Sharif Digital Repository

Treatment of wastewater containing carbohydrates by Pichia saitoi growing on beet molasses was investigated in a well-mixed continuous tank as an alternative to bulking control. The yeast strain that used in this work was isolated from non-alcoholic beverage industrial wastewater, with a view on TOC removal compared with other strains in previous study.In this research the isolated yeast showed high COD and TOC removal at three hydraulic retention times, HRT= 48, 24 and 18 hours.Maximum COD and TOC reductions were obtained at HRT=48 hours, which were 96% and 88%, respectively.The influent COD and TOC were 2500 and 148 mg/1, respectively.The pH maintained for synthetic wastewater was about... 

Molybdenum complexes bearing a salicylidene 2-picoloyl hydrazone ligand have been synthesized and characterized. The salicylidene 2-picoloyl hydrazone ligand (H2sal-phz) was prepared by reaction of picoloyl hydrazine with salicylaldehyde. Reaction of H2sal-phz with MoO2(acac) 2 generates the dioxo molybdenum complex MoO2(sal-phz) (CH3OH). Treatment of MoO3 in the presence of H 2O2 with H2sal-phz produces the oxo-peroxo molybdenum(VI) complex MoO(O2)(sal-phz)(CH3OH). The new compounds were characterized by 1H NMR and IR spectroscopies, and elemental analysis. The complexes were also characterized by single crystal X-ray diffraction crystallography. The complexes were evaluated for epoxidation... 

Four metal dithiocarbamate complexes (Zn, Ni, Hg and Sn) based on an amine containing pyridyl and nitrile groups, 3-((pyridin-2-yl)methylamino)propanenitrile, were prepared and characterized by their elemental analysis, spectroscopic data (such as IR, 1H and 13C NMR), TGA analysis and X-ray crystallography of the Ni(II) complex. The presence of a band in the 1000 cm-1 region in the IR spectra, without any splitting, confirms the symmetrical bidentate bonding mode of the dithiocarbamate ligand. Also, the short thioureide C=N distance in the X-ray analysis of the Ni complex confirms the delocalization of π electrons over the S2CN moiety and strong double bond character between the carbon and... 

An efficient route for the synthesis of gem-bis(dithiocarbamate) derivatives is developed using dithiocarbamic acid salts generated from primary aliphatic amines and CS2. The method offers high yields, employs mild reaction conditions, and demonstrates excellent functional group compatibility. The structures of the products were confirmed spectroscopically and by X-ray analysis  

The synthesis of a Mo(VI) Schiff base complex, cis-[MoO2{(4,6-bis(tert-butyl)-2-{(benzyl)iminomethyl}phenolate)2}], cis-[MoO2(L)2] where L = 4,6-bis(tert-butyl)-2-{(benzyl)iminomethyl}phenol, derived from benzylamine and 3,5-di-tert-butylsalycilaldehyde is reported. Full characterization of this complex was accomplished with elemental analyses, spectroscopic studies (NMR, IR and electronic) and X-ray structure analysis. This complex was tested as a catalyst for the homogeneous oxidation of olefins. The Mo(VI) complex is catalytically active for the epoxidation of aliphatic substrates at 80 °C, yielding the epoxide as the sole product in yields up to 100% and turnover numbers up to 5000.... 

A mononuclear mixed ligand complex of iron, [FeIII(N-OPh-sal)(acac)EtOH], where Hacac and N-HOPh-Hsal denote acetylacetone and N-hydroxyphenyl-salicylideneamine, respectively, has been synthesized and characterized by elemental analysis, spectral studies and X-ray crystallography. The catalytic system containing this complex and urea hydrogen peroxide as oxidizing agent was used to selectively oxidize a range of sulfides to the corresponding sulfoxides in good yields under mild conditions. The electronic spectra of the catalytic system were applied to explore reactivity and stability of the catalyst during sulfide oxidation reactions and to examine the nature of active species, as well. ©... 

This work is concerned with the monitoring of ultrasound effects on inhibition, as well as the reversible kinetics modeling of asphaltene flocculation in toluene-n-alkane systems, which has been rarely reported in the literature. A crude oil sample was exposed to ultrasound waves, and then the colloidal structural evolutions of flocculated asphaltene particles induced by addition of n-alkane were studied, using a confocal microscopy. Observations confirmed that radiation of ultrasound can change the irreversibility of asphaltene flocculation in crude oil. To interpret the kinetics of asphaltene flock aggregation, the Smoluchowski model was used, and the time dependent size distribution of... 

The reaction of dithiocarbamic acid salts with trimethyl orthoformate in the presence of BF3·OEt2 was investigated to give 4-(N,N-dialkyldithiocarbamato)-2-dialkyliminio-1,3-dithietane tetrafluoroborates in good yields. Additionally, a one-pot procedure for the synthesis of 2-iminium-1,3-dithiolanes from the BF3·OEt2 catalyzed reaction of dithiocarbamic acid salts with styrene epoxide is described  

This paper is to do a brief research on the buckling behavior of composite triangular plates with various edge boundary conditions and in-plane loads. It may be regarded as a right and simple numerical method for the analysis of composite triangular thin plate using the natural Area coordinates. Previous studies on the solution of triangular plates with different boundary conditions were mostly based on the Rayleigh-Ritz principle which is performed in the Cartesian coordinate. In this method, the energy functional of a general triangular plate is derived and the Rayleigh-Ritz method is utilized to derive the governing eigenvalue equation for the buckling problem. The geometry is presented... 

A new high step-up boost converter with an active clamp circuit to eliminate voltage spike caused by leakage inductor is introduced in this paper. The introduced power converter has a high voltage gain for variable input voltage from 48V to 80V. Since both main and auxiliary switches turn on with zero voltage switching (ZVS) and all the diodes turn off under zero current switching (ZCS) condition, switching losses and EMI noises are strongly degraded. Therefore, the converter's efficiency is improved significantly. Simulation results show a 96.4% peak efficiency and 95.4% average efficiency. The proposed topology is suitable for low-input-voltage and low-output power applications such as... 

In this study, a new LLC resonant converter for high-voltage high-power applications is introduced. The introduced power converter is a two-phase interleaved full-bridge based that uses a transformer with secondary and tertiary windings to obtain higher output voltage. Zero voltage switching (ZVS) at MOSFETs turn on and zero current switching (ZCS) for all the output diodes at turn off are achieved for a wide range of input voltage (100 V-200 V) and output power (200 W-1500 W) variations. Simulation results show a 95% peak efficiency. © 2021 IEEE  

Vehicular Ad-hoc Networks (VANETs) have emerged as part of Intelligent Transportation Systems (ITS), offering the potential to enhance passenger and driver safety, as well as driving conditions. However, VANETs face significant security challenges and various attacks due to their wireless nature and operation in free space. Mutual authentication between vehicles and RSUs is one of the most, if not the most, critical security requirements in VANETs. In this process, maintaining resource authenticity, data authenticity and preserving users’ privacy, are key concerns. This paper proposes a pseudonym-based authentication scheme for VANETs, built upon existing approaches. The proposed scheme not... 

Airships are inherently sensitive to random atmospheric disturbances that could potentially make their data gathering and observation missions a formidable task. In this context robust closed loop feedback controllers are important. The present study is therefore focused on optimal feedback controller design of an indigenous domestically designed airship (DA) for added robustness against atmospheric disturbances. While the general airship six degrees of freedom (6DoF) governing equations of motion are mathematically nonlinear, one often needs to resort to local linearization methods to benefit from proven linear closed loop controller (CLC) design approaches. In this sense an optimal linear... 

Airships are inherently sensitive to random atmospheric disturbances that could potentially make their data gathering and observation missions a formidable task. In this context robust closed loop feedback controllers are important. The present study is therefore focused on optimal feedback controller design of an indigenous domestically designed airship (DA) for added robustness against atmospheric disturbances. While the general airship six degrees of freedom (6DoF) governing equations of motion are mathematically nonlinear, one often needs to resort to local linearization methods to benefit from proven linear closed loop controller (CLC) design approaches. In this sense an optimal linear... 

Abdominal aortic aneurysm (AAA) is an irreversible bulge in the artery with higher prevalence among the elderlies. Increase of the aneurysm diameter by time is a fatal phenomenon which will lead to its sidewall rupture. Invasive surgical treatments are vital in preventing from AAA development. These approaches however have considerable side effects. Targeted drug delivery using microbubbles (MBs) has been recently employed to suppress the AAA growth. The present study is aimed to investigate the surface adhesion of different types of drug-containing MBs to the inner wall of AAA through ligand-receptor binding, using fluid-structure interaction (FSI) simulation by using a patient CT-scan... 

Coronary artery disease (CAD) is the prevalent reason of mortality all around the world. Targeting CAD, specifically atherosclerosis, with controlled delivery of micro and nanoparticles, as drug carriers, is a very proficient approach. In this work, a patient-specific and realistic model of an atherosclerotic plaque in the left anterior descending (LAD) artery was created by image-processing of CT-scan images and implementing a finite-element mesh. Next, a fluid-solid interaction simulation considering the physiological boundary conditions was conducted. By considering the simulated force fields and particle-particle interactions, the correlation between injected particles at each cardiac... 

Targeted drug delivery using nanocarriers (NCs) is one of the novel techniques that has recently been used to improve drug delivery to the Abdominal aortic aneurysm (AAA) disease. The purpose of this study is to evaluate the surface density of NCs (SDNC) adhered via ligand-receptor binding to the inner wall of AAA. For this purpose, fluid–structure interaction (FSI) analysis was first performed for the patient-specific and ideal AAA models. Then, by injecting NCs into the aortic artery, the values of SDNC adhered to and interacted with AAA wall were obtained. Two types of NCs, liposomes, and solid particles in four different diameters, were used to investigate the effect of the diameter and...