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Metal complexes of non-symmetric tetradentate Schiff bases derived from n-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine
, Article Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry ; Volume 30, Issue 7 , 2000 , Pages 1393-1404 ; 00945714 (ISSN) ; Lashanizadegan, M ; Sharif University of Technology
Marcel Dekker Inc
2000
Abstract
Novel non-symmetrical tetradentate Schiff base complexes with N2O2 and N3O donor sites have been obtained using the half-unit N-(1-hydroxy-2-acetonaphthone)-1-amino-2-phenyleneimine (HL). Two reaction pathways have been used (i) preparation of the free ligand which is then reacted with the desired metal salt, and (ii) template synthesis without isolation of the free ligand. The prepared nickel and copper complexes have been characterized by elemental analyses, conductance, IR, UV, and 1H NMR spectroscopy