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Modeling of CO2-brine interfacial tension: Application to enhanced oil recovery
, Article Petroleum Science and Technology ; Volume 35, Issue 23 , 2017 , Pages 2179-2186 ; 10916466 (ISSN) ; Abbasi, P ; Baghban, A ; Zargar, G ; Abbasi, P ; Sharif University of Technology
2017
Abstract
Development of reliable and accurate models to estimate carbon dioxide–brine interfacial tension (IFT) is necessary, since its experimental measurement is time-consuming and requires expensive experimental apparatus as well as complicated interpretation procedure. In the current study, feed forward artificial neural network is used for estimation of CO2–brine IFT based on data from published literature which consists of a number of carbon dioxide–brine interfacial tension data covering broad ranges of temperature, total salinity, mole fractions of impure components and pressure. Trial-and-error method is utilized to optimize the artificial neural network topology in order to enhance its...
Effect of Major Principal Stress Direction Rotation on Cyclic Behavior of Dense Sand Using Dynamic Hollow Cylinder Aparratus
, M.Sc. Thesis Sharif University of Technology ; Jafarzadeh, Fardin (Supervisor)
Abstract
In the past years a lot of research has been done on effects of different parameters on dynamic behavior of soils. According to these studies, principal stress direction rotation and intermediate principal stress coefficient have a major effect on monotonic behavior of soils, but more studies needed for observingtheir effect on dynamic behavior of soils.
In recent study undrained isotropic consolidated specimens of dense Babolsar sand subjected to α changes using dynamic hollow cylinder apparatus and the inner and outer cell pressure kept constant so that b was relative to α changes.
Fisrt series of testswere done to find an appropriate value for induced cyclic deviator stress. The...
In recent study undrained isotropic consolidated specimens of dense Babolsar sand subjected to α changes using dynamic hollow cylinder apparatus and the inner and outer cell pressure kept constant so that b was relative to α changes.
Fisrt series of testswere done to find an appropriate value for induced cyclic deviator stress. The...
Enhancing the Stability of Nanoparticles Added to a Diesel-biodiesel Blend with the Aim of Improving the Properties of the Blend
, M.Sc. Thesis Sharif University of Technology ; Fotovat, Farzam (Supervisor)
Abstract
The gradual depletion of the resources of fossil fuels, as well as the instability of their price in addition to the necessity of mitigation of hazardous air pollutants, are the chief reasons to increase the use of renewable sources. Biodiesel, as one of the best alternatives, can mitigate the emission of air pollutants resulting from fuel combustion. However, using raw biodiesel is not economically viable due to its lower quality in comparison with diesel. In this study, the role of nanoparticles in the improvement of biodiesel characteristics has been investigated. Firstly, biodiesel was produced from waste cooking oil (WCO) using the transesterification reaction, and then ceria and...
Investigating the effect of several auxiliary carbon sources in treatment of petroleum deposits by the bacterial strain BBRC9012
, Article CHISA 2006 - 17th International Congress of Chemical and Process Engineering, Prague, 27 August 2006 through 31 August 2006 ; 2006 ; 8086059456 (ISBN); 9788086059457 (ISBN) ; Roostaazad, R ; Yaghmaei, S ; Sharif University of Technology
2006
Abstract
Effect of several auxiliary carbon sources such as crude oil, different precultures, and quality of adding crude oil in treatment of petroleum wax deposits by an isolated bacterial strain, BBRC9012, was investigated. First and second experiments which compered effect of molasses, glucose and crude oil, indicated that glucose and molasses causes more microbial growth, biosurfactant production and bioemolsification than crude oil. Both optometry and Surface tension measurements showed that using molasses-BHB preculture for wax treatment is not suitable and when crude oil is used as auxiliary carbon source a one day lag phase is unavoidable. It was also shown that when crude oil is added to...
Metabolomics diagnostic approach to mustard airway diseases: A preliminary study
, Article Iranian Journal of Basic Medical Sciences ; Volume 21, Issue 1 , 2018 , Pages 59-69 ; 20083866 (ISSN) ; Aliannejad, R ; Oskouie, A. A ; Tavirani, M. R ; Kalantari, S ; Naseri, M. T ; Baghban, A. A ; Parastar, H ; Aliakbarzadeh, G ; Sharif University of Technology
Mashhad University of Medical Sciences
2018
Abstract
Objective(s): This study aims to evaluate combined proton nuclear magnetic resonance (1H NMR) spectroscopy and gas chromatography-mass spectrometry (GC-MS) metabolic profiling approaches, for discriminating between mustard airway diseases (MADs) and healthy controls and for providing biochemical information on this disease. Materials and Methods: In the present study, analysis of serum samples collected from 17 MAD subjects and 12 healthy controls was performed using NMR. Of these subjects, 14 (8 patients and 6 controls) were analyzed by GC-MS. Then, their spectral profiles were subjected to principal component analysis (PCA) and orthogonal partial least squares regression discriminant...
ANFIS modeling of rhamnolipid breakthrough curves on activated carbon
, Article Chemical Engineering Research and Design ; Volume 126 , 2017 , Pages 67-75 ; 02638762 (ISSN) ; Sasanipour, J ; Haratipour, P ; Alizad, M ; Vafaee Ayouri, M ; Sharif University of Technology
Institution of Chemical Engineers
2017
Abstract
Owning to interesting properties of biosurfactants such as biodegradability and lower toxicity, they have broad application in the food industry, healthy products, and bioremediation as well as for oil recovery. The present study was aimed to develop a GA-ANFIS model for predicting the breakthrough curves for rhamnolipid adsorption over activated carbon. To that end, a set of 296 adsorption data points were utilized to train the proposed FIS structure. Different graphical and statistical methods were also used to evaluate the model's accuracy and reliability. Results were then compared to those of the previously reported Artificial Neural Network (ANN) and Group Method Data Handling (GMDH)...
Synthesis and Application of Preformed Viscoelastic Hydrogels in Enhanced Oil Recovery
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor)
Abstract
Preformed particle gels (PPGs) due to its advatantage over commonly used in situ gels has been successfully applied for controlling excess water production in mature oil reservoirs. Field results of using PPGs in oil fields shows that commonly used PPGs are highly sensitive to hard reservoir conditions such as high temperature and salinity and can not effectively block fractures and high permeability layers.Objects of this study are synthesis and evaluating performance of this novel polymer based hydrogel in oil reservoirs with high temperature and salinity. Central composite design ( which is a experiment design approach) was used for synthesizing thirteen gel samples and optimal sample was...
Design and Manufacture of Polymeric Nanocomposite in Order to Control the Production and Migration of Sand in Reservoirs
, Ph.D. Dissertation Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor)
Abstract
Sand production from oil reservoirs leads to various problems, such as well productivity reduction, operating equipment corrosion, and increased production costs. Therefore, controlling sand production in unconsolidated reservoirs is crucial for operating companies. Chemical injection into the formation in order to strengthen and reduce sand production is one of the most important methods of sand control. In this study, a hydrogel nanocomposite was designed and its effectiveness in sand control was investigated. Various tests were carried out to define and assess its efficacy, as follows: Morphological tests demonstrated the creation of a dense, homogeneous, and porous structure. Structural...
A micromodel investigation on the flooding of glycolipid biosurfactants for enhanced oil recovery
, Article Geoenergy Science and Engineering ; Volume 230 , 2023 ; 29498910 (ISSN) ; Saghandali, F ; Baghban Salehi, M ; Mokhtarani, B ; Taghikhani, V ; Saviz, S ; Sharif University of Technology
Elsevier B.V
2023
Abstract
Biosurfactants can enhance oil recovery by decreasing the interfacial tension between water and oil, and altering the rock's wettability. In this study, the effect of two low molecular-weight glycolipid biosurfactants (rhamnolipid and sophorolipid) on enhancing oil recovery was investigated. The biosurfactants were economically produced from waste sunflower oil. The qualitative oil dispersion experiments were used to evaluate the biosurfactants’ ability to separate oil, Surface tension and interfacial tension tests were carried out at various salinity rates. The potential of rhamnolipid and sophorolipid solutions to alter carbonate rock from an oil-wet state to a water-wet state was studied...
Performance Evaluation of Rhamnolipid & Sophorolipid Biosurfactants Capable of Wettability Change and Oil Recovery Increase
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor) ; Mokhtarani, Babak (Co-Supervisor)
Abstract
As fossil fuels are still the world's most important source of energy, as well as the maturity of most of the world's oil reservoirs, there is a need for enhanced oil recovery methods to meet the world's increasing oil demands. MEOR methods are new and promising methods that are still in the research and development stage. One of the MEOR methods is the use of biosurfactants, which increase the oil recovery by two mechanisms: 1) reducing the interfacial tension between water and oil and 2) changing the wettability of the rock. In this study, the performance of two glycolipid biosurfactants, rhamnolipid and sophorolipid, in increasing oil recovery has been investigated. Initially, surface...
Investigation of the Effect of Asphaltene on the Stability of Water-oil Emulsion
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor) ; Masihi, Mohsen (Supervisor)
Abstract
During the production of crude oil from reservoirs, the production of quantities of formation water along with this oil, causes the crude oil does not have the necessary indicators for transportation, refining and ultimately export. The presence of water and salt along with crude oil causes corrosion of refinery and transmission equipment and makes oil unfavorable in terms of economic efficiency (both for domestic use and for export). water and salt produce stable emulsion with oil that can be stable for a long time and can not be easily separated from crude oil. Therefore, separation of water and salt from crude oil is one of the most important issues in the oil industry. Breaking this...
Providing A New Solution to Enhance Oil Recovery (Eor) by Using Properties of Imidazolium Ionic Liquids and Synthesis of Microgels
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Baghban Salehi, Mahsa (Supervisor) ; Mokhtarani, Babak (Co-Supervisor)
Abstract
The methods of Enhanced Oil Recovery (EOR) from reservoirs have been taken into consideration recently due to the decline in oil reserves and the rise in energy demand. Studies and investigations indicate the tremendous potential of chemical approaches based on injecting ionic liquids into the porous media with the goal of improving oil recovery. Additionally, hydrogels and polymers, which are two of the process' primary materials, are thought to be good alternatives. In the current study, a hydrogel based on carboxymethyl cellulose was first created and synthesized. Ionic liquids based on imidazolium and triflate anion were then added, and their effectiveness in enhancing the properties...
Fabrication of Composite Scaffold Composed of Cartilage Extracellular Matrix/Chitosan with High Mechanical Strength for Cartilage Tissue Engineering
, M.Sc. Thesis Sharif University of Technology ; Mashayekhan, Shohreh (Supervisor) ; Baghban Eslami Nejad, Mohammad Reza (Supervisor)
Abstract
Methods that has been used for articular defects are faced with many limitations, so new therapies based on tissue engineering were taken into consideration in recent years. However, tissue engineering also encounters challenges regarding optimal scaffold construction and suitable cell source selection. Mature harvested chondrocytes are limited in number and may lose their chondrogenic potential in several cultures, leading to dedifferentiation. In addition, using stem cells also presents unique challenges associated with them, among which hypertrophic differentiation is the most substantial problem. Choosing the appropriate biomaterial similar to the cartilage structure with sufficient...
Evaluation of the Surface Activity of Novel Ionic Liquids and Their Application in the Enhanced Oil Recovery Process
, M.Sc. Thesis Sharif University of Technology ; Taghikhani, Vahid (Supervisor) ; Mokhtarani, Babak (Supervisor) ; Baghban Salehi, Mahsa (Co-Supervisor)
Abstract
The following dissertation discusses Ionic Liquids (ILs) as an alternative to commercial surfactants for use in the Enhanced Oil Recovery process. Ionic Liquids came to researchers’ attention due to their environmental nature and their tolerance for high temperatures and salinity. In this work, firstly, an extensive literature review is carried out, and then, experiments are designed and performed to evaluate ILs’ surface activity and performance in a lab-scale EOR set-up. The Ionic Liquids used in this work consist of three types of methylimidazolium nitrate, [MIM]+[NO3]-, with three different alkyl chain lengths. This combination, and specifically the effect of nitrate anions on EOR and...
Intelligent semi-active vibration control of eleven degrees of freedom suspension system using magnetorheological dampers
, Article Journal of Mechanical Science and Technology ; Volume 26, Issue 2 , 2012 , Pages 323-334 ; 1738494X (ISSN) ; Sarrafan, A ; Khayyat, A. A. A ; Zabihollah, A ; Sharif University of Technology
2012
Abstract
A novel intelligent semi-active control system for an eleven degrees of freedom passenger car's suspension system using magnetorheological (MR) damper with neuro-fuzzy (NF) control strategy to enhance desired suspension performance is proposed. In comparison with earlier studies, an improvement in problem modeling is made. The proposed method consists of two parts: a fuzzy control strategy to establish an efficient controller to improve ride comfort and road handling (RCH) and an inverse mapping model to estimate the force needed for a semi-active damper. The fuzzy logic rules are extracted based on Sugeno inference engine. The inverse mapping model is based on an artificial neural network...
Performance and exhaust emission characteristics of a spark ignition engine operated with gasoline and CNG blend
, Article Proceedings of the Spring Technical Conference of the ASME Internal Combustion Engine Division ; 2012 , Pages 179-187 ; 15296598 (ISSN) ; 9780791844663 (ISBN) ; Hamidi, A. A ; Mozafari, A. A ; Sharif University of Technology
2012
Abstract
Using CNG as an additive for gasoline is a proper choice due to higher octane number of CNG enriched gasoline with respect to that of gasoline. As a result, it is possible to use gasoline with lower octane number in the engine. This would also mean the increase of compression ratio in SI engines resulting in higher performance and lower gasoline consumption. Over the years, the use of simulation codes to model the thermodynamic cycle of an internal combustion engine have developed tools for more efficient engine designs and fuel combustion. In this study, a thermodynamic cycle simulation of a conventional four-stroke spark-ignition engine has been developed. The model is used to study the...
A comparative study of the performance of a SI engine fuelled by natural gas as alternative fuel by thermodynamic simulation
, Article 2009 ASME Internal Combustion Engine Division Fall Technical Conference, ICEF 2009, Lucerne, 27 September 2009 through 30 September 2009 ; 2009 , Pages 49-57 ; 9780791843635 (ISBN) ; Hamidi, A. A ; Mozafari, A. A ; Sharif University of Technology
American Society of Mechanical Engineers (ASME)
2009
Abstract
With the declining energy resources and increase of pollutant emissions, a great deal of efforts has been focused on the development of alternatives for fossil fuels. One of the promising alternative fuels to gasoline in the internal combustion engine is natural gas [1-5]. The application of natural gas in current internal combustion engines is realistic due to its many benefits. The higher thermal efficiency due to the higher octane value and lower exhaust emissions including CO2 as a result of the lower carbon to hydrogen ratio of the fuel are the two important feature of using CNG as an alternative fuel. It is well known that computer simulation codes are valuable economically as a cost...
Analytical and experimental analyses of nonlinear vibrations in a rotary inverted pendulum
, Article Nonlinear Dynamics ; Volume 107, Issue 3 , 2022 , Pages 1887-1902 ; 0924090X (ISSN) ; Pasharavesh, A ; Khayyat, A. A. A ; Sharif University of Technology
Springer Science and Business Media B.V
2022
Abstract
Gaining insight into possible vibratory responses of dynamical systems around their stable equilibria is an essential step, which must be taken before their design and application. The results of such a study can significantly help prevent instability in closed-loop stabilized systems by avoiding the excitation of the system in the neighborhood of its resonance. This paper investigates nonlinear oscillations of a rotary inverted pendulum (RIP) with a full-state feedback controller. Lagrange’s equations are employed to derive an accurate 2-DoF mathematical model, whose parameter values are extracted by both the measurement and 3D modeling of the real system components. Although the governing...
A suction-controlled ring device to measure the coefficient of lateral soil pressure in unsaturated soils
, Article Geotechnical Testing Journal ; Volume 44, Issue 1 , 2020 ; Garakani, A. A ; Golshani, A ; Mirzaii, A ; Sharif University of Technology
ASTM International
2020
Abstract
A suction-controlled ring device has been developed to continuously measure the coefficient of lateral soil pressure in deformable unsaturated soil samples from the at-rest to the active condition under application of increasing vertical pressure and controlled matric suction. The device incorporates a thin aluminum specimen ring equipped with horizontal strain gages for recording the lateral soil strains. In addition, a sensor recording water volume changes is utilized to continuously monitor the degree of saturation of the soil sample during tests. The matric suction within the soil texture is controlled using the axis translation technique. In order to verify the performance of the ring...
Gum tragacanth gels as a new supporting matrix for immobilization of whole-cell
, Article Iranian Journal of Chemistry and Chemical Engineering ; Volume 24, Issue 4 , 2005 , Pages 1-7 ; 10219986 (ISSN) ; Vaziri, A ; Seifkordi, A. A ; Kheirolomoom, A ; Sharif University of Technology
2005
Abstract
We introduce a new smooth, non-toxic, biocompatible method for cross-linking of gum tragacanth (GT), a polysaccharide of natural origin, in order to serve as a new supporting matrix for immobilization systems. The modified gum is used as a matrix for the catalysis of the conversion of benzyl penicillin to 6-aminopenicillanic acid (6-APA) by means of Escherichia coli ATCC11105 with penicillin G acylase (PGA) activity. The results show that GT beads can not only serve as a proper matrix for immobilization, but show enhanced hydrolysis rate and stability compared to other immobilization systems used for this reaction. This signifies the potential of GT as a biocompatible matrix for...