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    Manufacturing and Investigating of Nano carbon/Polyethylene Nanocomposites via In-situ Polymerization

    , M.Sc. Thesis Sharif University of Technology Sadrani, Alaleh (Author) ; Ramezani Saadatabdi, Ahmad (Supervisor)
    Abstract
    In this research UHMWPE/CB nanocomposites were prepared via in situ polymerization using Bi-supported Ziegler-Natta catalytic systems. Magnesium etoxide and carbon black were used as supports of catalyst. TiCl4 accompanied by triisobutyl aluminum and diisobutyl phthalate (DIBP) constituted Ziegler-Natta catalytic system. Preparation of catalyst and polymerization were done in slurry phase under the argon atmosphere. Then, structural, thermal and mechanical properties of produced nanocomposites with different CB content were evaluated by SEM, DSC, TGA, DMTA and tensile tests. Scanning Electron Microscopy (SEM) images also certified very good dispersion of CBs throughout PE matrix....