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    Efficient and less-toxic indium-doped mapbi3 perovskite solar cells prepared by metal alloying technique

    , Article Solar RRL ; Volume 6, Issue 9 , 2022 ; 2367198X (ISSN) Tavakoli, M. M ; Fazel, Z ; Tavakoli, R ; Akin, S ; Satapathi, S ; Prochowicz, D ; Yadav, P ; Sharif University of Technology
    John Wiley and Sons Inc  2022
    Abstract
    Perovskite materials with ABX3 structure (A: organic, B: metal, and X: halides) have attracted tremendous attention due to their outstanding optoelectronic properties. Herein, a novel approach is developed using chemical vapor deposition (CVD), i.e., metal alloying of halide-perovskite domain via ion-transfer (MAHDI) for the growth of high-quality perovskite films, grown directly from a metal precursor. This technique easily enables us to replace the toxic Pb metal (B site) with other metals using alloying approach. Using the proposed approach, we fabricated stable and efficient Pb–In perovskite solar cells (PSCs) with a maximum power conversion efficiency (PCE) of 21.2%, which is more... 

    Effect of bromine doping on the charge transfer, ion migration and stability of the single crystalline MAPb(Br: XI1- x)3photodetector

    , Article Journal of Materials Chemistry C ; Volume 9, Issue 42 , 2021 , Pages 15189-15200 ; 20507534 (ISSN) Mahapatra, A ; Prochowicz, D ; Kruszyńska, J ; Satapathi, S ; Akin, S ; Kumari, H ; Kumar, P ; Fazel, Z ; Tavakoli, M. M ; Yadav, P ; Sharif University of Technology
    Royal Society of Chemistry  2021
    Abstract
    Organic-inorganic halide perovskites (OIHPs) have emerged as a promising semiconductor for the fabrication of efficient optoelectronic devices such as photodetectors (PDs). Among all the perovskite compositions, the mixed-halide MAPb(BrxI1-x)3 formulations have gained more attention for photodetection application thanks to their tunable optoelectronic properties and great stability. However, there is still a lack of sufficient understanding of the effect of Br doping on the stability and physical properties of MAPb(BrxI1-x)3 based PDs. In this work, we prepare a series of MAPb(BrxI1-x)3 (x = 0, 0.04, 0.08, 0.12, and 0.16) single crystals (SCs) and investigate the influence of the Br content...