Sharif Digital Repository

Ni-Co/SiC composite coatings with various contents of SiC particles were electrodeposited in a modified Watt's type of Ni-Co bath containing suspended 20 nm SiC particles. Deposition parameters including current density, bath SiC concentration and magnetic stirring rate were optimized for the highest amount of the SiC codeposition: the current density of 4 A/dm2, 40 g/dm 3 SiC concentration and 480 rpm stirring rate. In order to study the SiC particles codeposition, the Guglielmi's model of codeposition was modified for high volume percentages of the second phase and the modified model was employed to explain the effects of deposition parameters on the kinetics of the particles codeposition.... 

The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the cathodic current density. The composition, surface morphology, roughness, layers growth pattern as well as the phase structure of deposits were extensively studied via SEM, EDS, AFM and XRD analysis. Effects of bath ingredients on the electrodeposition behavior were analyzed through cathodic linear sweep voltammetry. Although the concentration of Zn2+ in bath was 13 times higher than Ni2+, the Zn-Ni deposition potential was much nearer to Ni deposition potential rather than that of Zn. Addition of NaH2PO2 to the Ni deposition bath considerably raised the current... 

The Ni-P/Zn-Ni compositionally modulated multilayer coatings CMMCs were electrodeposited from a single bath by switching the deposition current density. The corrosion resistance of the deposits was studied and compared with that of monolayers of Ni-P and Zn-Ni alloys via Tafel polarization, EIS and salt spray tests. Characterization of corrosion products by means of EDS and XRD revealed more details from the corrosion mechanism of the monolayers and multilayers. The corrosion current density of Ni-P/Zn-Ni CMMCs were around one tenth of Zn-Ni monolayer. The CMMC with incomplete layers performed lower polarization resistance and higher corrosion current density compared to the CMMC with... 

The effects of bath composition and deposition variables on the electrodeposition of Zn–Ni–P alloys were studied in order to develop a single bath for deposition of Ni–P/Zn–Ni compositionally modulated multilayer coatings (CMMCs). The basis for development of the bath was a large increase in the Ni deposition rate compared to that of Zn at low deposition overpotentials combined with the impossibility of codeposition of Zn with P. EDS analysis demonstrated that the deposits obtained from the Zn–Ni–P bath at low overpotentials were practically all Ni–P, while the alloy deposited at high overpotentials was mainly Zn–Ni with around 3.2 wt% P content. © 2017 Elsevier B.V  

Ni-Co/SiC nanocomposite coatings were electrodeposited in a modified watt type of Ni-Co bath containing 20 nm SiC particles to be codeposited. Potentiodynamic polarization tests were conducted to study the effect of the SiC particulates on the electrodeposition of Ni and Co. Scanning electron microscopy was used to assess the morphology of the Ni-Co alloy and Ni-Co/SiC nanocomposite coatings. The distribution of the particulates in the matrix was considered by means of transmission electron microscopy. Applying nanomechanical testing instruments coupled to atomic force microscopy, mechanical properties of the alloy and composite coatings were studied and compared. The presence of 11 vol.%... 

Zn/Ni nanocrystalline multilayer coatings were electrodeposited using single bath method and switching current densities. Effect of deposition current densities (i1 and i2) and number of layers (n) on composition, surface morphology and roughness, microhardness, phase structure and corrosion resistance of Zn/Ni multilayers were studied and compared with that of single layer. Analyzing and optimizing the influences of mentioned parameters on corrosion resistance of multilayers carried out through Response Surface Methodology. The model based on RSM results demonstrated that improvement in corrosion resistance due to increase in “difference of deposition current densities” was more effective... 

γ-Alumina is used to catalyze the Cannizzaro reaction in the absence of any base under microwave irradiation in high yields. In the case of terephthalaldehyde the reaction is carried out with high selectivity  

Enolizable ketones have been reacted in a one-pot method with aromatic aldehydes, acetyl chloride and acetonitrile at room temperature in the presence of SnCl4/SiO2 to furnish the corresponding β-acetamidoketones in improved yields. Acetylation of an aromatic hydroxyl group was observed while using 4-hydroxybenzaldehyde or vanillin and the corresponding β-acetamidoketones were isolated in an excellent yield  

The boundary layer integral method is used to investigate the development of the turbulent swirling flow at the entrance region of a conical nozzle. The governing equations in the spherical coordinate system are simplified with the boundary layer assumptions and integrated through the boundary layer. The resulting sets of differential equations are then solved by the fourth-order Adams predictor-corrector method. The free vortex and uniform velocity profiles are applied for the tangential and axial velocities at the inlet region, respectively. Due to the lack of experimental data for swirling flows in converging nozzles, the developed model is validated against the numerical simulations. The... 

The governing equations of two-dimensional steady density currents are solved numerically using a finite volume method. The v2̄-f turbulence model, based on standard k - s model, is used for the turbulence closure. In this method, all Reynolds stress equations are replaced with both a transport equation for v2̄ and an elliptic relaxation equation for f, a parameter closely related to the pressure strain redistribution term. The Simple-C procedure is used for pressure-velocity coupling. In addition, Boussinesq's approximation is used to obtain the momentum equation. The computed height of the progressive density current is compared to the measured data in the literature, resulting in good... 

The deposition behavior of fine sediment is an important phenomenon, and yet unclear to engineers concerned about reservoir sedimentation. An elliptic relaxation turbulence model (v2̄ - f model) has been used to simulate the motion of turbid density currents laden whit fine solid particles. During the last few years, the v2̄ - f turbulence model has become increasingly popular due to its ability to account for near-wall damping without use of damping functions. In addition, it has been proved that the v2̄ - f model to be superior to other RANS methods in many fluid flows where complex flow features are present. Due to low Reynolds number turbulence of turbidity current,(its critical Reynolds... 

In this paper, an analytical solution for steady creeping motion of viscoelastic drop falling through a viscous Newtonian fluid is presented. The Oldroyd-B model is used as the constitutive equation. The analytical solutions for both interior and exterior flows are obtained using the perturbation method. Deborah number and capillary numbers are considered as the perturbation parameters. The effect of viscoelastic properties on drop shape and motion are studied in detail. The previous empirical studies indicated that unlike the Newtonian creeping drop in which the drop shape is exactly spherical, a dimpled shape appears in viscoelastic drops. It is shown that the results of the present... 

In this paper, creeping motion of a viscoelastic drop falling through a Newtonian fluid is investigated experimentally and analytically. A polymeric solution of 0.08 % xanthan gum in 80:20 glycerol/water and silicon oil is implemented as the viscoelastic drop and the bulk viscous fluids, respectively. The shape and motion of falling drops are visualized using a high speed camera. The perturbation technique is employed for both interior and exterior flows, and Deborah and capillary numbers are considered as perturbation parameters up to second order. The product of Deborah and capillary numbers is also used as a perturbation parameter to apply the boundary condition on the deformation on the... 

In this paper, we consider the problem of minimizing the uplink delays of users in a 5G cellular network. Such cellular network is based on a Cloud Radio Access Network (CRAN) architecture with limited fronthaul capacity, where our goal is to minimize delays of all users through an optimal resource allocation. Earlier works minimize average delay of each user assuming same transmit power for all users. Combining Pareto optimization and Markov Decision Process (MDP), we show that every desired balance in the trade-off among infinite-horizon average-reward delays, is achievable by minimizing a properly weighted sum delays. In addition, we solve the problem in two realistic scenarios;... 

Microwave induced Cannizzaro reaction, which was performed in presence of neutral γ-alumina as a polymeric catalyst, was discussed. Cannizzaro reaction was carried out on alumina surface and other unknown products were also obtained. Solvent extraction method was utilized to isolate mild and selective benzyl alcohol and carboxylic acids  

A well known method to reduce the intrinsic complexity of Multiple Input Multiple Output (MIMO) systems is to choose a subset of available antennas which have stronger links than the others, in order to perform the specified MIMO algorithm. The data resulted from the antenna selection process (at the receiver side) is sent back to the transmitter side via a feedback channel. There seems to be a need to reduce the number of feedack bits, specially when the number of antennas is not small. In this paper, we investigate the problem of reducing the number of feedback bits in antenna selection techniques. We've proposed two methods using vector quantization techniques to perform feedback bit... 

Nowadays, deployment of peer-to-peer video streaming systems over wireless mesh networks has attained raising popularity among large number of users around the world. In this paper, we present an efficient peer-to-peer live video streaming architecture over multi-hop wireless mesh networks. In our proposed architecture, we take the physical topology of network into account and based on a distributed distributed locality-aware neighbor selection algorithm in the overlay construction phase, we generate an efficient mesh-based overlay on top of wireless mesh networks. In locality-aware neighbor selection algorithm, instead of choosing randomly, peers find their best neighbors based on their... 

Standard sparse decomposition (with applications in many different areas including compressive sampling) amounts to finding the minimum ℓ 0-norm solution of an underdetermined system of linear equations. In this decomposition, all atoms are treated 'uniformly' for being included or not in the decomposition. However, one may wish to weigh more or less certain atoms, or, assign higher costs to some other atoms to be included in the decomposition. This can happen for example when there is prior information available on each atom. This motivates generalizing the notion of minimal ℓ 0-norm solution to that of minimal weighted ℓ 0-norm solution. On the other hand, relaxing weighted ℓ 0-norm via...