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Synthesis parameters effect on the final morphology of the layered double hydroxide (LDH)
, Article Protection of Metals and Physical Chemistry of Surfaces ; Volume 53, Issue 3 , 2017 , Pages 460-465 ; 20702051 (ISSN) ; Afshar, A ; Sharif University of Technology
Maik Nauka Publishing / Springer SBM
2017
Abstract
Smart coatings which prevent corrosion by several mechanisms recently have been carefully planned. One of these mechanisms is the use of ion exchangers like LDH in the coating network. Since the morphology is the most important properties for the applications that the surface plays an important role, LDH morphology was evaluated in this study. For this purpose, the LDH contain a kind of green inhibitor was synthesized and after evaluating its performance it was examined morphologically by changing significant parameters like MII/MIII, pH, aging time and temperature. It is found that, high ratio of the MII/MIII cause thinner layer of LDH. The pH also has special effect on the surface...
Corrosion protection of aluminum by smart coatings containing layered double hydroxide (LDH) nanocontainers
, Article Journal of Materials Research and Technology ; Volume 8, Issue 3 , 2019 , Pages 3004-3023 ; 22387854 (ISSN) ; Afshar, A ; Sharif University of Technology
Elsevier Editora Ltda
2019
Abstract
In this study, the LDH containing a kind of green inhibitor (sodium molybdate) was synthesized and utilized in a poly-vinyl alcohol (PVA) base coating applied on the aluminum (5054 series) surface. After evaluating the LDH performance, the inhibitor release from the LDH crystals was examined by changing significant parameters like MII/MIII (the molar ratio of divalent ions into trivalent ions), pH, aging time and temperature. In order to find the kinetic release of intercalated inhibitor a prediction model was introduced in 3.5% NaCl solution. The model expressed that the pH as the processing parameter has special effect on the kinetic releasing of the inhibitor. It can enhance the amount of...
Corrosion Protection of Aluminium by Smart Coatings Containing Layered Double Hydroxide (LDH) Nanocontainers
, Ph.D. Dissertation Sharif University of Technology ; Afshar, Abdollah (Supervisor)
Abstract
Smart coatings which prevent corrosion by several mechanisms recently have been carefully planned. One of these mechanisms is the use of ion exchangers like Layered Double Hydroxide (LDH) in the coating network. In this study, the LDH containing a kind of green inhibitor (sodium molybdate) was synthesized and utilized in a Poly-Vinyl Alcohol (PVA) base coating applied on the aluminium (5054 series) surface. After evaluating the LDH performance, the inhibitor release from the LDH crystals was examined by changing significant parameters like MII/MIII (the molar ratio of divalent ions into trivalent ions), pH, aging time and temperature. Considering the LDH morphology or the thickness of the...
Experiments design for hardness optimization of the Ni-Cr alloy electrodeposited by pulse plating
, Article Acta Metallurgica Sinica (English Letters) ; Volume 26, Issue 5 , 2013 , Pages 558-564 ; 10067191 (ISSN) ; Yousefi, E ; Dolati, A ; Mohammadi, M. R ; Sharif University of Technology
2013
Abstract
The hardness of the Ni-Cr alloy which is electrodeposited in chloride solution, is optimized by design of experiment method (central composite design). Various parameters were evaluated in order to find significant factors in this process. Frequency, duty cycle, current density and temperature were selected as effective factors. Analyses of variance (ANOVA) were performed on the results of the designed experiments. The best model which can predict the hardness of the Ni-Cr alloy electrodeposits was found whereas the frequency and quadratic behaviour of the current density were the most significant model terms. Serious interaction of the current density with frequency and duty cycle also were...
Electrodeposition of the Ni-Cr Alloy by Pulse Plating
, M.Sc. Thesis Sharif University of Technology ; Dolati, Abolghasem (Supervisor) ; Mohammadi, Mohammad Reza (Supervisor)
Abstract
In this thesis, the hardness of Ni-Cr alloys is optimized by design of experiment (DOE) method (Central Composite Design) in pulse electrodeposition performed in chloride solution. Various parameters were evaluated for finding significant factors in pulse electrodeposition of Ni-Cr alloy. Frequency, duty cycle, current density and temperature were selected as effective factors. 30 experiments were designed by the central composite design method. Analyses of Variance (ANOVA) were performed on the results of these 30 experiments. The best models which can predict the hardness, Cr content, deposition rate, thickness and cathode efficiency of Ni-Cr alloy electrodeposits were found and...
An Investigation on Deficiencies and Factors Affecting Construction Procedure; Case Study: Fars Province
, M.Sc. Thesis Sharif University of Technology ; Mofid, Masoud (Supervisor) ; Mortaheb, Mohammad Mehdi (Co-Advisor)
Abstract
Most regions in Iran are located on an active plate boundary. Therefore, many parts of the country face a risk of earthquake damage at some point in time. Therefore, anticipating and addressing the consequences of earthquake events in order to minimize loss of life and damage to property is a national issue.There is concern about the ability of a signification fraction of buildings in Iran to withstand earthquake events. The deficiencies in the design and construction of buildings in Iran result in low-quality buildings vulnerable to earthquakes. It is necessary to identify and investigate the parameters that contribute to these deficiencies.Previous research studies indicate that...
Blind Universal Steganalysis in Multiple Actor Paradigms and its Relation to Pixel-Cost
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
Steganography is method for communicating confidential information through a non-trustworth in way which hides the existence of communication. For improving the security of steganography statistical detectability must decrease as such as possible. Despite the fact, that the quality of the relation between statistical detectability and amount of distortion engendered by embedding is still an open problem, problem of detectability reduces to problem of management of pixel embedding in order to minimization of distortion. As in wet paper coding methods, an optimum (or approximately optimum) algorithm proportioned to Pixel-cost has been offered, the current problem of steganography is to find...
Designing a Vehicle Counting and Classification System
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
In recent years, Intelligent Transportation Systems (ITS) have received special attentions both in research and in commercial areas. Increased infrastructure facilities, like surveillance cameras, has made this concept even more attainable than before. In this respect, the ability to automatically extract information from traffic images, as one of the key inputs of ITSs, is of great importance. With an increased number of surveillance cameras and the need for more accurate information regarding the road users and their interactions, in order to better city traffic management, building and repairing roads, trip time estimation, number of people per roads estimation and etc, using human...
Economic Model Predictive Control with Time Varying Constraints
, M.Sc. Thesis Sharif University of Technology ; Haeri, Mohammad (Supervisor)
Abstract
In today's world we are dealing with many devices and processes with the goal of efficiency and performance improvement. In many processes particularly chemical ones, the goal is to control the output according to its constraints in the way that the performance is economically efficient, such as reducing energy consumption and energy loss and increasing efficiency. In order to control a process with economical goals, an economical cost function is used and after determination of optimal values a controller is used to guide the process so can achieve them. Model predictive control (MPC) is very common in this economic control Due to advantages such as considering the problem constraints. In...
Embedded Camera Design for Machine Vision Traffic Aplication
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
With the advent of technology, small in size sensors, memory, speeding up the processor and lowering the cost, it is possible to build an embedded camera system. The goal of this project is to design and build an embedded camera system so it can execute any set of necessary algorithms as depending on the application. In this project, two models of embedded camera systems have been presented as an integrated system and a system with independent units. To design the integrated embedded system, ZYNQ processor is used and two structures are presented in the form of hardware-software and hardware design. In hardware-software design, image processing operations are done by software and in hardware...
Activity Analysis Based on Mobile Sensors
,
M.Sc. Thesis
Sharif University of Technology
;
Gholampour, Iman
(Supervisor)
Abstract
Smartphone sensors like accelerometer, gyroscope and magnetometer are very common nowadays. This gives us the opportunity for sensor-based activity recognition. This thesis's goal is to collect data from different smartphone sensors and then extract hand-crafted features and classify them using machine learning algorithms. Metro, bus, taxi, bicycle, running, upstairs, walking and standing are studied activities in this thesis. All above steps are covered in this research, later we want to present an activity recognition model and then test it through a web server, after that, we modify the model by proposing to change learning coefficient to gain better accuracy. Finally, an Android app was...
The Impact of Digital Technologies on CO2 Emissions: A Comparison between Developed and Developing Countries
, M.Sc. Thesis Sharif University of Technology ; Miremadi, Iman (Supervisor)
Abstract
The importance and vitality of focusing on sustainable transition and reducing carbon dioxide emissions are clear to everyone today. However, until recently, the impact of digitization as a major global trend involving the application of digital technologies to change and optimize various elements of business, society, and daily life on the environment and carbon dioxide emissions has been underestimated. Despite the growing amount of research in this field, according to current studies, the connection between digitization and carbon dioxide emissions is not clear. To achieve environmental and sustainable development goals, fossil fuel consumption and greenhouse gas (GHG) emissions must be...
Teraffic Analysis with the Usage of Big Data Anlytics
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
Predicting traffic condition is one of the most important topics for traffic engineers and is a vital part of smart city. Extracting traffic behavior and realizing new traffic behaviors plays undeniable parts in big decision making of cities. On the other hand, progress of new technologies and devices for controlling and monitoring traffic caused the volume of traffic related data to grow exponentially. Velocity and variety of these data made normal data mining solution to fail in modeling and performing well. New data era has changed the view of large numbers of science and engineering majors. Traffic engineering also needs big data analytics for process of its own big data. Thus the need...
Exploring Public Perception of Justice in Mobility Transitions: Evidence from a Bicycle Sharing System in Iran
,
M.Sc. Thesis
Sharif University of Technology
;
Miremadi, Iman
(Supervisor)
Abstract
Globally, bicycle sharing is one of the fast-growing solutions to climate change in the transport sector. However, what inequities may be reflected, exacerbated, or arose from its adoption and use? Relying on a qualitative research design involving interviews with bicycle sharing users, non-adopters, and daily observers of the cycling infrastructure (N = 36), site visits, and a literature review, we examine distributive, procedural, and recognition injustices in association with Bdood, an operating BSS in Iran, a developing country that allows for less-documented types of injustice to arise. In doing so, we utilize a comprehensive transport/mobility justice framework, drawn from the fields...
People Detection and Tracking with Privacy Protection
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
The multi people tracking is considered a fundamental problem in computer vision, which has received considerable attention from academic and commercial fields. This issue deals with a set of proposed methods that track the movement path of several humans in a video-like sequence. The problem of multi people tracking is the foundation of other computer vision problems, including human gesture estimation, motion recognition, and behavioral analysis, and is mainly used in emerging fields such as automatic car driving, smart security, service robots, etc. Although many methods have been proposed and investigated to solve the above problem; But there are still serious challenges, such as severe...
Kinetic study and growth behavior of template-based electrodeposited platinum nanotubes controlled by overpotential
, Article Materials Chemistry and Physics ; Volume 187 , 2017 , Pages 141-148 ; 02540584 (ISSN) ; Dolati, A ; Imanieh, I ; Yashiro, H ; Kure-Chu, S. Z ; Sharif University of Technology
Elsevier Ltd
2017
Abstract
Platinum nanotubes (PtNTs) are fabricated by potentiostatic electrodeposition at various overpotentials (−200 up to −400 mV versus SCE) in polycarbonate templates (PCTs) with pore diameter of 200 nm in a solution containing 5 mM H2PtCl6 and 0.1 M H2SO4. The synthesized PtNTs are characterized by field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The electrochemical growth mechanism within nanoscopic pores and the relationship between morphological variations and kinetic parameters are investigated for the first time. It is shown that more porous structure of nanotubes forms at high overpotentials possibly due to preferably nucleation. The...
Scene Detection and Analysis by Image Classification in Specific Classes
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
Traffic density estimation is one of the most challenging problems in Intelligent Transportation Systems. One of the important traffic information that is broadcasted to drivers is Traffic Density information. In many traffic control centers; human operators are responsible for estimating traffic density from captured video data. Increasing traffic cameras and constraint number of operators introduce an updating delay to broadcasted information. So it is important to have an automatic traffic density estimation system. In this thesis, machine vision is used to solve this problem. Supervised Image classification is our approach. In supervised Image classification, images are classified to...
Investigating the Relation Between Pixel Cost, Steganographic Capacity and Statistical Detectability
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
Statistical detectability is a feature of a steganalyzer that states its power for distinguishing between cover and stego images. A steganographer tries to design the steganography algorithm such that the steganalyzer could not detect the stego images. As a result, designing an efficient steganography algorithm (assigning the pixel cost) that could minimize the statistical detectability is an important objective in steganography. However, making a sensible relation between the pixel cost and statistical detectability is an open problem.
In this thesis, by modeling the steganalyzer using the LDA topic model, we analyze its error probability as a criterion of statistical detectability....
In this thesis, by modeling the steganalyzer using the LDA topic model, we analyze its error probability as a criterion of statistical detectability....
Audio Processing For Internet of Things
, M.Sc. Thesis Sharif University of Technology ; Gholampour, Iman (Supervisor)
Abstract
Audio signal processing is a greatly useful approach to the Internet of Things since analyzing prominent audio signals can provide valuable information about environmental activities. Environmental sound processing is used in applications such as mechanical systems diagnosis, industrial maintenance, security systems, etc. This approach requires the design and development of sound classification and detection systems. In this thesis, we have achieved 84.5% accuracy on optimizing the features (by feature engineering and feature learning) and exploiting different types of machine learning algorithms. Well-known databases such as ESC-50 have been used to test and evaluate the whole system. Among...
Analyzing IoT System Using Location-Base Data
,
M.Sc. Thesis
Sharif University of Technology
;
Gholampour, Iman
(Supervisor)
Abstract
Nowadays, using different types of data has shown significant impacts on analyzing the related systems. Growth in data volume, systems complexity and existence of error and obscurity in collecting the data, increased the necessity of inventing new data analysis methods. Location-based data is an important data type for such analyses which are collected from sensors in different places. These data besides other official organization's information like municipality or Google … provide us a bulk volume of raw data. Such collections of raw data are mostly diverse, heterogeneous, bulk and outspread. Inspite of that, raw data with machine learning algorithms lead to considerable practical...