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navabi-shirazi--mohammad-ali
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Pulsating Pulmonary Blood Inflow in Total Cavopulmonary Connection (TCPC) after Fontan Surgery
, M.Sc. Thesis Sharif University of Technology ; Sayadi, Hassan (Supervisor) ; Firoozabadi, Bahar (Supervisor) ; Navabi Shirazi, Mohammad Ali (Co-Supervisor) ; Malakan Rad, Elaheh (Co-Supervisor)
Abstract
Patients with a single ventricle disease who have undergone Fontan surgery have always had long-term complications. These complications include pulmonary artery stiffness and decreased ability to exercise. In fact, due to removal of the right ventricle from the circulatory system, blood pressure and pulsatility inflow to total cavopulmonary connection (TCPC) are reduced following this surgery. Creating waves (radial displacement) on the IVC (Inferior Vena Cava) wall can increase pulmonary flow pulsations. The Objective of this study is to test the effect of induced wave amplitude on the pulmonary flow pulsations at the rest condition. Computational fluid dynamic (CFD) simulations were...
Synthesis and Characterization of ZnO/Fe3O4/N-Doped Reduced Graphene Oxide Photocatalyst as Photo-degradation Reagent for Dye Pollutant
, M.Sc. Thesis Sharif University of Technology ; Pourjavadi, Ali (Supervisor)
Abstract
Photocatalysts are compounds that can perform oxidation and reductions in the presence of light. One of the most known applications for photocatalyst is degrading organic contaminants in wastewater and making them harmless to the environment.In this project, a magnetic photocatalyst based on Fe3O4@ZnO/N-RGO has been synthesized and characterized with FT-IR, FE-SEM and EDS, XRD, and TGA. Moreover, photocatalytic dye degradation reactions for Rhodamine B, Methylene Blue, and Methyl Orange have been investigated and compared in the presence of Fe3O4@ZnO/N-RGO, Fe3O4@ZnO/RGO, Fe3O4@ZnO, and ZnO. Furthermore, the performance of the photocatalyst has been studied for 5 consecutive reactions and...
Atom Transfer Radical Polymerization of Acryl Amide in Reverse Suspension
, M.Sc. Thesis Sharif University of Technology ; Pourjavadi, Ali (Supervisor)
Abstract
Atom transfer radical polymerization (ATRP) is a convenient approach to synthesis of polymer with narrow molecular weight distribution. ATRP of acrylamide (AAm) is taken into consideration because of the intrinsic properties of acrylamide such as water solubility and biocompatibility. As reported in many recent works, polymerization of acrylamide by this method didn’t provide monomodal molecular weight distributions. In best condition with strong ligands such as Me4Cyclam, polymerization was carried out in a short time with high yield but polymerization was not highly controlled. It was shown that polymerization of acrylamide under typical ATRP condition displayed a much lower ATRP...
Evaluation of a novel extra-cardiac Fontan procedure with implantation of a biocompatible membrane
, Article IRBM ; Volume 36, Issue 5 , 2015 , Pages 287-292 ; 19590318 (ISSN) ; Firoozabadi, B ; Saidi, M. S ; Monjezi, M ; Navabi Shirazi, M. A ; Malakan Rad, E ; Sharif University of Technology
Elsevier Masson SAS
2015
Abstract
Fontan operation is a final palliative surgical treatment for patients with a single ventricle (SV) physiology. One of the common disadvantages of Fontan operation is to generate a non-pulsatile flow instead of the normal pulsatile flow produced by contraction of the ventricle. Theoretically, in SV patients, maintaining the antegrade flow through pulmonary valve can produce flow pulsatility in the right and left pulmonary arteries. However, it not only increases the energy loss in the Fontan of total cavopulmonary pathway (TCPC), but also imposes an extra load on pulmonary arteries as well as the ventricle. In this study, the potential capability of pulmonary valve of the patient that can be...
Pulsatile blood flow in total cavopulmonary connection: a comparison between Y-shaped and T-shaped geometry
, Article Medical and Biological Engineering and Computing ; Volume 55, Issue 2 , 2017 , Pages 213-224 ; 01400118 (ISSN) ; Firoozabadi, B ; Saidi, M. S ; Monjezi, M ; Navabi Shirazi, M. A ; Malakan Rad, E ; Sharif University of Technology
Springer Verlag
2017
Abstract
Single-ventricle anomaly is a hereditary heart disease that is characterized by anatomical malformations. The main consequence of this malformation is desaturated blood flow, which without proper treatment increases the risk of death. The classical treatment is based on a three-stage palliative procedure which should begin from the first few days of patient’s life. The final stage is known as Fontan procedure, in which inferior vena cava is directly connected to pulmonary arteries without going through the ventricle. This connection is called total cavopulmonary connection (TCPC). After surgery, the single ventricle supplies adequate and saturated systemic blood flow to the body; however,...
Numerical Analysis of Mechanized Tunneling Effects in Different Conditions on Internal Forces and Settlement of Superstructures
, M.Sc. Thesis Sharif University of Technology ; Ahmadi, Mohammad Mahdi (Supervisor)
Abstract
In this research with Finite Element Methods in ABAQUS, numerical modeling has done in three-dimensions, which can be used to determine the effect of different factors on the surface settlement. Also, various factors such as geotechnical conditions, tunnel diameter,tunnel depth, the impact of the thickness of the segments and the amount of eccentricity of the structure relative to the longitudinal axis of the tunnel considered in this study. Face Pressure Supports, and Grout Injection Pressures are taken into account, too.Tunnel drilling causes a change in the displacement area and creates a changing zone around the tunnel. In this regard, not only adjacent buildings will be affected by...
Reduction of Graphene Oxide by Polyphenols of Green Tea in the Presence of Oxidation of Transition Metals
, M.Sc. Thesis Sharif University of Technology ; Akhavan, Omid (Supervisor)
Abstract
In this research, we have used green tea polyphenols as green reductants for reduction of graphene oxide. Furthermore, for the first time, the presence of some metals such as iron, tungsten and copper in the efficiency of reduction is investigated. XPS spectra indicate that iron can be considered as one of the best choices for helping polyphenols in the reduction process. Hence, we used AFM, XPS, Raman spectroscopy and I-V diagram to characterize graphene oxide reduced by polyphenols and iron. In recent years, hydrazine has been recognized as one of the standard reducing agents for effective reduction of graphene oxide. In our analysis, it is found that the conductivity of our reduced...
Solving Toll Pricing Problem in Real Transportation Networks
, M.Sc. Thesis Sharif University of Technology ; Zokaee Aashtiani, Hedayat (Supervisor)
Abstract
Toll Pricing as a means to relieve traffic congestion has received significant attention by transportation planners recently. Inappropriate use of transportation networks is one of the major reasons that cause congestion in networks. Toll Pricing is a method of traffic management which guides the traffic flow to proper time and path in order to reduce the total delay in networks. This thesis investigates a method for solving Minimum Toll Revenue problem in real and large scale transportation networks. The objective of this problem is to find tolls that simultaneously cause users to use the transportation network effectively and minimize the total toll revenues that must be collected....
Simulation of Rapid Formation of Multicellular Spheroids in Double-emulsion Droplets with Controllable Microenvironment
, M.Sc. Thesis Sharif University of Technology ; Moosavi, Ali (Supervisor) ; Sadrhosseini, Hani (Supervisor)
Abstract
This study is aimed at simulation of double emulsion formation in a microfluidic double flow focusing device which consists of two cross-junctions connected serially. The water in oil (w/o) emulsions are produced in the first junction. In the second junction, water in oil emulsions are encapsulated by an outer aqueous phase to generate water in oil in water (w/o/w) double emulsions. Water in oil emulsions are formed in hydrophobic channels and water in oil in water double emulsions are formed in hydrophilic channels. A three phase numerical model, based on the VOF-CSF method, is developed for simulating the process of double emulsion formation. An adaptive mesh refinement technique is...
Preparation and Investigation of the Electrochemical Behavior of Sensors Modified with Reduced Graphene Oxide nanohybrids for Electrochemical Determinations of Some Biologically Important Compounds
, M.Sc. Thesis Sharif University of Technology ; Shahrokhian, Saeed (Supervisor)
Abstract
In the first work, a stable composite film of silver nanoparticles decorated on reduced graphene oxide is easily prepared. The surface morphology of the modified electrode is characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM) techniques. The electrochemical behavior of TNZ on the surface of the modified electrode is investigated by using linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). The prepared modified electrode acts as a highly sensitive platform for the voltammetric determination of tinidazole (TNZ). Voltammetric investigations demonstrated that, in comparison to the glassy carbon electrode individually coated with...
Modification of carbohydrate polymers via grafting in air. 1. Ceric-Induced synthesis of starch-g-polyacrylonitrile in presence and absence of oxygen [electronic resource]
, Article Starch - Starke ; Volume 54, Issue 3-4, pages 140–147, April 2002 ; Zohurian Mehr, Mohammad J
Abstract
Monomer grafting, a unique technique for polysaccharide modification, is always performed under inert (e.g., N2) atmosphere. This work is the first report related to evaluating the possibility and efficiency of the grafting of acrylonitrile (AN) onto starch in presence of oxygen. Thus, corn starch (in both granular and gelatinized states) as well as soluble starch were grafted by AN using a ceric-carbohydrate redox initiating system. Graft copolymerizations were performed under nitrogen, air, and oxygen atmospheres at similar conditions. Grafting occurrence was verified using chemical and spectral proofs. The polymerization mechanism and kinetics were investigated by recording the...
Modification of carbohydrate polymers via grafting in Air. 2. Ceric-Initiated graft copolymerization of acrylonitrile onto natural and modified polysaccharides [electronic resource]
, Article Starch - Stärke ; Volume 54, Issue 10, pages 482–488, October 2002 ; Zohuriaan-Mehr, Mohammad J
Abstract
Acrylonitrile (AN) was grafted onto various natural and modified polysaccharides (i.e., gum arabic, gum tragacanth, xanthan gum, sodium alginate, chitosan, sodium carboxymethyl cellulose, hydroxyethyl cellulose, methyl cellulose) by using ceric-carbohydrate redox initiating system. After overcoming practical problems, mainly from the high viscosity of the aqueous solutions of the different substrates, the graft copolymerization reactions were run either in air or in N2 atmosphere under similar conditions. Grafting was confirmed using chemical and spectral (FTIR) proofs. The reactions were kinetically investigated using semi-empirical expressions and time-temperature profiles. An anomalous...
Control of a Distributed Generation System Comprising Wind Turbine, Photovoltaic Array, and Fuel Cell in Standalone
Operation
,
M.Sc. Thesis
Sharif University of Technology
;
Zolghadri, Mohammad Reza
(Supervisor)
;
Karimi, Houshang
(Supervisor)
Abstract
On account of the exhausting nature and increasing daily cost of the fossil fuels, it seems that replacing the fossil fuels by an alternative source of energy is inevitable. Moreover, in the remote areas that the electricity network is not accessible, the use of distributed sources (DSs) such as solar energy and wind energy is advantageous. Continuity of the supply and voltage control of the load in spite of the stochastic nature of the generated power of the renewable energy resources are the main concerns in the distributed generation (DG) systems. In this thesis, stand-alone operation of a DG unit comprising a solar unit and wind turbine as primary sources of energy is considered. A...
Modeling of in Plane Behavior of Retrofitted Adobe Walls with Finite Element Method under Cyclic Loading
, M.Sc. Thesis Sharif University of Technology ; Bakhshi, Ali (Supervisor) ; Ghannad, Mohammad Ali (Co-Advisor)
Abstract
Statistical studies indicate the fact that in Iran, like many other developing countries, a significant percentage of buildings are made of traditional materials and most of them are adobe buildings especially in rural areas. Furthermore, geological data indicates that Iran is located in alps-Himalayas seismic zone and exposed by destructive earthquakes and adobe buildings suffer the most damages comparing with other type of the structures. According to these explanations, this research deals with adobe buildings behavior and provides solutions for reinforcing them and improving the seismic response of these buildings. These studies include numerical modeling with finite elements methods by...
Silica chloride/wet SiO2 as a novel heterogeneous system for the deprotection of acetals under mild conditions [electronic resource]
, Article Phosphorus, Sulfur, and Silicon and the Related Elements ; Volume 178:2667-2670, Issue 12, 2003 ; Pourjavadi, Ali ; Zolfigol, Mohammad Ali ; Bamoniri, Abdolhamid
Abstract
A combination of silica chloride and wet SiO2 was used as an effective deacetalizating agent for the conversion of acetals to their corresponding carbonyl derivatives under mild and heterogeneous condition
Evaluation of the Performance of Fluid Dampers in Controlling the Seismic-Induced Response of Structures
, M.Sc. Thesis Sharif University of Technology ; Rahimzadeh Rofooei, Fayaz (Supervisor)
Abstract
Natural disasters, such as earthquakes and hurricanes, can strike without warning, resulting in a range of destruction from structural damage to loss of life. For this reason, research on structural control, which provides a new basis for design of structural systems against winds, earthquakes, waves, and traffic loadings, become of interest in civil engineering. This thesis focuses on using fluid dampers as a passive energy dissipation device. Viscous Fluid Dampers (VFD) are the most commonly used passive energy dissipation devices that are manufactured in various forms. However, the orifice type of Viscous Fluid Damper (VFD) is considered for structural applications. In this thesis, the...
Evaluation of the photo-catalytic degradation of pyrene using fe-doped tio2 in presence of UV
, Article Desalination and Water Treatment ; Volume 169 , 2019 , Pages 232-240 ; 19443994 (ISSN) ; Borghei, S. M ; Haji Seyed Mohammad Shirazi, R ; Sharif University of Technology
Desalination Publications
2019
Abstract
The oil-based compounds are widely used in modern human life, and the accidental release or leakage of these compounds is led to water and soil pollution and creates many problems for the environment. The purpose of this study was to determine the efficiency of photo-catalytic degradation of pyrene using Fe-doped TiO2 in the presence of UV. This experimental study was carried out at laboratory scale in a 2 L pilot reactor. The nanoparticle was synthesized by the sol-gel method. Pyrene degradation was investigated under different conditions of pH, reaction time, nanoparticle concentration and pollutant concentration. For the statistical analysis, SPSS V.16 software and one-way analysis of...
Development of an electrochemical sensor based on (rGO-CNT) nanocomposite for raloxifene analysis
, Article Materials Chemistry and Physics ; Volume 263 , 2021 ; 02540584 (ISSN) ; Shahrokhian, S ; Navabi, M ; Sharif University of Technology
Elsevier Ltd
2021
Abstract
A novel modified electrode is reported for the electrochemical investigation of the oxidation mechanism and also voltammetric determination of raloxifene (RLX). The surface of the electrode was modified with a thin layer of reduced graphene oxide-carbon nanotube nano-composite (rGO-CNT) was prepared, and successfully employed for the electrochemical studies of RLX. The morphology of the sensor surface was characterized by using a scanning electron microscopy. RLX Oxidation response significantly increased at the GCE covered with rGO-CNT, regarding the bare and CNT or rGO functionalized GCE. Experimental parameters affecting the RLX response were optimized and mechanism of the RLX oxidation...
Distributed Fault-tolerant Computation for Massive Data
, M.Sc. Thesis Sharif University of Technology ; Maddah-Ali, Mohammad Ali (Supervisor)
Abstract
In this thesis we consider the problem of distributed computation by many processors.We mainly concentrate on matrix multiplication problem in this thesis because of its importance. A distributed system consists of N worker processors and one master processor. The master processor should distribute the computation between workers and after computation in each of them, collect the results. In this thesis, we are going to mitigate the effect of straggler processors by using coding methods. Straggler processors can cause delays in the computation time.In this thesis, we firstly introduce a method to multiply any number of matrices in each other. The proposed method occurred in one shot without...
Incomplete Reduction of Iron Ore in a Fluidized Bed Reactor
, M.Sc. Thesis Sharif University of Technology ; Halali, Mohammad (Supervisor)
Abstract
The main goal of current investigation was partial reduction of Fe2O3 available in Hematite-rich ore to Magnetite by Fludization Bed method. The reductive gas, CO, was produced by incomplete combustion of Acetylene and Airmixed in inappropriate ratio. X-Ray Diffraction and X-Ray Florescence analyses were implemented in order to conducting qualitative analysis of present phases before and after reduction of the ore. Quantitative analysis of the same phases was also conducted by Titration. The latter analysis revealed the precise magnitude of available iron in each of the oxide containing phases. The chemical composition of the reactor gas was also determined before and after reduction...