Sharif Digital Repository

Selective catalytic reduction (SCR) of NOx by NH3 over a series of Mn–M/Z catalysts (M = Cr, Mn, Fe, Co, Ni, Cu, Zn, and Z = the ZSM-5 Zeolite) synthesized by wet impregnation method was investigated. Mn–Fe/Z, Mn–Co/Z, and Mn–Cu/Z catalysts exhibited approximately 100 % NOx conversion over a wide temperature range (200–360 °C) in a defined atmospheric condition, which was noticeably greater than that of Mn–Cr/Z (340–360 °C). Furthermore, the effect of addition of second metal oxide species to the initial Mn/Z catalyst on the structure of catalysts was studied by several characterization techniques. BET measurements revealed high surface area and pore volume of the Mn–Cu/Z catalyst. In... 

The perovskite oxide BaTiO3, doped with Ge oxides oxidized methane to C2 coupled hydrocarbons. The pure barium titanate exhibited an ultraviolet absorption effect. The addition of GeO2 resulted in an increase in absorption of wavelength. Small amount of Ge decreased band gap energy. For promoted BaTiO3 catalysts with stable cation valance, electron donation ability of lattice oxygen was parallel to its ability of adsorb and active oxygen, and decreased the chance of deep oxidation of methyl radicals and C2 hydrocarbons and thus will result in an increase of C2 yield. This is an abstract of a paper presented at the 42nd Loss Prevention Symposium (New Orleans, LA 4/6-10/2008)  

The perovskite oxide BaTiO3, doped with Ge oxides oxidized methane to C2 coupled hydrocarbons. The ultraviolet-visible spectra of pure barium titanate and Ge doped BaTi(1-x)GexO3(x=0.05,0.1) were compared. The pure barium titanate exhibited an ultraviolet absorption effect. The addition of GeO2 resulted in an increase in absorption of wavelength. Therefore, small amount of Ge decreased band gap energy. Oxygen is inserted by nucleophilic attack which may be considered as an acid-base process. For promoted BaTiO3catalysts with stable cation valance, electron donation ability of lattice oxygen is parallels to its ability of adsorb and active oxygen, and decrease the chance of deep oxidation of... 

The perovskite oxide BaTiO3, doped with Ge oxides oxidized methane to C2 coupled hydrocarbons. The ultraviolet-visible spectra of pure barium titanate and Ge doped BaTi(1-x) GexO3 (x=0.05 ,0.1) were compared. The pure barium titanate exhibited an ultraviolet absorption effect. The addition of GeO2 resulted in an increase in absorption of wavelength. Therefore, small amount of Ge decreased band gap energy. Oxygen is inserted by nucleophilic attack which may be considered as an acid-base process. For promoted BaTiO3 catalysts with stable cation valance, electron donation ability of lattice oxygen is parallels to its ability of adsorb and active oxygen, and decrease the chance of deep oxidation...