extractive phase was prepared and packed in a needle trap microextraction device for extraction of volatile organic compounds, followed by their determination by gas chromatography. The superhydrophobic phase was prepared by surface modification of melamine formaldehyde (MF) sponge embedded by reduced graphene oxide (rGO). The overall properties of the modified MF along with its high sorption capacity and low cost fabrication were indicative of its feasibility to be highly suitable for extraction of organic pollutants. The determined water contact angle (>150o) from the surface of melamine formaldehyde–reduced graphene oxide (MF–rGO) revealed its high affinity toward...