Sharif Digital Repository

Nickel oxide (NiOx) is a promising hole transport material in inverted organic-inorganic metal halide perovskite solar cells. However, its low intrinsic conductivity hinders its further improvement in device performance. Here, we employ a trimercapto-s-triazine trisodium salt (TTTS) as a chelating agent of Ni2+ in the NiOx layer to improve its conductivity. Due to the electron-deficient triazine ring, the TTTS complexes with Ni2+ in NiOx via a strong Ni2+-N coordination bond and increases the ratio of Ni3+:Ni2+. The increased Ni3+ concentration adjusts the band structure of NiOx, thus enhancing hole density and mobility, eventually improving the intrinsic conductivity of NiOx. As a result,... 

In this research, polyaniline@Ba0.5Sr0.5Fe12O19@MWCNTs nanocomposite was prepared via co-precipitation and in-situ polymerization methods, respectively. Microstructural, magnetic and electromagnetic wave absorption analysis of the prepared nanocomposite were studied via XRD, FESEM, VSM and VNA. Compared with Ba0.5Sr0.5Fe12O19@MWCNTs, the microwave absorption bandwidth of the coated nanocompoite with polyaniline was significantly enhanced, which increased to approxiamately 4 GHz from 3 GHz. The effective microwave absorption performance of the Ba0.5Sr0.5Fe12O19@MWCNTs nanocomposite was attributed to increase in the interfacial polarization, improvement in impedance matching as well as porous... 

The present research deals with bifurcation and vibration responses of a composite truncated conical shell with embedded single-walled carbon nanotubes (SWCNTs) subjected to an external pressure and axial compression simultaneously. The distribution of reinforcements through the thickness of the shell is assumed to be either uniform or functionally graded. The equations of motion are established using Green-Lagrange type nonlinear kinematics within the framework of Novozhilov nonlinear shell theory. Linear membrane prebuckling analysis is conducted to extract the prebuckling deformations. The stability equations are derived by applying the adjacent equilibrium criterion to the prebuckling... 

The aeroelastic flutter characteristics of a functionally graded carbon nanotube reinforced composite (FG-CNTRC) truncated conical shell under simultaneous actions of a hydrostatic pressure and yawed supersonic airflow are scrutinized. The nonlinearity in geometry of the conical shell is considered in Green–Lagrange sense and the model is derived according to the Novozhilov nonlinear shell theory. The aerodynamic pressure is modeled based on the quasi-steady Krumhaar's modified supersonic piston theory by considering the effect of the panel curvature and flow yaw angle. Parametric studies are conducted to investigate the effects of boundary conditions, semi-vertex angle, distribution and... 

A discussion regarding speech accents will be given while describing a set of statistical signal processing methods for the modeling, analysis, synthesis, and morphing of English language accents. Accent morphing deals with the changing of the accent of a speech to a different accent. Accent itself is a distinctive pattern of pronunciation of speech within a community of people who belong to a national, geographic, or socioeconomic grouping. Then, the signal processing methodology for speech accent processing will be reviewed while the concept of an accent profile has been presented  

We analyse optimal pricing for a retailer that sells two products using a mixed price bundling strategy. We consider substitutable products, where there is a disutility associated with jointly consuming both products. Mixed price bundling implies that customers can freely choose to buy one of the two products, both of them, or neither of them. The retailer determines the price of each product when it is sold separately, the bundle discount if these two products are sold in a bundle, and the inventory levels for each product. We first derive the optimal price and bundle discount when the store traffic is deterministic. Our results show that the mixed bundling strategy is the most beneficial... 

In this study, dynamic modeling of an elbow axially functionally graded (AFG) macro/micro-tube carrying magnetic flow with different cross-sections is considered. Parametric optimization is performed for vibration suppression of such fluid-interaction systems. Implementing computer simulations, passive vibration control procedures, along with the effect of AFG materials and magnetic properties of the fluid as well as precisely manufactured geometry of the system, is investigated. It is assumed that the material characteristics of the system vary in the longitudinal direction based on exponential and power-law distribution profiles. Influence of the downstream inclination angle and... 

In this work, single- and double-layer electromagnetic wave absorbers were prepared by as-prepared MWCNTs/BaTiO3/pitted carbonyl iron composites. MWCNT/BaTiO3 (MW/BTO) was prepared via sol-gel method whereas the carbonyl iron particles (CI) were corroded via pitting corrosion method. The structural, microstructural, magnetic and microwave absorption properties of the composites were evaluated via X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), vibrating sample magnetometer (VSM) and vector network analyzer (VNA) methods. CST studio software was employed to simulate the microwave absorption characteristics of double-layer absorbers. Moreover, the effects of... 

In this study, ternary MWCNTs/CoFe2O4/FeCo nanocomposite coated with conductive PEDOT-polyaniline (PA@MW/F/C) co-polymers were synthesized by microwave-assisted sol-gel followed in-situ polymerization methods. The phases, crystal structures, morphologies, magnetic and electromagnetic features of the as-prepared samples were identified via XRD, SEM, XPS, VSM, and VNA respectively. Absorption characteristics were investigated in the frequency (12–18 GHz) Ku band. XRD, VSM and SEM analysis confirmed the partial reduction process of CoFe2O4 and successfully decorated magneto-dielectric particles with co-polymers. By measuring electromagnetic features of the samples, it was found that coating... 

In this research, carbon nanotube decorated with Cu nanoparticles (CNT/Cu) was synthesized by a new solvothermal process. Solvothermal treatment of CuSO4 and NaOH was completed in ethanol containing ultrasonically dispersed CNTs at 160 °C for 3 h. In the solvothermal process, Cu nanoparticles were heterogeneously deposited on the surface of COOH-functionalized CNTs through the reduction of the Cu+2 ions. Cu nanoparticles with the size of ≈8 nm on CNTs (and some in the solution) and strong bonding between Cu and CNT were obtained by the used process. Microstructural characterization revealed that the solvothermal method is an appropriate method for producing homogenous CNT/Cu nanostructure.... 

In this study, dynamic modeling of an elbow axially functionally graded (AFG) macro/micro-tube carrying magnetic flow with different cross-sections is considered. Parametric optimization is performed for vibration suppression of such fluid-interaction systems. Implementing computer simulations, passive vibration control procedures, along with the effect of AFG materials and magnetic properties of the fluid as well as precisely manufactured geometry of the system, is investigated. It is assumed that the material characteristics of the system vary in the longitudinal direction based on exponential and power-law distribution profiles. Influence of the downstream inclination angle and... 

Porphyrin-POM hybrid materials with excellent NLO properties are supposed to be a worthy entrant for forthcoming telecommunication, optical fibers, optical data storage and optical limiting devices, but due to adverse solubility problems, they are replaced by polymeric materials. Herein, we assessed third order NLO and second hyperpolarizability of porphyrin-polyimide compounds (NH-PI and Zn-PI) synthesized from the reaction of 4,4ʹ-hexafluoroisopropylidene-diphthalic anhydride (6FDA) with C44H32N6 (NH-DATPP) and C44H30N4Zn (Zn-DATPP) porphyrins under ambient conditions. The Z-scan measurement of these compounds revealed reverse saturation absorption as well as self-defocusing performance.... 

Based on MRI diffusion and perfusion, a new criterion for detection and the healing progress of damaged tissue is suggested. The study is based on the ratio of capillary radii in symmetrical damaged and normal tissue neighboring spaces. The Apparent Diffusion Coefficient (ADC) and Cerebral Blood Flow (CBF) were measured in the brain tissues of six male Wistar rats utilizing suggested MRI measurement techniques. The ADC values of damaged and normal regions were (392 ± 34.1) × 10-6 mm2s-1 and (659 ± 40.7) × 10-6 mm2s-1, respectively. The CBF values of damaged and normal regions were 14.5 ± 10.13 ml/min/ 100 g and 125 ± 41.03 ml/min/100 g, respectively. The geometrical parameters of the... 

Understanding the population growth patterns of Spodoptera exigua on alternate host plants can provide valuable information for developing an effective pest management program. In this study, using age-specific lifetable indices, we evaluated the role of alternate crops commonly found in cotton agroecosystem of Pakistan to better understand population dynamics of S. exigua. The longest larval and pupal periods (16.35 and 9.95days, respectively) were observed on spinach, while the shortest periods were recorded on okra (13 days) and cauliflower (8.4 days), respectively. Relatively more female moths (61%) were produced on spinach with low rm (0.095) and λ (1.0997) while highest rm (0.120) and... 

Understanding the population growth patterns of Spodoptera exigua on alternate host plants can provide valuable information for developing an effective pest management program. In this study, using age-specific lifetable indices, we evaluated the role of alternate crops commonly found in cotton agroecosystem of Pakistan to better understand population dynamics of S. exigua. The longest larval and pupal periods (16.35 and 9.95days, respectively) were observed on spinach, while the shortest periods were recorded on okra (13 days) and cauliflower (8.4 days), respectively. Relatively more female moths (61%) were produced on spinach with low rm (0.095) and λ (1.0997) while highest rm (0.120) and... 

A numerical model has been developed for studying the flow and heat transfer characteristics of single phase liquid flow through a microchannel. In this work the heat transfer characteristics of pressure driven and electroosmotic flow through microchannels have been studied. The governing equations are the Poisson-Boltzmann and Navier-Stokes equations which have been solved numerically using the standard Galerkin and the Mixed 4-1 finite element methods, respectively. Finally the energy equation is solved numerically using the Stream-wise Upwind Petrov Galerkin (SUPG) method. Two dimensional Poisson-Boltzmann equation was first solved to find the electric potential field and net charge... 

Cellulose nanowhiskers (CNWs) prepared via TEMPO mediated oxidation are used as biodegradable filler in an epoxy matrix. Since CNWs are hydrophilic and epoxy is hydrophobic, amphiphilic block copolymer surfactants are employed to improve the interactions between the filler and the matrix. The surfactants used are Pluronics, a family of triblock copolymers containing two poly(ethylene oxide) blocks and one poly(propylene oxide) block. In this study, Pluronic L61 and L121 with molecular weight of 2000 and 4400 g/mol and hydrophilic to lipophilic balance of 3 and 1 respectively, are used and their effect on the dispersion of CNWs in epoxy is discussed. The hydrophilic tails of Pluronics... 

Nanostructured Ag@SiO2-Penicillin was synthesized from high-purity Ag0 NPs with a mean particle size of about 10 nm produced by electromagnetic levitation gas condensation (ELGC) method. The silver and penicillin contents of the synthesized nano-antibiotic were about 34 wt% and 2.5 wt% respectively, as determined by ICP-OES and TGA analyses. The antibacterial properties and synergistic effects of nanostructured Ag@SiO2 and Ag@SiO2–Penicillin on killing the Methicillin-susceptible S. aureus (MSSA) and Methicillin-resistant S. aureus (MRSA) bacteria were also examined. The nanoparticles were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Ag@SiO2-Penicillin... 

This work was intended to develop a new cross-linked gelatinized starch-xanthan gum hydrogel system, to characterize the properties of the new material, and to explore its potential applications in controlled drug delivery. Cross-linked starch-xanthan gum polymers were synthesized with varying levels of xanthan gum and sodium trimetaphosphate (STMP). The reaction of starch-xanthan gum polymers with STMP was examined using solid 31P NMR spectroscopy and FTIR. Morphology of the films made from the new polymers was studied by scanning electron microscopy. The swelling properties and the network parameters such as gel mesh size of the films were investigated. The permeation of solutes with... 

Purpose - The purpose of this paper is to develop and compare conventional and neural network-based controllers for gas turbines. Design/methodology/approach - Design of two different controllers is considered. These controllers consist of a NARMA-L2 which is an artificial neural network-based nonlinear autoregressive moving average (NARMA) controller with feedback linearization, and a conventional proportional-integrator-derivative (PID) controller for a low-power aero gas turbine. They are briefly described and their parameters are adjusted and tuned in Simulink-MATLAB environment according to the requirement of the gas turbine system and the control objectives. For this purpose, Simulink...