Sharif Digital Repository

The present study reports a simple electrochemical approach to the fabrication of a new nanocomposite containing PtPd nanoflowers (NFs) promoted with two-dimensional (2D) nanosheets (NSs) structure cuprous oxide (Cu2O) supported on reduced graphene oxide (rGO) (PtPd-NFs/Cu2O-NSs/rGO). Scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectra, Raman spectroscopy, and energy dispersive X-ray spectroscopy are used for characterization of the PtPd-NPs/Cu2O-NPs/rGO. SEM images showed that vertical-standing arrays of Cu2O with an edge length up to 1 μm and thickness of about 20 nm are electrodeposited on the surface of rGO film. Also, PtPd needle-like NFs with visible and... 

In the present work, N-doped hollow carbon nanospheres (N-HCNSs) is prepared by direct carbonization of polyaniline-co-polypyrrole (PACP) hollow spheres without template needing. Two different NiO nanostructures (nanosheets and nanowires) are prepared by forming a shell around the N-HCNSs via simple hydrothermal/calcination processes (NiO-NSs@N-HCNSs and NiO-NWs@N-HCNSs). The morphology and structure of the nanostructures are characterized using field emission scanning electron microscopy (FE-SEM), transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD). The prepared nanocomposites are used as catalysts for the electrocatalytic... 

Propagation of a Gaussian x-ray laser beam has been analyzed in collisionless thermal quantum plasma with considering a ramped density profile. In this density profile due to the increase in the plasma density, an earlier and stronger self-focusing effect is noticed where the beam width oscillates with higher frequency and less amplitude. Moreover, the effect of the density profile slope and the initial plasma density on the laser propagation has been studied. It is found that, by increasing the initial density and the ramp slope, the laser beam focuses faster with less oscillation amplitude, smaller laser spot size and more oscillations. Furthermore, a comparison is made among the laser... 

Propagation of Gaussian X-ray laser beam is presented in collisional quantum plasma and the beam width oscillation is studied along the propagation direction. It is noticed that due to energy absorption in collisional plasma, the laser energy drops to an amount less than the critical value of the self-focusing effect and consequently, the laser beam defocuses. It is found that the oscillation amplitude of the laser spot size enhances while passing through collisional plasma. For the greater values of collision frequency, the beam width oscillates with higher amplitude and defocuses in a shallower plasma depth. Also, it is realized that in a dense plasma environment, the laser self-focusing... 

In this work, we present the design and fabrication of a novel nanocomposite based on noble metal and metal oxide nanoparticles dispersed on highly porous carbon obtained via the pyrolysis of an inorganic complex and metal-organic frameworks. This nanocomposite is prepared by a two-step procedure: first, the composite support of nanoporous carbon (NPC) is obtained by the direct carbonization of the Cr-benzene dicarboxylic ligand (BDC) MOF in an Argon atmosphere at 500 °C (Cr2O3-NPC). A mixture containing Cr2O3-NPC and [PtCl(SnCl3)(SMe2)2] is then prepared, and underflow of Argon is heated to 380 °C. Finally, Pt-SnO2 nanoparticles are loaded on the Cr2O3-NPC support, and the obtained... 

The micromorphology and semiconductor properties of TiO2 thin films growth using different ion beam energies have been finely analyzed using atomic force microscopy (AFM), ultra-violet visible (UV–visible) spectroscopy and stereometric analysis. The AFM measurements and surface stereometric analysis are essential for the accurate characterization of the 3-D surface topographic features and allow the determination of the 3-D surface texture parameters that influence the optical properties of the material. The samples were divided into four groups to discuss the obtained results, according to the ion beam energy applied in the sample preparation. The results obtained from experimental... 

In this paper, we have successfully deposited Ag-Cu thin films. Nanoscale morphology and nanotexture were studied using atomic force microscopy (AFM) through fractal and stereometric parameters. Additional algorithms have been developed to study new fractal parameters such as surface entropy, fractal succolarity, and fractal lacunarity. The results revealed that as the deposition time increased, films exposed isotropies between ~65 and 82%, which were correlated to the fractal patterns, where from #3 to #5 there were greater spatial complexities. Moreover, surface roughness increased from #1 to #3, which was observed for both Sq and Sa. Similar behavior was exhibited by the other height... 

Among various two-dimensional carbon allotropes, graphyne has received extensive research attention with outstanding physical features and excellent application prospects for energy storage systems, specifically lithium-ion batteries anode. The mechanical characteristic of the anode affects the performance and durability of the battery during charge/discharge cycles. Therefore, this research investigates the mechanical properties of α -, β -, and γ -graphyne multilayer configurations using the molecular dynamics (MD) simulation approach. The results demonstrate that the mechanical properties of multilayer graphyne do not significantly depend on carbon layers; however, as the layer numbers... 

In this paper, we present two energy-efficient full adders (FAs) which are a crucial building block of nano arithmetic logic units (nano-ALUs) with the Cell Design Methodology (CDM). Since the most suitable design configuration for CNT-based ICs is pass transistor configuration (PTL), CDM which properly benefits from PTL advantages is utilized. So the designs herewith take full advantages of simplicity, fewer transistors and better immunity against threshold voltage fluctuations of the PTL than the CCMOS configuration. CDM also resolves two problems of PTL by employing elegant mechanisms which are threshold voltage drop and loss of gain. Using the amend mechanisms and SEA sizing algorithm... 

WO3 films with thicknesses between 550 and 853 nm were deposited on glass substrates using the electron beam evaporation method at room temperature. The microstructures and surface roughness of the films were studied by X-ray diffraction (XRD) and atomic force microscopy (AFM). It was observed that the crystalline structure of the WO3 thin films significantly changes from the amorphous to crystalline states with a crystalline texture, and the mosaicity and grain size dependent on the film thickness. The transmittance spectra of the obtained WO3 films were measured in the range from 340 to 850 nm, and the Swanepoel method was used to determine the refractive indices and the thicknesses of the... 

WO3 films with thicknesses between 550 and 853 nm were deposited on glass substrates using the electron beam evaporation method at room temperature. The microstructures and surface roughness of the films were studied by X-ray diffraction (XRD) and atomic force microscopy (AFM). It was observed that the crystalline structure of the WO3 thin films significantly changes from the amorphous to crystalline states with a crystalline texture, and the mosaicity and grain size dependent on the film thickness. The transmittance spectra of the obtained WO3 films were measured in the range from 340 to 850 nm, and the Swanepoel method was used to determine the refractive indices and the thicknesses of the... 

The morphology, structure and optical properties of zinc sulfide (ZnS) thin films prepared through radio-frequency (RF) magnetron sputtering have been analyzed using atomic force microscopy (AFM), UV–Vis–NIR spectrophotometry, X-ray diffraction, and multifractal analyses. The X-ray diffraction patterns revealed that all ZnS thin films show a single peak at around 29.6°, which has been ascribed to the (111) planes of sphalerite phase, indicating that the growth direction of the films is the [111] direction. UV–Vis–NIR transmittance spectra were used to determine the refractive index of the samples, their thickness, and their band gap energy, showing the optical and semiconductor properties a... 

The micromorphology of tantalum pentoxide (Ta2O5) thin films, deposited on glass substrates by electron gun method, has been analyzed using atomic force microscopy (AFM), UV–Vis–NIR spectrophotometry and multifractal analyses. Two samples were grown at basic pressure of 7 × 10−6 mbar, work pressures of 1.3 × 10−4 and 2.0 × 10−4 mbar, and thicknesses of 0.38 μm and 0.39 μm, respectively. Subsequently, these samples were annealed at 300 °C for 2 h. The physical, structural and optical analyses were investigated by spectroscopic ellipsometry, spectrophotometry and AFM. The measured transmittance spectra were studied based on the Swanepoel method, whose results also yielded to the estimation of...