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    Theoretical Study of Metallochlorophylls of Forth Period Elements in Periodic Table

    , M.Sc. Thesis Sharif University of Technology Faramarzi, Sadegh (Author) ; Parsafar, Gholamabbas (Supervisor)
    Abstract
    In this study, some properties of metallochlorophylls - compounds produced by replacing Mg2+ in tetrapyrrolic ring of chlorophyll b with divalent ions – of the forth period transit elements of the periodic table have been investigated. Using DFT/B3LYP method and DGDZVP basis set, structures of these compounds were optimized and the energy of electronic levels, Gibbs free energy of formation of complex, contribution of atomic orbitals to formation of molecular orbitals and partial charges in these molecules were computed. The results show that some properties of these complexes cannot be justified by the common theories of complexes. Among these properties is the negligible effect of... 

    Simulation of Graphene Nanoribbon based Photodetector

    , M.Sc. Thesis Sharif University of Technology Faramarzi, Vahid (Author) ; Faez, Rahim (Supervisor)
    Abstract
    In this work, we have simulated graphene nanoribbon based photodetector and impact of changing the width, and Boron-Nitride doping and Stone-Wales defects on the optical properties of GNR has study. The energy band structure of GNR with nearest-neighbor approximation in a tight binding model calculated. To correspond with experiment and accuracy, we need to consider the impact of third nearest neighbors and edge bond relaxation. By Using the band structure, we calculated joint density of state and optical matrix elements and obtain inter band selection rule for A-GNR and Z-GNR. Then, using the Fermi’s golden rule, we investigate optical properties of GNR such as optical conductivity and... 

    Nanoribbons of SnO2 as a high performance Li-ion battery anode material

    , Article Materials Research Express ; Volume 5, Issue 6 , 2018 ; 20531591 (ISSN) Sadati Faramarzi, M ; Abnavi, A ; Ghasemi, S ; Sanaee, Z ; Sharif University of Technology
    Institute of Physics Publishing  2018
    Abstract
    Here, SnO2 nanoribbons (NRs) synthetized on the catalyst-free stainless steel (SS) substrate as a possible anode for Li-ion batteries (LIBs) have been reported. SnO2 NRs were synthesized on catalyst-free SS substrate via vapor-solid (VS) growth approach. Morphological and structural characterizations of the SnO2 NRs were confirmed using scanning electron microscopy (SEM), transmission electron microscopy (TEM) microscopes and x-ray diffraction (XRD) respectively. The prepared binder-free electrode demonstrated high initial discharge/charge capacities of 1818/929 mAh g-1 at current density of 300 mA g-1. A reversible capacity of 676 mAh g-1 with a coulombic efficiency of 98.5% has been... 

    Numerical simulation of unsteady airflow in a nasal cavity for various sizes of maxillary sinus opening in a virtual endoscopic surgery

    , Article Respiratory Physiology and Neurobiology ; Volume 291 , 2021 ; 15699048 (ISSN) Moniripiri, M ; Amjadimanesh, H ; Faramarzi, M ; Sadrizadeh, S ; Abouali, O ; Sharif University of Technology
    Elsevier B.V  2021
    Abstract
    Functional endoscopic sinus surgery (FESS) is performed to treat sinusitis when treatment with medication fails. In the present study, three different virtual maxillary sinus endoscopic surgeries were performed on a realistic 3-D computational model of the nasal cavity of an adult male under the supervision of a specialist. They included only uncinectomy, uncinectomy + 8mm Middle Meatal Antrostomy (MMA) and uncinectomy + 18 mm MMA. Simulations were performed for two human activity respiratory rates, including rest and moderate activities, and effects of different surgeries and respiratory rates on maxillary sinus were investigated. It was found that after endoscopic sinus surgery, the volume... 

    Invetigation Over Bio Elimination of Para Chlorophenol by Paraconiothyrium Fungal Strain Variabile

    , M.Sc. Thesis Sharif University of Technology Movahednia, Mohammad Mehdi (Author) ; Yaghmaei, Soheila (Supervisor) ; Faramarzi, Mohammad Ali (Supervisor)
    Abstract
    The ability of Paraconiothyrium variabile, a soil isolated ascomycete, was investigated to remove para chlorophenol in submerged culture media. Among the tested para chlorophenol concentrations, concentration of 40 and 100 mg l-1were found to have minimum and maximum toxic effects, respectively, on the growth of the microorganism and at the same time high and low bioelimination percentages. The fungal strain was able to remove 86% of ρ-CP (with initial concentration of 40 mg l-1) but no significance removal observed at 100 mg l-1 concentration. Monitoring of laccase production level in the fermentation broth together with pollutant removal confirmed the key role of this copper containing... 

    SnO2@a-Si core-shell nanowires on free-standing CNT paper as a thin and flexible Li-ion battery anode with high areal capacity

    , Article Nanotechnology ; Volume 28, Issue 25 , 2017 ; 09574484 (ISSN) Abnavi, A ; Sadati Faramarzi, M ; Abdollahi, A ; Ramzani, R ; Ghasemi, S ; Sanaee, Z ; Sharif University of Technology
    Institute of Physics Publishing  2017
    Abstract
    Here, we report 3D hierarchical SnO2 nanowire (NW) core-amorphous silicon shell on free-standing carbon nanotube paper (SnO2@a-Si/CNT paper) as an effective anode for flexible lithium-ion battery (LIB) application. This binder-free electrode exhibits a high initial discharge capacity of 3020 mAh g-1 with a large reversible charge capacity of 1250 mAh g-1 at a current density of 250 mA g-1. Compared to other SnO2 NW or its core-shell nanostructured anodes, the fabricated SnO2@a-Si/CNT structure demonstrates an outstanding performance with high mass loading (∼5.9 mg cm-2), high areal capacity (∼5.2 mAh cm-2), and large volumetric capacity (∼1750 mAh cm-3) after 25 cycles. Due to the... 

    The Study of The Behaviour of Steel Structures with Semi-Rigid Connections Subject to Fire

    , M.Sc. Thesis Sharif University of Technology Alanchari, Ehsan (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    Fire is one the events which threatens the very existence of every building, residential, office, industrial or else. However, this threat is more serious with regard to buildings with steel structures. Steel, despite its many advantages over other structural materials, such as having high strength to weight ratio, ductility, toughness and resilience, has the disadvantage of rapidly losing its strength at elevated temperatures, i.e. in fire. Therefore, it is the responsibility of the designer to make the serious decision of whether to use steel, concrete, timber, or other materials for the structure of the building to be designed. Observations made during full-scale fire tests as well as... 

    Studying the Behaviour and Performance of an Innovative Floating Offshore Platform

    , M.Sc. Thesis Sharif University of Technology Moradkhan, Esmaeil (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    The objective of this project is to study the behaviour and performance of an innotative floating offshore platform. Such Platform not only can be used for exploring oil from offshore fields, but for creating artificial islands, where land is in short supply. Due to its specific and, at the same time, simple geometry (symmetric), its fabrication does ont involve much complexity. Studies carried out on this platform include the investigation into its structural behaviour under gravitational (including self weight) and bouyancy forces. Studied cases include a number of platforms with different (geometrical) sizes and under 3 various bouyancy conditions (percentage), namely 1) 50% of the height... 

    Micro-modeling of Tehran 4-stroke Gasoline Motorcycle Fleet Emission and Investigating the Effects of Increasing Fueling System and Engine Technology Level

    , M.Sc. Thesis Sharif University of Technology Hassani, Amin (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    The city of Tehran is dealing with air pollution problems for years. Providing a solution for this problem requires information about different pollutants emission sources. In this subjects, emission factors and emission models are essential tools for decision makers. Among different mobile emission sources in Tehran, motorcycles are of high importance. In this project, for the first time in Iran, exhaust gas pollutants emission of 66 motorcycles with different ages and engine displacement volumes were measured according to Euro-3 standard certification procedure. Measurement results showed that none of the tested motorcycles passed the Euro-3 certification limit on CO emission. Calculations... 

    Partially Homogenous HCCI Combustion Chemical Kinetics Model Initial Conditions Development by CFD Modeling

    , M.Sc. Thesis Sharif University of Technology Babazadeh, Amin (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    Homogeneous Charge Compression Ignition (HCCI) engines are the new generation of internal combustion engines which have diesel-like thermal efficiency, while they have low nitrogen oxide and soot emission. One of the major problems of HCCI engines is combustion timing control due to its dependence on reactivity of the charge and chemical kinetics. Moreover, limiting operation range between knock and misfiring is the other drawback of using these kind of engines. In the present work, partially homogeneous HCCI combustion in a single cylinder diesel engine is modeled using Computational Fluid Dynamics (CFD) coupled with chemical kinetics. Simulation includes the engine cycle from exhaust valve... 

    Traffic Source Particle Pollution Distribution Using Micro-scale Simulation

    , M.Sc. Thesis Sharif University of Technology Babaei, Mahdi (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    Today air pollution has become one of the major urban management concerns. Air pollution could have dangerous effects on human health in short time or long time in many situations. Numerical modelling is one of the most applicable among different ways for predicting pollutant concentration like field measurement, physical model in wind tunnel, and simulation. Modelling of pollutant dispersion is a way for estimating concentration and aggregation of the pollutant near the surface and with different distances from pollution source. In different dispersion models, one of simplest is the Gaussian model. In this approach it is supposed that emission plume obeys from Gaussian distribution and is... 

    Investigating the Response Reduction Factor of Steel 3-D Braced Frames with Eccentricity

    , M.Sc. Thesis Sharif University of Technology Afshari, Behrouz (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    Studying the performance of irregular structures in past earthquakes reveals that due to their severe vulnerability, we need to accurately assess the behavioral characteristics of such structures. On the other hand, all existing seismic codes recommend the use of response modification factor to determine the base shear, design forces of the members, and the design drift ratios, which seem to have limited comprehensiveness. Moreover, the response modification factor for a structural system is discussed in a general manner and the effect of factors such as number of bays, number of stories, span length, story height and irregularities are not considered. In this research, the effects of... 

    Experimental Study of the Hysteretic Behavior of a new Bracing System

    , M.Sc. Thesis Sharif University of Technology Zarei, Davood (Author) ; Khansari, Vahid (Supervisor)
    Abstract
    In this study, the behavior of a new innovative bracing system under cyclic loading and according to AISC code is investigated. An Ideal bracing system, in addition to having sufficient stiffness, should have a suitable ductility. Also, in order to prevent inelastic behavior of other structural members, braces, in addition to possessing high architectural adaptivity, must be able to contain the damage within itself and behave like a fuse. Three specimens with different sections, IPE100, HEA100 and 2UNP100, were designed and tested. The results of these tests represent an elastic- (approximately) perfectly plastic behavior of the brace if an appropriate section is used. Moreover, this bracing... 

    Investigating the Response Modification Factor of 3-D Steel Braced/Moment-Resisting Frames with Irregularity in Plan

    , M.Sc. Thesis Sharif University of Technology Rezazadeh, Mohsen (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    Study of former earthquakes damages reveals that irregular structures are more susceptive to failure than regular ones. Irregular structures are classified into two categories, namely those with irregularity in elevation and the ones with irregularity in plan. Besides, one of the crucial parameters in working out the earthquake’s equivalent static load is response modification coefficient (R). Based on the type of seismic lateral force-resisting system, this parameter can have various values. In this research, using nonlinear static analysis, the response modification coefficient of a great number of 3-D steel frames of 5, 7 and 9 m spans and having 1 to 10 stories with various... 

    Experimental Study of a New Steel Shear Wall

    , M.Sc. Thesis Sharif University of Technology Seyf, Hamed (Author) ; Khansari, Vahid (Supervisor)
    Abstract
    The lateral force & its control has always been a great concern to structural designers. Based on the project’s location, this force can be either earthquake or wind force. In our country, Iran, the earthquake force is usually the dominant one. Of the most important differences between these two kinds of forces, we may point out the cyclic characteristics and nature of earthquake forces. One can choose different strategies to face the earthquake force including the use of dampers. Dampers exist in vast varieties of different categories which we will briefly explain in this thesis. Dampers can be used on their own or in combination with other lateral force resistance systems like bracings or... 

    An Experimental Study of the Hysteretic Shear Behavior of a Semi-Rigid Connection

    , M.Sc. Thesis Sharif University of Technology Mohammadi, Alireza (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    The behaviour of a semi-rigid connection with appreciable shear deformation capacity was studied experimentally. The tests carried out on the specimens of this connection composed of ‘monotonic’ and ‘cyclic’ tests. The monotonic tests results showed the high shear deformation capacity of this connection as well as its high energy dissipation capacity. The cyclic tests, however, indicated the ability of this connection to endure large number of ‘well-rounded’ hysteresis cycles, which led to the dissipation of great amount of energy before failure  

    Investigating the Behavior of a Type of Energy Absorbing Bracing System

    , M.Sc. Thesis Sharif University of Technology Farahani, Hossein (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    Bracing Systems are usually a set of inclined members that are embedded in structures to resist lateral forces and control lateral displacements. There are different types and behaviors for Bracing Systems depending on the way of assembling and locating them in the structure. Braced Frames, such as Concentrically Braced Frames (CBFs), generally have high stiffness and low ductility. Another Type of Braced Frames is Eccentrically Braced Frames (EBFs) which improves CBFs by establishing suitable ductility as well as stiffness. Inelastic behavior of Links involved with EBFs caused this in EBFs. Nevertheless, these systems have no efficiency in next earthquake, because links are parts of beams... 

    Numerical Modeling of the Behavior of an Innovative Steel Shear Wall

    , M.Sc. Thesis Sharif University of Technology Valikhani, Alireza (Author) ; Khonsari, Vahid (Supervisor)
    Abstract
    The behavior of a new steel shear wall, already devised by the supervisor of this project, and tested by other students, was modeled numerically. Such numerical simulation was carried out using the Finite Element Methods of analysis. Hexagonal solid elements were employed in order to discretize the tested specimens and those parts of the test assembly which had to be included in the models. Both, Monotonic and Cyclic tests were simulated numerically. Comparison of the tests results with those of the numerical models showed fair correlation between them. Percentages of error in the dissipated energy for the three monotonic tests were 6.9%, 6.4% and 11.2%, respectively, whereas that of the... 

    Investigating and Comparison of Emission and Fuel Consumption Behavior of Diesel Vehicles under Various Elevations Using Portable

    , M.Sc. Thesis Sharif University of Technology Ashjaee, Behzad (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    As elevation increase, environmental impacts will change, and this will affect on vehicle performance. The pressure drop and consequently the drop in air density at high altitude affect the volumetric efficiency of the engine. This exacerbates engine combustion, since the engine displacement volume is constant, with the drop in air density, the intake air mass flow rate decreases. In this situation, the engine does not have enough air to burn the fuel, and as a result the engine ignition will getting into the defect. ECU only changes the amount of injecting fuel and has no control on the entering air flow to the engine. In such circumstances, emissions from the vehicle are expected to... 

    Design of a Portable Dilution Sampling System for Measuring Fine Particle and Vocs Emissions from Vehicles and Stack in Iran

    , M.Sc. Thesis Sharif University of Technology Geraei, Hosna (Author) ; Hosseini, Vahid (Supervisor)
    Abstract
    Combustion sources such as diesel vehicles are the most of the particular matter sources in ambient air. Near the tailpipe, exhaust is very hot, condense and have high velocity. This properties cause to need special methods and instrument to collect them. Numerously of combustion sources will emitted the VOCs, IVOCs, and SVOCs. This component mixed with ambient air and changing to particle phase from gas phase. Reaction between nitrogen oxides with sunlight cause to damage ozone layer and tissue in long time. Furthermore, breathe of VOCs gases cause to eye irritation, gastrointestinal effects, Damage to the nervous system, headache, dizziness, fatigue, vibration and loss of organ...