Sharif Digital Repository

In this study, 40% CaO/γ-Al2O3 catalyst was used for biodiesel production from corn oil. A transesterification reaction was done for 5h at a temperature of 65°C in the presence of corn oil, methanol (methanol to oil molar ratio of 12:1), and CaO/γ-Al2O3 catalyst (0.06g/g (6wt%)). Catalyst used in this study was synthesized using the sol-gel method. In this method, two parameters of gelation temperature and nitric acid concentration were used as variables in the catalyst synthesis step, and experiments were designed using central composite design (CCD). The results indicate that the optimal point is achieved at a gelation temperature of 70°C and... 

In this study, the artificial neural network (ANN) was used for the prediction of WDT. The inputs to network are molar mass and pressure, and the output is WDT at each input. A two-layer network with different hidden neurons and different learning algorithms such as LM, SCG, GDA and BR were examined. The network with 16 hidden neurons and Levenberg-Marquardt (LM) train function showed the best results in comparison with the other networks. Also, the predicted results of this network were compared with the thermodynamic models and better accordance with experimental data for ANN was concluded  

Transesterification reaction was performed in the presence of soybean oil, methanol, and Demineralized water plant sedimentation catalyst at 60°C for 8 h in this study. Central composite design method was used to study the effect of catalyst concentration and methanol to oil molar ratio on purity and yield of produced biodiesel. The results showed catalyst concentration of 9.08 wt% and methanol to oil molar ratio of 22.49 as the optimum condition in which the values of purity and yield of the produced biodiesel in the second-order models were 99.89% and 81.83%, respectively. Experiments are in good agreement with the mentioned values as corresponded values are 99.95% and 86.68%,... 

Chatter suppression is of great importance in machining processes for achieving more material removal rate, high precision and surface quality. In this paper, an H∞ control algorithm is proposed for chatter suppression in the presence of tool wear and parameter uncertainties. Orthogonal turning process is modelled as a single degree of freedom model that includes the effect of tool flank wear. Control input of the system is the force provided by a piezo-actuator.The turning process model includes the uncertainties in cutting velocity, tool wear and dynamic model parameters. Using the μ-synthesis technique, an H∞ optimal controller is designed based on a DK-iteration algorithm. The... 

Chatter suppression is an important topic in any type of machining process. In this paper, orthogonal cutting process is modeled as a single degree of freedom dynamic system. A nonlinear delay differential equation is presented that models flank wear of the tool. Uncertainties in cutting velocity, tool wear size and parameters of the dynamic model are included in the model of cutting process. The force provided by a piezo-actuator is taken as the control input of the system. A sliding mode control scheme is used and an effective control law is derived which suppresses the chatter vibration. Results for two distinct cases of a sharp tool and a worn tool are presented and compared which shows... 

Chatter suppression is an important topic in any type of machining process. In this paper, orthogonal cutting process is modeled as a single degree of freedom dynamic system. A nonlinear delay differential equation is presented that models flank wear of the tool. Uncertainties in cutting velocity, tool wear size and parameters of the dynamic model are included in the model of cutting process. The force provided by a piezo-actuator is taken as the control input of the system. A sliding mode control scheme is used and an effective control law is derived which suppresses the chatter vibration. Results for two distinct cases of a sharp tool and a worn tool are presented and compared which shows... 

Using the unique pricing method of Tapsi, the second-largest ride-hailing company in Iran, we estimate the price elasticity of demand for Tapsi rides. Tapsi mechanically divides Tehran, the largest city of Iran, into 256 regions using a 16 × 16 matrix of straight lines, to implement surge pricing in response to excess regional demand or supply. Surge multiplier works for all ride requests within each region, independent of supply and demand in neighboring regions or rides characteristics. We exploit this sharp discontinuity in pricing by running a regression discontinuity to estimate the causal effect of the price change on the number of ride requests, i.e., price elasticity of demand. Using... 

In this paper, bifurcation analysis is performed for the nonlinear milling process under sub-harmonic resonance and regenerative chatter, with tool wear and process damping effects. Multiple-scales approach is used to construct analytical approximate solutions for non-autonomous parametrically excited equations of the system with time delay terms. The new bifurcation parameters are the detuning parameter (deviation of the tooth passing frequency from three times of the chatter frequency), damping ratio (affected by process damping) and tool wear width. Jump phenomenon and multi-values responses are observed in the first order solution under sub-harmonic resonance condition. Periodic,... 

In this paper, the occurrence of various types of bifurcation including symmetry breaking, period-doubling (flip) and secondary Hopf (Neimark) bifurcations in milling process with tool-wear and process damping effects are investigated. An extended dynamic model of the milling process with tool flank wear, process damping and nonlinearities in regenerative chatter terms is presented. Closed form expressions for the nonlinear cutting forces are derived through their Fourier series components. Non-autonomous parametrically excited equations of the system with time delay terms are developed. The multiple-scale approach is used to construct analytical approximate solutions under primary... 

In this paper, internal resonance and nonlinear dynamics of regenerative chatter in milling process is investigated. An extended dynamic model of the peripheral milling process including both structural and cutting force nonlinearities is presented. Closed form expressions for the nonlinear cutting forces are derived through their Fourier series components. In the presence of the large vibration amplitudes, the loss of contact effect is included in this model. Using the multiple-scales approach, analytical approximate response of the delayed nonlinear system is obtained. Considering the internal resonance dynamics (i.e. mode coupling), the energy transfer between the coupled x-y modes is... 

This paper deals with the problem of chatter suppression in milling process in order to achieve higher precision, better surface quality and larger material removal rate (MRR). The peripheral milling process is modeled as a two degrees of freedom system and the effects of tool wear and process damping are considered. It is shown that when regenerative chatter develops, both tool wear and process damping act as stabilizing factors. For larger values of depth of cut and consequently higher MRR, tunable vibration absorbers (TVA) (in x-y directions) are designed to improve stability. An optimal algorithm is developed which determines the optimum values for absorbers' parameters. The effects of... 

In this paper, an extended dynamic model of peripheral milling process including process damping, structural and cutting force nonlinearities is presented. Cutting forces are described through a third-order polynomial function of chip thickness while a cubic nonlinear function is considered for the structural stiffness. Under stable and regenerative chatter conditions and using Fourier series components, closed form expressions for the nonlinear cutting forces are derived. Parameters of the proposed model are identified through a set of experiments. For this purpose, modal experiments and measurement of cutting forces (at various feed rates) are performed to determine the modal parameters... 

Peripheral milling is extensively used in manufacturing processes, especially in aerospace industry where end mills are used for milling of wing parts and engine components. Knowledge of the cutting forces is the first necessary stage in analysis of the milling process. In this paper, cutting forces are presented for both two and three dimensional models. Instead of the common linear dependency of cutting forces to the cut chip thickness, two nonlinear models are presented. In the first model, cutting forces are considered as a function of chip thickness with a complete third order polynomial. In the second one, the quadratic and constant terms of the third order polynomial are set to zero.... 

We have constructed a spherically symmetric structure model in a cosmological background filled with perfect fluid with non-vanishing pressure as an exact solution of the Einstein equations using the LemaѤtre solution. To study its local and quasi-local characteristics, including the novel features of its central black hole, we have suggested an algorithm to integrate the equations numerically. The result shows intriguing effects of the pressure inside the structure. The evolution of the central black hole within the FRW Universe, its decoupling from the expanding parts of the model, the structure of its space-like apparent horizon, the limiting case of the dynamical horizon tending to a... 

Using the unique pricing method of Tapsi, the second-largest ride-hailing company in Iran, we estimate the price elasticity of demand for Tapsi rides. Tapsi mechanically divides Tehran, the largest city of Iran, into 256 regions using a 16 × 16 matrix of straight lines, to implement surge pricing in response to excess regional demand or supply. Surge multiplier works for all ride requests within each region, independent of supply and demand in neighboring regions or rides characteristics. We exploit this sharp discontinuity in pricing by running a regression discontinuity to estimate the causal effect of the price change on the number of ride requests, i.e., price elasticity of demand. Using... 

In this paper, thermo mechanical finite element analysis of orthogonal machining process with a flexible tool is carried out to study the dynamic behaviour of the machining system and its stability against chatter vibration. By combining the simulation of chip formation in metal cutting with the dynamic phenomena leading to chatter development, the influence of various phenomena, including thermal effects resulting from friction and plastic deformations on the stability of the process are investigated. The novelty of this model is in its ability to evaluate the effect of temperature rise in the cutting zone on the stability of cutting process. Process stability is analyzed and compared for... 

The radical chlorination of polyethylene was carried out in perchloroethylene solvent using chlorine gas and ultraviolet photoradiation to investigate a reaction kinetics model. The recurrent structure of chloromethylene (-CHCl-) and methylene (-CH 2 -) groups and the percentage of substituted chlorine were determined using hydrogen-nuclear magnetic resonance (H-NMR) (500 MHz) spectra. A kinetics model has been proposed for this reaction in which the conversion of methylene (-CH 2 -) units to chloromethylene (-CHCl-) units was considered to be the main reaction step. The simplified version of the obtained kinetics model indicates that the reaction is first order with respect to the chlorine... 

Dynamic vibration absorbers are used as semi-active controllers to reduce the undesirable vibrations in many applications such as electrical transmission lines, helicopters, gas turbines, engines, bridges and etc. One type of these absorbers is tunable vibration absorber (TVA). In this paper, regenerative chatter in an orthogonal turning process is suppressed using a (TVA). It is shown that TVA can modify the frequency response function of the cutting tool so as to improve cutting stability in turning process. In addition, tool wear is an important factor which works as a positive damping and helps the chatter suppression beside exertion of the TVA. Finally, using the SIMULINK Toolbox of... 

Dynamic vibration absorbers are used as semi-active controllers to reduce the undesirable vibrations in many applications such as electrical transmission lines, helicopters, gas turbines, engines, bridges and etc. One type of these absorbers is tunable vibration absorber (TVA). In this paper, regenerative chatter in an orthogonal turning process is suppressed using a (TVA). It is shown that TVA can modify the frequency response function of the cutting tool so as to improve cutting stability in turning process. In addition, tool wear is an important factor which works as a positive damping and helps the chatter suppression beside exertion of the TVA. Finally, using the SIMULINK Toolbox of... 

Dynamic vibration absorbers are used to reduce the undesirable vibrations in many applications such as electrical transmission lines, helicopters, gas turbines, engines, bridges and etc. One type of these absorbers is tunable vibration absorber (TVA) which can act as a semi-active controller. In this paper, by applying a (TVA), chatter vibration is suppressed during boring process in which boring bar is modeled as a cantilever Euler-Bernoulli beam. The optimum specifications of absorber such as spring stiffness, absorber mass and its position can be determined by developing an algorithm based upon mode summation method. Finally, using the SIMULINK Toolbox of MATLAB, the analog simulated...