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    Response surface analysis of photocatalytic degradation of methyl tert-butyl ether by core/shell Fe3O4/ZnO nanoparticles

    , Article Journal of Environmental Health Science and Engineering ; Vol. 12, issue. 1 , 2014 Safari, M ; Rostami, M. H ; Alizadeh, M ; Alizadehbirjandi, A ; Nakhli, S. A. A ; Aminzadeh, R ; Sharif University of Technology
    Abstract
    The degradation of methyl tert-butyl ether (MTBE) was investigated in the aqueous solution of coated ZnO onto magnetite nanoparticale based on an advanced photocatalytic oxidation process. The photocatalysts were synthesized by coating of ZnO onto magnetite using precipitation method. The sample was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and vibration sample magnetometer (VSM). Besides, specific surface area was also determined by BET method. The four effective factors including pH of the reaction mixture, Fe3O4/ZnO magnetic nanoparticles concentration, initial MTBE concentration and molar ratio of [H2O2]/ [MTBE] were optimized using response surface... 

    Adsorption and oxidation study on arsenite removal from aqueous solutions by polyaniline/polyvinyl alcohol composite

    , Article Journal of Water Process Engineering ; Volume 14 , 2016 , Pages 101-107 ; 22147144 (ISSN) Roghani, M ; Nakhli, S. A. A ; Aghajani, M ; Rostami, M. H ; Borghei, S. M ; Sharif University of Technology
    Elsevier Ltd 
    Abstract
    In this study, the Polyaniline/Polyvinyl Alcohol (PANi/PVA) composite was examined for arsenite (As(III)) removal from aqueous solution. The effect of several parameters including PVA concetration (0–5 g/L), pH (1–13), adsorbent dosage (0.5–6 g/L), contact time (0–120 min), initial As(III) concentration (0.5–100 mg/L), and As(III) oxidation were evaluated on the adsorption efficiency. The results indicated that PVA has an effective role in increasing adsorptive capacity of PANi, by changing its morphology and extending its active surface sites. The adsorption process was pH dependent and As(III) removal consistently improved by increasing solution pH. Adsorption reached equilibrium within...