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    A strategy for total recovery of residue from terephthalic acid production process

    , Article Russian Journal of Applied Chemistry ; Volume 88, Issue 7 , July , 2015 , Pages 1201-1206 ; 10704272 (ISSN) Rezaei, V ; Sajadi, S. A. A ; Sharif University of Technology
    Maik Nauka-Interperiodica Publishing  2015
    Terephthalic acid is generally produced via oxidation of p-xylene. In this process, a large quantity of residue is produced containing cobalt, manganese, and bromine catalysts as well as by-products such as benzoic acid. Our purpose is to totally recover this residue. Extraction by water has been used as an efficient method to recover catalyst from this residue. In this study, the best condition for extraction was obtained at water/residue dilution ratio of 6: 1, extraction temperature of 45°C and extraction time of 40 min. Efficiency of catalyst recovery was 92 wt % at these conditions. The catalyst containing extracted solution can be reused in the oxidation process after being... 

    Surveying the jagorood river's self-purification

    , Article 6th International Conference on Environmental Informatics, ISEIS 2007 ; 21-23 November , 2014 Nazari-Alavi, A ; Mirzai, M ; Sajadi, S. A. A ; Alamolhoda, A. A ; Sharif University of Technology
    the development and enlargement of city structure has caused the environmental problems on watershed of Latian dam which is one of the drinking water resourses of Tehran. The enlargement of Lavasan town and existence of an army garrison that it's effluents of treatment plant discharge to this river necessitate a water quality surveillance in entrance area of the dam. The present research includes the survey of this river's self-purification in the mentioned-above area. Numerical analysis is used in different methods to explain self- purification. Frist, we have the numerical analysis and analytical methods for a known sample in order to determine the accuracy and deviation between two... 

    Stabilities and isomeric equilibria in aqueous solution of monomeric metal ion complexes of adenosine 5′-diphosphate (ADP3-) in comparison with those of adenosine 5′-monophosphate (AMP2-)

    , Article Chemistry - A European Journal ; Volume 9, Issue 4 , 2003 , Pages 881-892 ; 09476539 (ISSN) Bianchi, E. M ; Sajadi, S. A. A ; Song, B ; Sigel, H ; Sharif University of Technology
    Under experimental conditions in which the self-association of the adenine phosphates (AP), that is, of adenosine 5′-monophosphate (AMP2-) and adenosine 5′-diphosphate (ADP3-), is negligible, potentiometric pH titrations were carried out to determine the stabilities of the M(H;AP) and M(AP) complexes where M2+=Mg2+, Ca2+, Sr2+, Ba2+, Mn2+, Co2+, Ni2+, Cu2+, Zn2+, or Cd2+ (25°C; I = 0.1m, NaNO3). It is concluded that in the M(H;AMP)+ species M2+ is bound at the adenine moiety and in the M(H;ADP) complexes at the diphosphate unit; however, the proton resides in both types of monoprotonated complexes at the phosphate residue. The stabilities of nearly all the M(AMP) and M(ADP)- complexes are...