Sharif Digital Repository

Because of the importance of gas-solid fluidized beds in chemical industrial plants, many experimental and modeling efforts have been conducted the prediction of their behaviors up to now. Gas bubbles have a pivotal role in the hydrodynamics of bubbling gas-solid fluidized beds; so, fundamental understanding of the bubbling behavior of fluidized beds is required to describe bubble-related phenomena such as solids mixing and segregation, reaction conversion, heat and mass transfer, erosion of heat-transfer tubes and particle entrainment. In this work, the effects of different parameters such as bed aspect ratio, bed width, superficial gas velocity, and particle size distribution on the... 

Acidophilic microorganisms such as Thiobacillus ferrooxidans have the capability to carry out process of biorecovery of heavy metals. Its principle is the microbial production of the sulphuric acid and simultaneous recovery of metals. Acidithiobacillus ferrooxidans derives the energy for their metabolism from ferrous iron oxidation process which can be affected by the presence of heavy metals in the medium. In this study the ability of Acidithiobacillus ferrooxidans, on the biorecovery of heavy metals in shake flask has been investigated The adaptation of the Acidithiobacillus ferrooxidans to a kind of heavy metal such as Nickel, Cobalt, Vanadium, Molybdenum, Tungsten and the mixture of the... 

Reactive crystallization or precipitation is an important industrial process. Many chemicals and biochemicals such as catalysts and pigments are produced by precipitation. Because of the advantages of impinging jets in chemical engineering processes, the main aim of this research was to investigate the application of this method in precipitation and to study the effects of different operating and design parameters on the product’s quality and properties. Two chemical models of barium sulfate and copper oxalate were used as main products. Each of these chemicals was produced by a liquid-liquid reaction of two aqueous solutions, which were fed to an impinging-jets reactor. Effects of... 

In this work the transesterification reaction of waste cooking oil in the present of solid catalyst as a type of solid-liquid catalytic reaction, has been studied. For this purpose, two types of alkali solid catalysts were synthesized. CaO-ZrO2 and KOH/γ-Al2O3 catalysts were prepared by co-precipitation and impregnation method, respectively. These catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray fluorescence (XRF), BET surface area, and temperature programmed desorption of CO2 (TPD-CO2). The obtained results for the CaO-ZrO2 catalysts indicate that with increasing Ca/Zr atomic ratio, the activity of catalysts increases, but the stability... 

Analog to digital converters are one of the most important component of Bluetooth and GSM receivers. The pipeline and Successive Approximation Register (SAR) ADCs are mainly used in these receivers. However, the pipeline ADCs consume lots of power and SAR ADCs suffer the resolution in advanced technologies. On the other hand, the Delta-Sigma ADCs are capable of achieving high resolution with a low power. So in this thesis, the various kinds and different implementations of Delta-Sigma Modulators are introduced. The system level design and the conversion between Discrete-Time Modulators and Continuous-Time Modulators are explained. The non-ideality effects such as limited gain and bandwidth...