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A sensitive colorimetric detection of ascorbic acid in pharmaceutical products based on formation of anisotropic silver nanoparticles
, Article Scientia Iranica ; Volume 17, Issue 2 F , 2010 , Pages 148-153 ; 10263098 (ISSN) ; Karimi, M. A ; Shahheydari, F ; Sharif University of Technology
2010
Abstract
A sensitive colorimetric method for the detection of ascorbic acid was proposed in this research based on the reduction of silver ions by ascorbic acid in the presence of citrate-stabilized silver seeds, additional trisodium citrate and a polymer such as polyvinylpyrrolidone. The color of the stable sol is controlled by varying the concentration of trisodium citrate (TSC), polyvinylpyrrolidone, silver nitrate and silver seeds. The reduction of Ag + to triangle silver nanoparticles (Ag-NPs) by ascorbic acid in the presence of trisodium citrate (TSC) and silver seeds produced two very intense surface plasmon resonance peaks of Ag-NPs. The plasmon absorbance of Ag-NPs allows the quantitative...