Sharif Digital Repository

In the present work, a comprehensive economic, environmental and dynamic behavior analysis with multi-objective optimization for the unit 400 of BandarEmam aromatic plant are provided and the interaction between decision variables in these criterions is discussed. In the first part, potential of seven environmental features of the operational plant are qualified and normalized using life cycle assessement (LCA) for both process waste and utility environmental impacts. By choosing the number of trays and feed stage in three distillation columns as decision variables, optimization is performed to determine the best structural variables values based on the total annual cost and Environmental... 

In this project, the steady laminar flow coupled with heat transfer and chemical reactions corresponding to metal organic chemical vapor deposition (MOCVD) process in an axis-symmetrical rotating disk reactor has been simulated based on computational fluid dynamics (CFD) approach to optimize the parameters affecting the thickness of layer deposition. The simulation results have been validated with the benchmark solutions obtained from the literatures for the corresponding cases study. By genetic algorithms five geometrical structures have been optimized to achieve minimal radial changes in the rate of deposition. Using the optimum values, radial variations deposition rate of 22.7% decreased... 

Synthesis gas to light olefin reactions especially propylene production is one of the important path for clean fuel production in gas conversion processes. The object of this study is to define true kinetic model of process first step (e.g. Synthesis gas to light Olefins). For that, kinetic model for Co/Mn/TiO2 catalyst, which has the best conversion and selectivity for propylene, has been developed. Kinetic reaction parameters were measured by kinetic modeling in (220-300)0C temperature , (1-5)bar pressure , H2/CO=(1:3) and (450-600)hr-1 space velocity .After studying with significant models ,the best fitting can obtained with "KPCO P 1/2H2/(1+aPco+bPH2 1/2)2"equation. Later to... 

Gas hydrate is a nonstoichiometric structure that has been produced from water and gas in appropriate thermal and pressure conditions. There has been a long time that scientists work on predicting hydrate production condition. Predicting the hydrate behavior for pure substances is easier than mixtures; because there are some behaviors of mixtures that we do not know their reasons yet. In this thesis, there has been tried to give a model to describe hydrate reactions to temperature and pressure changes besides predicting the hydrate type and the cage occupancy. Since the hydrate behavior is nonstoichiometric, it is useful to know the cage occupancy to predict the amount of hydrate... 

In the present work, a comprehensive economic, environmental and exergy analysis and multi-objective optimization for gas sweetening plant are provided and the interaction between decision variables in these criterions is discussed. In the first part, potentials of three environmental features (global warming, acid rain, smog formation) of the operational plant are quantified and normalized using life cycle assessment (LCA) for both process waste and utility environmental impacts.Acid rain index is determined as the most important environmental impactindex in this unit. By choosing proper decision variables based on sensitivity analysis, LCA and EA results, optimization is performed to...