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    Compositional Modeling of Surfactant Adsorption in Chemical Flooding with Verification with Laboratory Data

    , M.Sc. Thesis Sharif University of Technology Khandan, Hossein (Author) ; Jamshidi, Saeed (Supervisor) ; Ghazanfari, Mohammad Hossein (Supervisor)
    Abstract
    One of the most important EOR methods in oil reservoirs is surfactant and polymer flooding. Surfactants cause decreasing in interfacial tension between oleic and aqueous phases. However, polymers give us efficient mobility control in displacing oil by increasing the viscosity of aqueous phase. Therefore, oil is displaced in aqueous phase by viscous forces.
    One of the most important challenges in surfactant flooding is adsorption. The net surface charge distributed on the rock surface depends strongly on pH. When we inject surfactant in reservoir, electrostatic charge on rock surface causes the first-layer adsorption. After that we have had second-layer adsorption.
    In this thesis we... 

    Estimating an Index of Iran’s Informal Economy in 1350-1386 With Concentration on the Impact of Government’s Intervention by EMIMIC Model (The Multiple Indicators-Multiple Causes Model and Error-Correction Model)

    , M.Sc. Thesis Sharif University of Technology Khandan, Abbas (Author) ; Nili, Masoud (Supervisor)
    Abstract
    In this research, an Index of Iran informal economy in response to the government interventions in credit, labor and product markets is stimated by EMIMIC model. To do this, first these interventions are measured using principal components analysis. In the model, the variables GDP and employment are used as indicators and taxation rates, government distortions in credit, labor and product markets, government expenditure, per capita income, unemployment and inflation as causes of the informal economy. We conclude these government interventions have affected Iran informal economy and their influence is more than indirect interventions influence such as taxation. The estimated index of Iran... 

    Government interventions and the size of the informal economy. The case of Iran (1971-2007)

    , Article Journal of Economic Policy Reform ; Vol. 17, issue. 1 , 2014 , pp. 71-90 ; ISSN: 17487870 Khandan, A ; Nili, M ; Sharif University of Technology
    2014
    Abstract
    Literature on the informal economy can mainly be divided into two different contrasting theories. According to the dual labor market theory (DLM), which considers the informal economy as a spare sector providing jobs for formally unemployed resources, unpleasant economic situations force people to act informally. Legalists, on the other hand, blame government interventions such as minimum wages or price control policies for pushing rent-seeking firms toward the shadows. This study using an Error-correction Multi-Indicators Multi-Causes (EMIMIC) model, a systematic method consisting of structural and measurement equations, shows that these two theories are complementary rather than... 

    Direct production of dimethyl ether from synthesis gas utilizing a new bifunctional catalyst

    , Article 19th International Congress of Chemical and Process Engineering, CHISA 2010 and 7th European Congress of Chemical Engineering, ECCE-7, 28 August 2010 through 1 September 2010, Prague ; 2010 Khandan, N ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
    2010
    Abstract
    A series of bifunctional catalysts Cu-ZnO-ZrO 2/Al-modified H-Mordenite were prepared by co precipitating sedimentation method and were characterized. Active sites were dispersed well. The synthesis of dimethyl ether (DME) via direct CO hydrogenation was evaluated in a three-phase slurry reactor. Cu-ZnO-ZrO 2/Al-modified H-Mordenite was a suitable catalyst for the production of dimethyl ether from synthesis gas. The appropriate ratio of methanol synthesis catalyst (Cu-ZnO-ZrO 2) to methanol dehydration catalyst (Al-modified H Mordenite) was 2:1. In this condition, CO conversion and DME selectivity were ≈ 68% and 82%, respectively. This is an abstract of a paper presented at the 7th European... 

    Synthesis of dimethyl ether over modified H-mordenite zeolites and bifunctional catalysts composed of Cu/ZnO/ZrO2 and modified H-mordenite zeolite in slurry phase

    , Article Catalysis Letters ; Volume 129, Issue 1-2 , 2009 , Pages 111-118 ; 1011372X (ISSN) Khandan, N ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
    2009
    Abstract
    Synthesis of dimethyl ether (DME) via methanol dehydration were investigated over various catalysts, and via direct CO hydrogenation over hybrid catalysts composed of Al-modified H-Mordenite zeolite and Cu/ZnO/ZrO 2. H-Mordenite zeolite exhibited the highest activity in dehydration of methanol. However, its selectivity toward dimethyl ether was rather low. For this reason, the H-Mordenite was modified. Modification of zeolites was performed by wet impregnation method and considered catalysts were characterized by AAS, XRD and NH3-TPD analyses. Results of catalytic tests indicated that H-Mordenite modified with 8 wt% aluminum oxide was the best catalyst for synthesis of dimethyl ether from... 

    Determining an optimum catalyst for liquid-phase dehydration of methanol to dimethyl ether

    , Article Applied Catalysis A: General ; Volume 349, Issue 1-2 , 2008 , Pages 6-12 ; 0926860X (ISSN) Khandan, N ; Kazemeini, M ; Aghaziarati, M ; Sharif University of Technology
    2008
    Abstract
    The liquid-phase dehydration of methanol to dimethyl ether was investigated over various materials including synthetic zeolites, namely, ZSM-5, Y, Mordenite, Ferrierite and Beta as well as silica and alumina. The key characters investigated were the Si/Al ratio and cation exchange. The results showed that the Mordenite zeolite exchanged with H+ exhibited the highest activity in dehydration of methanol. After finding the most active catalyst, the Mordenite zeolite was modified with Cu, Zn, Ni, Al, Zr, Mg and Na via wet-impregnation method to further improve its selectivity, and characterized by AAS, XRD, NH3-TPD, NH3-FT-IR and BET surface area techniques. It was found that these materials... 

    Designing a new multifunctional peptide for metal chelation and Aβ inhibition

    , Article Archives of Biochemistry and Biophysics ; Volume 653 , 2018 , Pages 1-9 ; 00039861 (ISSN) Shamloo, A ; Asadbegi, M ; Khandan, V ; Amanzadi, A ; Sharif University of Technology
    Academic Press Inc  2018
    Abstract
    According to the Amyloid hypothesis, as the foremost scientific explanation for Alzheimer Disease (AD), the neuropathology of AD is related to toxic fragments of amyloid beta (Aβ) protein. Based on this hypothesis, an attractive therapeutic approach was demonstrated to identify multifunctional peptides able to modulate Aβ pathologies as the source of AD. On this premise, a bifunctional polypeptide based on the iAβ5p lead compound, was designed to inhibit Aβ aggregation and free metal ions. Herein, the efficacy of this novel drug in Zn2+ and Cd2+ ion chelation was examined through an integrated technique comprising combined Docking, QM, and MD simulations. MD relaxation of a set of probable... 

    Synthesis of tetrahydrofuran from maleic anhydride on Cu-ZnO-ZrO2/H-Y bifunctional catalysts

    , Article Catalysis Communications ; Volume 9, Issue 13 , 2008 , Pages 2195-2200 ; 15667367 (ISSN) Aghaziarati, M ; Soltanieh, M ; Kazemeini, M ; Khandan, N ; Sharif University of Technology
    2008
    Abstract
    A series of bifunctional Cu-ZnO-ZrO2/H-Y catalysts of different compositions were prepared by coprecipitating sedimentation method and were characterized by surface area and XRD analyses. The catalytic performance in synthesis of tetrahydrofuran was evaluated and optimized in a three-phase slurry batch reactor. The experimental results showed that the appropriate ratio of Cu/ZnO in the hydrogenation catalyst was 50/45, for which the conversion of maleic anhydride (MA) and selectivity of tetrahydrofuran (THF) reached 100% and 46%, respectively, at 50 bar and 493 K after 6 h of operation. Also, according to these results, it was demonstrated that the incorporation of zirconium oxide in the... 

    Hydrogenation of maleic anhydride to tetrahydrofuran using bifunctional catalysts

    , Article 18th International Congress of Chemical and Process Engineering, CHISA 2008, Prague, 24 August 2008 through 28 August 2008 ; 2008 Aghaziarati, M ; Kazemeini, M ; Soltanieh, M ; Khandan, N ; Sharif University of Technology
    2008
    Abstract
    A series of bifunctional catalysts, including Cu-ZnO-ZrO 2 and H-Y zeolite catalysts, were prepared and tested for conversion of maleic anhydride (MA) to tetrahydrofuran (THF). Cu-ZnO-ZrO 2 catalyst was used as the hydrogenating component and H-Y zeolite as the dehydrating component. The appropriate ratio of Cu/ZnO in the hydrogenation catalyst was 50:45, for which the conversion of MA and selectivity of THF reached 100 and 46%, respectively, at 50 bar and 493 K. The bifunctional catalyst of Cu-ZnOZrO 2/H-Y can produce THF from MA with high activity, selectivity, and stability. This is an abstract of a paper presented at the 18th International Congress of Chemical and Process Engineering... 

    Studying the Kinematics Compensation Mechanism in the Gait of Individuals with Excessive Anti-version using a Subject-Specific Musculoskeletal Model

    , M.Sc. Thesis Sharif University of Technology Khandan, Amin Reza (Author) ; Farahmand, Farzam (Supervisor) ; Narimani, Roya (Supervisor)
    Abstract
    In cases with excessive anteversion even after adolescence, surgeons have to choose osteotomy surgery to modify this abnormality. This surgery and modifying the anatomical problem does not necessarily lead to modify the patients’ gait cycle abnormalities; the authors’ hypothesis is the probable reason may be the persistence of the implement of the patients’ kinematics compensation mechanism even after the surgery. This mechanism is used to almost correct the gait of those with excessive anteversion. First, by using gait analysis text books, a patient’s gait cycle is analyzed; this analysis is consist of 3DGA with EMG and observational gait. Then, by using OpenSim, the patient’s patterns of... 

    Synthesis and Characterization of a Copper Catalyst for Low Temperature Water –Gas Shift Reaction

    , M.Sc. Thesis Sharif University of Technology Rafiee Renani, Mansoureh (Author) ; Khorasheh, Farhad (Supervisor) ; Khandan, Nahid (Co-Advisor)
    Abstract
    Water Gas Shift (WGS) reaction is an old reaction in which syngas is used for producing Hydrogen. At the present time, the major application of this reaction is in fuel cells, since the necessary Hydrogen for these cells is provided by this reaction.
    The present study investigate the influence of different preparation methods on properties of Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction, which is now known as the Commercial catalyst for low temperature WGS, and its influence on performance of Cu-ZnO/Al2O3 catalyst to derive an optimal Cu-ZnO/Al2O3 catalyst for water gas shift (WGS) reaction. Cu-ZnO/Al2O3 catalysts was synthesized by CP, DP, DP-Ultra, IWI , CP-Urea, and... 

    Molecular Dynamics Simulation of Aβ42 Neurotoxicity Inhibition in Order to Alzheimer’s Disease Treatment

    , M.Sc. Thesis Sharif University of Technology Khandan, Vahid (Author) ; Firoozabadi, Bahar (Supervisor) ; Saeedi, Mohammad Saeed (Supervisor)
    Abstract
    Alzheimer’s disease (AD) is the most common type of dementia in the elderly. The neuropathology and treatment of AD is not precisely determined yet, but according to the pathological studies, AD is associated with presence of toxic soluble oligomers and insoluble senile plaques formed by amyloidosis of Amyloid Beta (Aβ) in neocortical region of brain. An attractive therapeutic approach to treat AD is to identify small ligands that are capable of binding to critical residues in order to inhibit or reverse Aβ amyloidosis process as source of neurotoxicity. In this area, therapeutic efforts designed various organic agents and most of them focused on the N-terminal sequence of Aβ. The aim of... 

    Kinetics Study and Determining an Optimum Reactor Condition for Dimethyl-ether Synthesis by Dehydration of Methanol over Nano-Crystalline γ-Al2O3

    , M.Sc. Thesis Sharif University of Technology Alamolhoda, Sarah (Author) ; Kazemeini , Mohammad (Supervisor) ; Khorashe, Farhad (Supervisor) ; Khandan, Nahid (Supervisor)
    Abstract
    Dimethyl Ether (DME) is a pure and economic fuel which can be used as a suitable alternative for diesel fuels. Two processes are traditionally used for DME synthesis: producing methanol from synthesis gas and then dehydrating it to DME (direct process), and converting methanol into DME in a catalytic dehydration reactor over a solid-acid catalyst (indirect process), in which the indirect process seems to have economical advantage. In this research, the γ-Al2O3 catalyst was synthesized through precipitation process and then characterized by powder X-ray diffraction (XRD) and porosimetry analysis. Afterwards this catalyst was utilized in methanol dehydration reaction in a slurry reactor. Next,... 

    Calculation of the Energy Release Rate of Nano-Cracks in FCC Materials Via the Many Body Atomic Scale FEM

    , M.Sc. Thesis Sharif University of Technology Ostad Hossein, Alireza (Author) ; Mohammadi Shodja, Hossein (Supervisor)
    Abstract
    Since the classical continuum theory fails to deal with the problems associated with defects, stress concentrators, and relevant deformation phenomena in solids, alternative approaches that can detect the atomistic nature of materials' fracture are required. The deficiency of the capture the size effect which yields delusively high values for some components of the stress field right on the edge of the stress concentrators, and its weakness in describing the complex interaction between small inhomogeneities, cracks and the like when they are only a few nanometers apart, are among some of the disadvantages of the classical approach. In recent years, however, atomistic methods are emerging to... 

    The Study of Eliminating Gender Gap in Iran Labor Market on Participation Rate of Married Urban Women

    , M.Sc. Thesis Sharif University of Technology Asghari, Fatemeh (Author) ; Rahmati, Mohammad Hossein (Supervisor) ; Joshaghani, Hossein (Supervisor)
    Abstract
    The low female labor force participation rate in the Iranian labor market relative to the global average and even to countries that do not differ significantly from the socio-economic characteristics of our country is one of the important questions of the Iranian labor market. In this study, we seek to answer the question of whether the economic participation rate of married women will increase if the gender gaps in wages, job findings and job losses among women and men are eliminated in the Iranian labor market. To answer this question using household expenditure and income data and labor force data, we show that between the two categories of occupations, in terms of the share of women's... 

    Semisolid Stir Joining of As-Cast Silicon-Aluminum Bronze

    , M.Sc. Thesis Sharif University of Technology Ferasat, Keyvan (Author) ; Kokabi, Amir Hossein (Supervisor) ; Ashuri, Hossein (Supervisor)
    Abstract
    Aluminum Bronzes have many applications in marine environments. These alloys suffer from both hot cracking and cold cracking. In order to overcome the hot cracking and cold cracking, Semisolid Stir Joining method and a proper thermal cycle was used respectively. Effects of temperature, stirring rate, and tool type were investigated in Semisolid Stir joining method. In this method, butt joint design was used in order to place specimens, and the specimens were heated up to specific temperatures (920, 925, 930°C). A stirrer (Cylindrical and Grooved tool) with three rotational speeds (800, 1200, 1600 RPM) was introduced into the stir weld seam. Welded specimens were cooled to the 900°C... 

    Differences in muscle synergies between healthy subjects and transfemoral amputees during normal transient-state walking speed

    , Article Gait and Posture ; Volume 76 , February , 2020 , Pages 98-103 Mehryar, P ; Shourijeh, M. S ; Rezaeian, T ; Khandan, A. R ; Messenger, N ; O'Connor, R ; Farahmand, F ; Dehghani Sanij, A ; Sharif University of Technology
    Elsevier B. V  2020
    Abstract
    Background: Lower limb amputation is a major public health issue globally, and its prevalence is increasing significantly around the world. Previous studies on lower limb amputees showed analogous complexity implemented by the neurological system which does not depend on the level of amputation. Research question: What are the differences in muscle synergies between healthy subjects (HS) and transfemoral amputees (TFA) during self-selected normal transient-state walking speed? Methods: thirteen male HS and eleven male TFA participated in this study. Surface electromyography (sEMG) data were collected from HS dominant leg and TFA intact limb. Concatenated non-negative matrix factorization... 

    Muscular activity comparison between non-amputees and transfemoral amputees during normal transient-state walking speed

    , Article Medical Engineering and Physics ; Volume 95 , 2021 , Pages 39-44 ; 13504533 (ISSN) Mehryar, P ; Shourijeh, M. S ; Rezaeian, T ; Khandan, A. R ; Messenger, N ; O'Connor, R ; Farahmand, F ; Dehghani Sanij, A ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    Research question: Would there be differences in muscle activation between healthy subjects’ (HS) dominant leg and transfemoral amputees’ (TFA) intact-leg/contralateral-limb (IL) during normal transient-state walking speed? Methods: The muscle activation patterns are obtained by calculating the linear envelope of the EMG signals for each group. The activation patterns/temporal changes are compared between-population using statistical parametric mapping (SPM). Results: Individual muscle activity showed significant differences in all muscles except vastus lateralis (VL), semitendinosus (SEM) and tensor fascia latae (TFL) activities. Significance: The information could be used by the therapists... 

    Circular colouring and algebraic no-homomorphism theorems

    , Article European Journal of Combinatorics ; Volume 28, Issue 6, August 2007, Pages 1843–1853 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Sharif University of Technology
    Abstract
    In this paper, we apply some new algebraic no-homomorphism theorems in conjunction with some new chromatic parameters to estimate the circular chromatic number of graphs. To show the applicability of the general results, as a couple of examples, we generalize a well known inequality for the fractional chromatic number of graphs and we also show that the circular chromatic number of the graph obtained from the Petersen graph by excluding one vertex is equal to 3. Also, we focus on the Johnson–Holroyd–Stahl conjecture about the circular chromatic number of Kneser graphs and we propose an approach to this conjecture. In this regard, we introduce a new related conjecture on Kneser graphs and we... 

    Density and power graphs in graph homomorphism problem

    , Article Discrete Mathematics ; Volume 308, Issue 17, 6 September 2008, Pages 4027–4030 Daneshgar, A. (Amir) ; Hajiabolhassan, Hossein ; Sharif University of Technology
    Abstract
    We introduce two necessary conditions for the existence of graph homomorphisms based on the concepts of density and power graph. As corollaries, we obtain a lower bound for the fractional chromatic number, and we set forward elementary proofs of the facts that the circular chromatic number of the Petersen graph is equal to three and the fact that the Coxeter graph is a core