Sharif Digital Repository

Owing to the inherent incompatibility with water, cyanation of aryl halides may be the most challenging category of palladium-catalyzed coupling reactions. The major challenges are attributed to the catalyst deactivation by the soluble cyanide (CN−) ions and desirable conversions only could be obtained by employing toxic organic solvents. The current minireview highlights mechanistic insights and breakthrough achievements for this reaction in the aqueous media  

Fast fault detection (FD) and reconfiguration is necessary for fault tolerant power electronic converters in safety critical applications to prevent further damage and to make the continuity of service possible. The aim of this study is to minimize the number of the used additional voltage sensors in a fault tolerant three-phase converter. In this paper, first a practical implementation of a very fast FD scheme with reduced sensor number is discussed. Then, an optimization in this scheme is also presented to decrease the detection time. For FD, special time and voltage criterion are applied to observe the error in the estimated phase-to-phase voltages for a specific period of time. The... 

Due to unstoppable growth of social networks and the large number of users, the detection of communities have become one of the most popular and successful domain of research areas. Detecting communities is a significant aspect in analyzing networks because of its various applications such as sampling, link prediction and communications among members of social networks. There have been proposed many different algorithms for solving community detection problem containing optimization methods. In this paper we propose a novel algorithm based on extended distributed learning automata for solving this problem. Our proposed algorithm benefits from cooperation between learning automata to detect... 

Abstract: The current study deals with the applications of a surfactant-like Brønsted acidic ionic liquid (IL) 1-dodecyl-3-methylimidazolium hydrogen sulfate ([DMIm]HSO4) for Mannich reaction at room temperature. The reaction was efficiently preceded in water as solvent without using any harmful and expensive organic additives. Our findings showed that the reaction is selective for cyclohexanone and no Mannich product was observed when cyclopentanone was used as starting material. Density functional theory (DFT) calculations were performed to provide an evidence about the nature of reactivity of the cyclohexanone/cyclopentanone. The activity of the catalyst was also tested for biodiesel...