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Modified carrageenan. 4. Synthesis and swelling behavior of crosslinked kappa C-g-AMPS superabsorbent hydrogel with antisalt and pH-responsiveness properties [electronic resource]
, Article Journal of Applied Polymer Science ; Vol.98, No.1, 255-263, 2005 ; Hosseinzadeh, H ; Mazidi, R
Abstract
To synthesize a novel biopolymer-based superabsorbent hydrogel, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) was grafted onto kappa-carrageenan (KC) backbones. The graft copolymerization reaction was carried out in a homogeneous medium and in the presence of ammonium persulfate (APS) as an initiator, N,N,N',N'-tetramethyl ethylenediamine (TMEDA) as an accelerator, and N,N'-methylene bisacrylamide (MBA) as a crosslinker. A proposed mechanism for KC-g-AMPS formation was suggested and the hydrogel structure was confirmed using FTIR spectroscopy. The affecting variables on swelling capacity, i.e., the initiator, the crosslinker, and the monomer concentration, as well as reaction temperature,...