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    Investigation and Synthesis of Zn-Ni-Mn Three Cationic Electrophosphate Coating

    , M.Sc. Thesis Sharif University of Technology Alimi, Zahra (Author) ; Ghorbani, Mohamad (Supervisor)
    Abstract
    The purpose of this study was to create a three-cationic electro phosphate coating of zinc-nickel-manganese by cathodic method and to investigate the effect of operating variables on the properties of zinc-nickel-manganese tri-cationic electro phosphate coating. Hence, the effects of variables such as coating acidity, coating thickness, coating temperature, coating time and concentration of manganese were studied in the bath on the properties such as coating morphology, corrosion resistance, coating thickness. Coating morphology was characterized by scanning electron microscopy and corrosion resistance by polarization test. The pH values of 1.4, 1.8, 2 and 2.2 were selected, and the results... 

    Investigation of Aligned Carbon Nanotubes Modified by Platinum Nanoparticles as Hydrogen Sulfide Sensor

    , M.Sc. Thesis Sharif University of Technology Salmani Rezaie, Salva (Author) ; Dolati, Abolghasem (Supervisor) ; Ghorbani, Mohamad (Supervisor)
    Abstract
    The present research describes sensing behavior of modified aligned carbon nanotubes toward detection of hydrogen sulfide. Aligned carbon nanotubes were grown on etched stainless steel by thermal chemical vapor deposition. Obtained CNTs have curved closed tips and bamboo like structure. Purification of carbon nanotubes were performed by electrochemical oxidation of CNTs. Potential cycling was applied on grown CNTs in different acid solutions and 0.2 M sulfuric acid was chosen to oxidize the CNTs. Carboxylic functional groups were produced by electrochemical oxidation of CNTs and can be observed in FTIR studies. These groups enhanced the electrochemical properties of electrodes and may act as...