Sharif Digital Repository

In the first section of the present thesis, a number of novel heterocycles were prepared; they include spirodihydropyridine, spiroindoline-2-thion, and pyrrolopyrimidines. The major advantages of the current investigation encompass high yields, short reaction times, mild reaction conditions and feasibility and low-cost materials. In the second section of this thesis, heterogeneous catalysts based on magnetic nanoparticles coated with organosilanes were synthesized. These catalysts were synthesized by hydrolysis of tetraethyl organosilanes and other organosilicons such as 3-aminopropyl triethoxy silane. The synthesized scaffolds were used to stabilize precious metals as Pd and Cu. The... 

Herein, cupric oxide (CuO)/graphitic carbon nitride (g-C3N4) is synthesized under microwave irradiation for enhanced photoelectrochemical (PEC) performance and photostability. A facile, one-pot method was utilized to directly deposit the nanocomposite onto FTO from a solution containing copper precursor and urea. Possible mechanisms of CuO/g-C3N4 formation and PEC performance improvement were examined via XRD, FTIR, FESEM, XPS, UV-Vis, and PL. Controlled amounts of urea determined the morphological evolution of CuO and the formation of a protective carbon layer, while its excess quantity converted to g-C3N4 in the presence of CuO. Through heat treatment of the nanocomposite, carbon-doped... 

Behavioral finance researchers have introduced behavioral biases, derived from psychology, to financial models in order to make them more realistic and to increase their explanatory power.One of the best known of these biases, considered in behavioral finance literature, is overconfidence, which means investors overestimate their own knowledge and ability to evaluate securities. Several theoretical models have studied the effects of this bias on financial markets and many empirical models have examined their assumptions, looking for whether investors are overconfident or not. Explained by these models, price overreaction to private information arrival and underreaction to public signal, is... 

In all five continents, existence of collapsible soils such as Loess has been reported. These kinds of soils have mutual properties such as open structure, high void ratio and low dry density. Collapsible soils are always at risk of experiencing significant reduction in volume due to increasing water content or degree of saturation. Hence, this kind of soil can lead to serious problems including reduce of load bearing capacity, excessive deformation and failure of foundations.Collapsible soils exist in several regions of Iran. Consequently, researching their properties is a key point of geotechnical studies in our country. Hence, in past 10 years, several studies have been conducted by... 

Cranioplasty is a surgical procedure for repairing skull defects. This surgery will protect the brain tissue, reduce pain in the lesion site and reduce the psychological burden on the patient. Cranioplasty implants should have distinct characteristics, i.e., high strength for protecting the brain, full coverage of skull defects, resistance to infection, non-expansion with heat, and reasonable price. Titanium implants, bone allografts, hydroxyapatite, and methyl methacrylate are commonly used in this surgery. However, these materials have many disadvantages that limit their use. As a result, biodegradable material and 3D printing technology are the next steps for designing scaffolds according... 

In the first part, preparation of different kinds of polypyrrole/carbon composites and their application for drug analysis are described. In the first work, A very sensitive electrochemical sensor constructed from a glassy carbon electrode modified with a layer-by-layer MWCNT/doped overoxidized polypyrrole (oppy/MWCNT /GCE) was used for the determination of acetaminophen (AC) in the presence of codeine and ascorbic acid (AA). In comparison to the bare glassy carbon electrode, a considerable shift in the peak potential together with an increase in the peak current was observed for AC on the surface of oppy/MWCNT/GCE, which can be related to the enlarged microscopic surface area of the... 

In this research, it has been trying to implement Virtual Structure method for formation flight of multiple spacecraft. In this method, a virtual solid frame with virtual center of mass is considered and agents are arranged in a formation with respect to the virtual center. In this work, a formation keeping control system is implemented in which a feedback from formation to virtual structure and vice versa is considered. The method is implemented firstly in a nongradient field and then developed into a circular orbit in order to investigate the in-orbital effects. An algorithm for collision avoidance, based on relative distances and relative velocities, was also developed. The algorithm was... 

Wall detection, as a part of scene understanding and indoor 3D modeling, can be used in robotic, architecture, and augmented reality. In robotic, scene analysis and understanding is knows as one of the main steps in robot navigation and simultaneous localization and mapping and walls need to be detected to form a 3D map of indoor environment. Ceiling and floor are also important elements of an indoor environment, therefore we can see our problem as a room layout estimation if we consider ceiling and floor. Using a deep learning structure, we estimate room layout in a semantic segmentation manner. Our approach is real-time. Our proposed method uses a deep fully-convolutional network, layout...