Sharif Digital Repository

In the present study, the effects of rotary tubes and magnetic-induced nanofluid on heat transfer characteristics of a compact heat exchanger are individually investigated. Two-phase Eulerian model is employed to predict the hydrothermal and entropic characteristics of Fe3O4/water ferrofluid in the heat exchanger. Results indicate that utilizing each rotary tubes and magnetic field method can improve the energy and exergy efficiencies of the compact heat exchanger under specific circumstances by forming different types of secondary flow. It is found that employing each method individually can increase the maximum heat transfer rate by more than 60%. In comparison with methods like passive... 

A considerable amount of energy is lost in the parabolic trough solar collectors due to the poor capability of working fluid in full absorption of the concentrated solar irradiation across the receiver tube. A new hybrid method is recommended here to cover up such deficiency by simultaneously using a rotary absorber tube and magnetic field inducer with nanofluid. Results showed that the combination effects of the receiver rotation and the magnetic field improve the convection mechanism in the absorber and increase both energetic and exergetic performance of the collector. The study reveals that there is an optimal rotational speed in the each magnetic field intensity for different... 

A considerable amount of energy is lost in the parabolic trough solar collectors due to the poor capability of working fluid in full absorption of the concentrated solar irradiation across the receiver tube. A new hybrid method is recommended here to cover up such deficiency by simultaneously using a rotary absorber tube and magnetic field inducer with nanofluid. Results showed that the combination effects of the receiver rotation and the magnetic field improve the convection mechanism in the absorber and increase both energetic and exergetic performance of the collector. The study reveals that there is an optimal rotational speed in the each magnetic field intensity for different... 

This article describes the synthesis and characterization of electronegative oxovanadium(IV) complexes containing tetradentate Schiff-base ligands derived from condensation of 1,3-propanediamine and 1,8-naphthylamine with 5-bromo-3-nitro-2-hydroxybenzaldehyde. New VOL1: [VO(5-Br-3-NO2salnaph)] and VOL2: [VO(5-Br-3-NO2salpn)] complexes were obtained in orange polymeric form with (V=O) stretching bands at 884 and 876 cm-1, respectively. The orange VOL1 and VOL2 complexes turn dark brown and green, respectively, when ground thoroughly in mortars. X-ray powder diffraction patterns of the ground VOL1 complex (VOL1g) scarcely show diffraction peaks. The data suggest that the linear chain polymeric... 

A series of previously reported mononuclear Cu(II) and homodinuclear Cu(II)Cu(II) complexes, as well as, novel mononuclear Cu(II), homodinuclear Cu(II)Cu(II), and heterodinuclear Cu(II)Ni(II) complexes of a phenol-based dinucleating ligand with two different N(amine)2O2 and N(imine)2O2 coordination sites, were synthesized and characterized by elemental analyses, infrared and electronic absorption spectroscopies and conductivity measurements. The electrochemical behavior and catecholase-like activity of the complexes were also studied using cyclic voltammetry and UV-vis spectrophotometry, respectively. Our results show that the dinuclear complexes are more effective catalysts in the oxidation... 

Compact heat exchangers as modern industrial devices are designed to improve heat recovery and saving energy processes in restricted spaces. In the current study, effect of a uniform external magnetic field with Fe3O4/water nanofluid for heat transfer enhancement of a fin-and-tube compact heat exchanger is numerically investigated. The obtained results are verified by the available experimental data to demonstrate accuracy of the present simulation. The results indicated that the local and average heat transfer coefficients increase around the tubes in the presence of an external magnetic field due to the vortex formation behind the tubes as well as the flow pattern alteration in the heat... 

A high-efficient method has been considered for simultaneously improving the hydrothermal and exergetic performance of heat exchangers. Two-phase Eulerian model is employed in a 3-D numerical study to precisely study the hydrothermal and entropic behaviors of Fe3O4/water ferrofluid, under the effect of a magnetic field inducer. The findings reveal that employing the magnetic field can improve the energetic and exergetic performance by generating a swirling flow in the heat exchanger. The pressure drop and entropy generation minimization are also achieved by the induced flow in comparison with other passive techniques due to the lack of any additional obstacle in the flow path. Results show... 

Flat plate solar collectors waste a massive part of the heat accumulated near the contact region, mainly due to poor thermal characteristics of working fluid. The demanding power for pumping the flow through the pipes seems a permanent concern in solar collectors. Also, active methods seem not to be applicable in such systems due to the external energy requirement and cost associated with it. An innovative and simple technique is considered here to eliminate such deficiencies all at once by equipping the flat plate collector with rotary absorber pipes and Fe3O4/water nanofluid. Results indicate that the applied method improves the convection mechanism in each pipe by mixing the accumulated... 

Flat plate solar collectors lose a massive part of heat accumulated near the contact region because of the poor thermal characteristics of the working fluid. A new cost-effective design is numerically studied to cover up such deficiency by equipping the flat plate collector with revolutionary tubes and magnetic field inducer to affect Fe3O4/water working nanofluid in the collector tubes. Results substantiate that each of the applied rotary tubes and magnetic field inducer improves the convection mechanism in the tubes by circulating the flow inside the tubes and saves more of available solar energy. Results reveal that 27.8% and 10.44% of lost energy are restored in the solar collector... 

The preparation and electrochemical performance of the carbon nanotube-paste electrode modified with salophen complexes of cobalt(III) perchlorate, with various substituents on the salophen ligand, as well as their electrocatalytic activity toward the oxidation of N-acetylcysteine (NAC) is investigated. Several Schiff base complexes containing various nucleophilic and electrophilic functional groups were prepared, and their electrochemical characteristics for the electro-oxidation of NAC were evaluated using cyclic and differential pulse voltammetry (CV and DPV). The results revealed, the modified electrodes show an efficient and selective electrocatalytic activity toward the anodic... 

The water-soluble cobalt(II) tetradentate Schiff base complex [Co(II)L](ClO4)2, L: (N,N′-bis{5-[(triphenylphosphonium)-methyl]salicylidine}-o-phenylenediamineperchlorate has been synthesized and characterized. This complex forms charge transfer (CT) complexes with imidazole and 1-methylimidazole. The formation constant, molar absorptivity (ε′), and thermodynamic parameters for charge transfer complexes formation of cobalt(II) Schiff base complexes with imidazole derivatives were determined by using UV-vis spectrophotometric method in aqueous solutions at constant ionic strength (I = 0.2 mol dm-3 KNO3) at pH 6.0 and various temperatures between 292 and 315 K. © 2007 Elsevier B.V. All rights... 

The electrochemical oxidation of sumatriptan on the surface of carbon paste electrode modified with multi-walled carbon nanotube and cobalt methyl-salophen complex is studied by using cyclic voltammetry and polarization studies. The results indicate that the drug is irreversibly oxidized in a one electron oxidation mechanism. It was found that the peak potential shifted negatively with increasing pH, confirms that H + participate in the oxidation process. The electrode is shown to be very effective for the detection of sumatriptan in the presence of other biological reductant compounds. The prepared modified electrode exhibits a very good resolution between the voltammetric peaks of... 

Using multiple antennas at the transmit and receive sides of a passive radar brings both the benefits of MIMO radar and passive radar. However one of the obstacles arisen in such configuration is the receive antennas placement in proper positions so that the radar performance is improved. Here we just consider the case of positioning one receiver among multiple illuminators of opportunity. Indeed it is a start for the solution of optimizing the geometry of the multiple receivers in a passive radar  

SbCl3 supported on montmorillonite K-10 is an efficient catalyst for the ring opening of epoxides with aromatic amines under solvent-free conditions and microwave irradiation to give the corresponding b-amino alcohols in high yields with high regioselectivity  

One of the important obstacles in MIMO (Multiple Input Multiple Output) radars is the issue of designing proper transmit signals. Indeed, the capability of signal design is a significant advantage in MIMO radars, through which, the system can achieve much better performance. Many different aspects of this performance improvement have been considered yet, and the transmit signals have been designed to attain such goal, e.g., getting higher SNR or better detector's performance at the receiver. However, an important tool for evaluating the radar's performance is its ambiguity function. In this paper, we consider the problem of transmit signal design, in order to optimize the ambiguity function... 

Two gains play key roles in recently developed MIMO wireless communication systems: "spatial diversity" gain and "spatial multiplexing" gain. The diversity gain refers to the capability to decrease the error rate of the MIMO channel, while the multiplexing gain implicitly refers to the amount of increase in the capacity of the MIMO channel. It has been shown that there is a fundamental tradeoff between these two types of gains, meaning interplay between increasing reliability (via an increase in the diversity gain) and increasing data rate (via an increase in the multiplexing gain). On the other hand, recently, MIMO radars have attracted much attention for their superior ability to enhance... 

It is a well known fact that using multiple antennas at transmit and receive sides improves the detection performance. However, in such multiple-input multiple-output (MIMO) configuration, proper positioning of transmitters and receivers is a big challenge that can have significant influence on the performance of the overall system. In addition, determining the power of each transmitter under a total power constraint is a problem that should be solved in order to enhance the performance and coverage of such a system. In this paper, we design the Neyman-Pearson detector under the Rayleigh scatter model and use it to introduce a criterion for the antenna placement at both transmit and receive... 

There has been much interest, recently, towards exploiting the Multiple-Input Multiple-Output (MIMO) technique in radar. It is shown that using multiple antennas at transmit and receive sides can improve the performance of the system. However, in order to analyze the system's performance, its ambiguity function, i.e. the ambiguity function of a MIMO radar, is needed to be defined. In this paper, beginning from the information theoretic definitions, we derive such function, specifically for a MIMO radar with widely separated antennas  

By combining the two ideas of MIMO (Multiple Input Multiple Output) and PCL (Passive Coherent Location) in radar, one can achieve the advantages of both recently developed techniques simultaneously. While using multiple antennas at the receive side provides a spatial diversity of the object to be detected, using multiple illuminators of opportunity, most importantly, makes the radar covert to the interceptors. One obstacle in such MIMO configuration is choosing the positions of the receive antennas. In this paper, after analyzing the Neyman-Pearson detector for the DVB-T based PCL, we introduce the probability of missed detection as a criterion to place the receive antenna. Here, we only... 

One of the most important obstacles in passive radar applications is removing the direct signal from the target channel. Otherwise, week echoes from the targets in the target channel would be ignored due to the limited dynamic range of the system. One of the most effective techniques in this field is using adaptive filters. In this paper various adaptive filters are introduced and their performances are shown and compared