Sharif Digital Repository

The polysaccharide, kappa-carrageenan (κC) was chemically modified to achieve a novel superabsorbent hydrogel via graft copolymerization of methacrylamide (MAM) onto the substrate followed by alkaline hydrolysis. Ammonium persulfate (APS) and N,N′-methylene bisacrylamide (MBA) were used as a free-radical initiator and a crosslinker, respectively. The saponification reaction was carried out using sodium hydroxide aqueous solution. Either κC-g-PMAM or hydrolyzed κC-g-PMAM (PMAM: polymethacrylamide) was characterized by FT-IR spectroscopy. The effect of grafting variables (i.e. concentration of MBA, MAM, and APS) and alkaline hydrolysis conditions (i.e. NaOH concentration, hydrolysis time and... 

Infinite series solutions are obtained for electrical potential, electroosmotic velocity, ionic conductance, and surface physicochemical properties of long pH-regulated rectangular nanochannels of low surface potential utilizing the double finite Fourier transform method. Closed form expressions are also obtained for channels of large height to width ratio for which the depthwise variations vanish. Neglecting the Stern layer impact, the effects of EDL (Electric Double Layer) overlap, multiple ionic species, and association/dissociation reactions on the surface are all taken into account. Moreover, finite-element-based numerical simulations are conducted to account for the end effects as well... 

Semi-analytical solutions are obtained for the electrical potential, electroosmotic velocity, ionic conductance, and surface physicochemical properties associated with long pH-regulated nanochannels of arbitrary but constant cross-sectional area. The effects of electric double layer overlap, multiple ionic species, and surface association/dissociation reactions are all taken into account, assuming low surface potentials. The method of analysis includes series solutions which the pertinent coefficients are obtained by applying the wall boundary conditions using either of the least-squares or point matching techniques. Although the procedure is general enough to be applied to almost any... 

The dispersion of a neutral solute band by electrokinetic flow in polyelectrolyte layer (PEL)-grafted rectangular/slit microchannels is theoretically studied. The flow is assumed to be both steady and fully developed and a first-order irreversible reaction is considered at the wall to account for probable surface adsorption of solutes. Considering low electric potentials, analytical solutions are obtained for electric potential, fluid velocity and solute concentration. Special solutions are also obtained for the case without wall adsorption. To track the dispersion properties of the solute band, the generalized dispersion model is adopted by considering the exchange, the convection and the... 

A new type of collapsible soil was encountered in Southern Iran and caused some serious technical problems including subsidence, collapse and sinkholes during the construction of Zahedan-Chabahar railway. Field observations indicated that in-situ soil contains excessive amount of salts resulting in dispersive features in response to seepage forces in addition to its collapsibility. Therefore, a systematic research plan including field sampling and laboratory testing was carried out to investigate the observed geotechnical features. Results of physio-chemical tests revealed the dominance of Sodium in excess of 70% relative to total dissolved salts, which results in high dispersive potential.... 

Fluid flow in microchannels has some characteristics, which one of them is rarefaction effect related with gas flow. In the present work, hydrodynamically and thermally fully developed laminar forced convection heat transfer of a rarefied gas flow in two microgeometries is studied, namely, microannulus and parallel plate microchannel. The rarefaction effects are taken into consideration using first-order slip velocity and temperature jump boundary conditions. Viscous heating is also included for either the wall heating or the wall cooling case. Closed form expressions are obtained for dimensionless temperature distribution and Nusselt number. The results demonstrate that for both geometries,... 

In the present work, the second law of thermodynamics analysis has been carried out for steady-state fully developed laminar gas flow in a parallel plate microchannel with asymmetrically heated walls. The rarefaction effects as well as viscous heating effects are taken into consideration. Closed-form expressions are obtained for velocity and temperature distributions and entropy generation rates. The results demonstrate that increasing values of the wall heat fluxes ratio result in greater entropy generation for positive Brinkman numbers, whereas the opposite is true for negative values of Brinkman. However, the effect of the wall heat fluxes ratio on entropy generation becomes insignificant... 

This study investigates the influence of viscous dissipation on thermal transport characteristics of the fully developed combined pressure and electroosmotically driven flow in parallel plate microchannels subject to uniform wall heat flux. Closed form expressions are obtained for the transverse distributions of electrical potential, velocity and temperature and also for Nusselt number. From the results it is realized that the Brinkman number has a significant effect on Nusselt number. Generally speaking, to increase Brinkman number is to decrease Nusselt number. Although the magnitude of Joule heating can affect Brinkman number dependency of Nusselt number, however the general trend remains... 

The present investigation is devoted to the fully developed slip flow mixed convection in vertical microducts of two different cross sections, namely, polygon, with circle as a limiting case, and rectangle. The two axially constant heat flux boundary conditions of H1 and H2 are considered in the analysis. The velocity and temperature discontinuities at the boundary are incorporated into the solutions using the first-order slip boundary conditions. The method considered is mainly analytical in which the governing equations in cylindrical coordinates along with the symmetry conditions and finiteness of the flow parameter at the origin are exactly satisfied. The first-order slip boundary... 

This is a theoretical study dealing with longitudinal gaseous slip flow forced convection between a periodic bunch of microcylinders arranged in regular array. The selected geometry has applications in microscale pin fin heat sinks used for cooling of microchips. The flow is considered to be hydrodynamically and thermally fully developed. The two axially constant heat flux boundary conditions of H1 and H2 are considered in the analysis. The velocity and temperature discontinuities at the boundary are incorporated into the solutions using the first order slip boundary conditions. The method considered is mainly analytical in which the governing equations and three of the boundary conditions... 

The issue of entropy generation in laminar forced convection of a Newtonian fluid through a slit microchannel is analytically investigated by taking the viscous dissipation effect, the slip velocity and the temperature jump at the wall into account. Flow is considered to be hydrodynamically fully developed but thermally developing. The energy equation is solved by means of integral transform. The results demonstrate that to increase Knudsen number is to decrease entropy generation, while the effect of increasing values of Brinkman number and the group parameter is to increase entropy generation. Also it is disclosed that in the thermal entrance region the average entropy generation number... 

Engineering, procurement and construction (EPC) contracts are commonly used for the construction of oil and gas production facilities. These projects are subjected to many uncertainties. EPC contractors often assume most of the project risks. Several studies have focused on the identification and analysis of EPC project risks. However, they generally fail to define appropriate and effective risk management strategies. The objective of this study is to define efficient risk mitigation strategies that can be utilized in EPC oil and gas projects. A comprehensive review of literature was conducted to identify the risks in EPC projects. Experts' opinion were used to analyze and categorize these... 

The purpose of this study is to investigate production of high quality ammonium uranyl carbonate (AUC) from “uranyl nitrate + ammonium bicarbonate”, or “uranyl nitrate + sodium carbonate” precursor solutions, by controlled injection of ammonium carbonate solution which could be applicable in material testing reactor (MTR) fuel production plant for recycling of rejected uranium oxide powder. The experimental observations revealed: at pHs higher than 6, precipitation proceeds with formation of no intermediate, thus ensuing a better morphology and size distribution of the AUC products. The results of scanning electron microscopy, X-ray diffraction, particle size analysis, and uranium content... 

VO2(picolinichydrazone) complex as a catalyst was stabilized on a SBA-15 mesoporous silica as a catalytic support by using (3-chloropropyl)triethoxysilane as a connector. SBA-15 is nanoporous and has a high ratio of surface area to volume. The immobilization of a metal–Schiff base complex to the surface area of SBA-15 can improve its catalytic effects by increasing the catalytic surface area. Unlike homogeneous catalysts, heterogeneous catalysts can be recovered and reused several times without any significant loss of catalytic activity. A vanadium–Schiff base complex-functionalized SBA-15 was synthesized by covalency connected by a pre-synthesised VO2(picolinichydrazone) complex to... 

Fluid flow and heat transfer at microscale have attracted an important research interest in recent years due to the rapid development of microelectromechanical systems (MEMS). Fluid flow in microdevices has some characteristics which one of them is rarefaction effect related with gas flow. In this research, hydrodynamically and thermally fully developed laminar rarefied gas flow in annular microducts is studied using slip flow boundary conditions. Two different cases of the thermal boundary conditions are considered, namely: uniform temperature at the outer wall and adiabatic inner wall (Case A) and uniform temperature at the inner wall and adiabatic outer wall (Case B). Using the previously... 

Several lattice Boltzmann models for multi-phase flow have been developed, but few of them are capable of modeling fluid flows with high density ratio in the order of 1000. Therefore, an advanced chromodynamics, Rothmann-Keller (RK) type model is employed in current study, which can handle liquid-gas density ratio in the order of 1000 and viscosity ratio in the order of 100. Other distinctive characteristics of the proposed model are high stability, and capability of setting parameters such as surface tension independently. In spite of these benefits, the original RK model fails to model wetting tendency of the fluids. As a result, it is impossible to correctly simulate two-fluid phase flow... 

Cardiovascular diseases have been known as one of the main reasons of mortality all around the world. Nevertheless, this disease is preventable if it can be diagnosed in an early stage. Therefore, it is crucial to develop Clinical Decision Support Systems (CDSSs) that are able to help physicians diagnose the disease and its related risks. This study focuses on cardiovascular disease diagnosis in an Iranian community by developing a CDSS, based on Support Vector Machine (SVM) combined with Binary Particle Swarm Optimisation (BPSO). We used SVM as the classifier and benefited enormously from optimisation capabilities of BPSO in model development as well as feature selection. Finally,... 

In the present paper, a novel superabsorbent hydrogel composite based on gelatin have been prepared via graft copolymerization of acrylic acid (AA) in the presence of kaolin powder using methylenebisacrylamide (MBA) as a crosslinking agent and ammonium persulfate (APS) as an initiator. Certain variables of the graft copolymerization (i.e., the monomer, the initiator, and the crosslinker concentration as well as kaolin/gelatin weight ratio) affected on the ultimate water-swelling capacity were optimized. The composite structure was confirmed using Fourier transform infrared (FTIR) spectroscopy. A new absorption band at 1728 cm1 in the composite spectrum confirmed kaolinorganic polymer... 

In this article, a fault-tolerant adaptive neural network fractional controller has been proposed for a class of uncertain multi-input single-output (MISO) incommensurate fractional-order non-strict nonlinear systems subject to five different types of unknown input nonlinearities, infinite number of actuators failures and arbitrary independent time-varying output constraints. The barrier Lyapunov function (BLF)-based backstepping technique and fractional Lyapunov direct method (FLDM) have been used to design the controller and establish system stability. To tackle the incommensurate derivatives problem, in each step of the backstepping technique, an appropriate Lyapunov function has been... 

The electrokinetic energy conversion, electroviscous effect, and induced internal and external magnetic fields in a smart polyelectrolyte grafted "soft"nanopore with pH responsiveness are studied here using an efficient molecular theory approach. The analysis is based on writing the total free energy of the system, including the conformational entropy of the flexible, self-avoiding polymer chains and the translational entropy of the mobile species, the electrostatic interactions, and the free energy due to chemical equilibrium reactions. Then, the free energy is minimized, while satisfying the necessary constraints to find the equilibrium state of the system. The predictions of the model are...