Sharif Digital Repository

In this work we report fabrication of a nanocrystal (NC)-based hybrid organicinorganic LED with structure of ITO/PEDOT:PSS/PVK/CdS-NCs/(Al or Mg:Ag). The hydrophilic CdS NCs were synthesized using a novel aqueous thermochemical method at 80 °C and sizes (around 2 nm) were controlled by thioglycolic acid (TGA) as the capping agent. The favorite feature of these NCs is their relatively high emission intensity and broad, near-white emission. The hydrophilic CdS NCs were successfully spin coated using Triton X-100 as the wetting agent. The fabricated LEDs demonstrated a turn on voltage about 7 V for Al metallic contact. The electroluminescence was a broad spectrum at 540 and 170 nm width, which... 

In this study, the enhanced trichloroethylene (TCE) degradation performance was investigated by polyvinyl alcohol coated calcium peroxide nanoparticles (PVA@nCP) as an oxidant in Fe(II)-based catalytic systems. The nanoscale iron sulfide (nFeS), having an average particle size of 115.4 nm, was synthesized in the laboratory and characterized by SEM, TEM, HR-TEM along with EDS elemental mapping, XRD, FTIR, ICP-OES, and XPS techniques. In only ferrous iron catalyzed system (PVA@nCP/Fe(II)), TCE degradation was recorded at 58.9% in 6 h. In comparison, this value was increased to 97.5% or 99.7% with the addition of citric acid (CA) or nFeS in PVA@nCP/Fe(II) system, respectively. A comparative... 

In this study, the enhanced trichloroethylene (TCE) degradation performance was investigated by polyvinyl alcohol coated calcium peroxide nanoparticles (PVA@nCP) as an oxidant in Fe(II)-based catalytic systems. The nanoscale iron sulfide (nFeS), having an average particle size of 115.4 nm, was synthesized in the laboratory and characterized by SEM, TEM, HR-TEM along with EDS elemental mapping, XRD, FTIR, ICP-OES, and XPS techniques. In only ferrous iron catalyzed system (PVA@nCP/Fe(II)), TCE degradation was recorded at 58.9% in 6 h. In comparison, this value was increased to 97.5% or 99.7% with the addition of citric acid (CA) or nFeS in PVA@nCP/Fe(II) system, respectively. A comparative... 

The effect of bisulfite (HSO3–) in nCaO2/Fe(III)/HSO3– system on improving HO• generation and trichloroethene (TCE) removal was innovatively reported. The enhancement mechanism of HSO3– for TCE removal in nCaO2/Fe(III)/HSO3– system was caused not only by the complexing and reducing effects on promoting the conversion of Fe(III) to Fe(II), but also due to the reaction with O2 in water to produce SO4–• for accelerating TCE degradation. A double effect of nCaO2 as an oxidant source to generate HO• and as a O2 source to promote SO4–• generation was revealed. A pseudo-second-order kinetic model of TCE removal was determined and 94.6% TCE degradation was achieved within 60 min at the... 

The mechanism of surfactants in surfactant-in situ chemical oxidation (S-ISCO) coupled process for trichloroethene (TCE) degradation was firstly reported. The performance of TCE solubilization and inhibition of TCE degradation in three nonionic surfactants (TW-80, Brij-35, TX-100) in PS/Fe(II)/citric acid (CA) system was compared and TW-80 was evaluated to be the optimal surfactant in S-ISCO coupled process due to the best TCE solubilizing ability and minimal inhibition for TCE degradation (only 31.8% TCE inhibition in the presence of 1 g L−1 TW-80 surfactant). The inhibition mechanism in TCE degradation was also demonstrated by comparing the strength of ROSs and PS utilization. In the... 

The authors regret that during Proof of the article by Sun et al. [1], Fig. 6 and Fig. 7 were wrong. We reproduce below the relevant part of correct Fig. 6 and Fig. 7. Fig. 6. The concentration of SO42− in nCP/Fe(II)/FeS system. [nCP]0 = [Fe(II)]0 = 0.30 mM, [FeS]0 = 0.60 mM, [TCE]0 = 0.15 mM. [Figure presented] Fig. 7. Chloride ion liberation and its mass balance in nCP/Fe(II)/FeS system along with TCE degradation. [nCP]0 = [Fe(II)]0 = 0.30 mM, [FeS]0 = 0.60 mM, [TCE]0 = 0.15 mM. [Figure presented] © 2021 Elsevier B.V  

Animal models and traditional cell cultures are essential tools for drug development. However, these platforms can show striking discrepancies in efficacy and side effects when compared to human trials. These differences can lengthen the drug development process and even lead to drug withdrawal from the market. The establishment of preclinical drug screening platforms that have higher relevancy to physiological conditions is desirable to facilitate drug development. Here, a heart-on-a-chip platform, incorporating microgrooves and electrical pulse stimulations to recapitulate the well-aligned structure and synchronous beating of cardiomyocytes (CMs) for drug screening, is reported. Each chip... 

Carbonaceous materials (CMs) have been applied extensively for enhancing the catalytic performance of environmental catalysts, however, the self-catalytic mechanism of CMs for groundwater remediation is rarely investigated. Herein, we unveiled the catalytic ability of various CMs via Fe(III) reduction through polyvinyl alcohol-coated calcium peroxide nanoparticles (PVA@nCP) for trichloroethylene (TCE) removal. Among selected CMs (graphite (G), biochar (BC) and activated carbon (AC)), BC and AC showed enhancement of TCE removal of 89% and 98% via both adsorption and catalytic degradation. BET and SEM analyses showed a higher adsorption capacity of AC (27.8%) than others. The generation of... 

Carbonaceous materials (CMs) have been applied extensively for enhancing the catalytic performance of environmental catalysts, however, the self-catalytic mechanism of CMs for groundwater remediation is rarely investigated. Herein, we unveiled the catalytic ability of various CMs via Fe(III) reduction through polyvinyl alcohol-coated calcium peroxide nanoparticles (PVA@nCP) for trichloroethylene (TCE) removal. Among selected CMs (graphite (G), biochar (BC) and activated carbon (AC)), BC and AC showed enhancement of TCE removal of 89% and 98% via both adsorption and catalytic degradation. BET and SEM analyses showed a higher adsorption capacity of AC (27.8%) than others. The generation of... 

Hydroxyapatite (HA) coatings were deposited on commercially pure titanium plates using a hydrothermal-electrochemical deposition method in an electrolyte containing calcium and phosphate ions. The deposition conditions used in this study were the followings: electrolyte temperature (33-80 °C), current density (1-8 mA/cm2), and deposition time (10-120 min). Needle-like and granular crystals of apatite coating were created with different concentrations of calcium (0.0021-0.042 M) and phosphate (0.00125-0.025 M) salts. The size of HA crystals of the coating was considerably changed with different concentration of calcium and phosphate salts, temperature of the electrolyte, and deposition time.... 

The Under Frequency Load Shedding (UFLS) is the last automated action to restore power system frequency stability when a severe contingency causes a significant drop in the frequency of interconnection or islanded areas. In this paper, a novel probabilistic algorithm that considers the wind turbine frequency response is proposed to design and optimize the UFLS scheme. The uncertainties of power systems such as wind speed, hourly load, inertia time constant, and generation losses are taken into account. The Monte-Carlo Simulation (MCS) method is used to model the power system uncertainties. Additionally, a novel method is developed to calculate the power system frequency response and... 

Because of the compatibility with tandem devices and the ability to be manufactured at low temperatures, inverted perovskite solar cells have generated far-ranging interest for potential commercial applications. However, their efficiency remains inadequate owing to various traps in the perovskite film and the restricted hole blocking ability of the electron transport layer. Thus, in this work, a wide-bandgap n-type semiconductor, 4,6-bis(3,5-di(pyridin-4-yl)phenyl)-2-phenylpyrimidine (B4PyPPM), to modify a perovskite film via an anti-solvent method is introduced. The nitrogen sites of pyrimidine and pyridine rings in B4PyPPM exhibit strong interactions with the undercoordinated lead ions in... 

The accuracy of five soft computing techniques was assessed for the prediction of monthly streamflow of the Gilgit river basin by a cross-validation method. The five techniques assessed were the feed-forward neural network (FFNN), the radial basis neural network (RBNN), the generalised regression neural network (GRNN), the adaptive neuro fuzzy inference system with grid partition (Anfis-GP) and the adaptive neuro fuzzy inference system with subtractive clustering (Anfis-SC). The interaction between temperature and streamflow was considered in the study. Two statistical indexes, mean square error (MSE) and coefficient of determination (R2), were used to evaluate the performances of the... 

The simultaneous oxidation performance of benzene, toluene, ethylbenzene, and xylene (BTEX) by nanoscale calcium peroxide particles (nCaO2) activated with ferric ions (Fe(III)) and the mechanism of the enhancement of BTEX degradation by L-cysteine (L-cys) were investigated. The batch experimental results showed that the nCaO2/Fe(III)/L-cys process was effective in the destruction of BTEX in both ultrapure water and actual groundwater. A proper amount of L-cys could enhance BTEX degradation due to the promotion of Fe(II)/Fe(III) redox cycles by the participation of L-cys, but an excessive presence of L-cys would cause inhibition. Adding 1.0 mM L-cys to the nCaO2/Fe(III) system, the... 

Considering the quasi-brittle mechanical properties of concrete, wedge-splitting tests are employed and improved in this paper to study the fracture behaviour of concrete. A novel wedge-splitting device is designed by fixing ten springs on the force transmission component. The adaptive spring force can be imposed on top of a concrete specimen to retard the brittle fracture process. With the proposed wedge-splitting test design for notched cuboid specimens, the complete load–strain/CMOD curves of concrete can be generated directly. The fracture toughness and the fracture energy can be calculated easily without numerical fitting using the double-K fracture model. The descending branch of the... 

This paper aims to develop a deteriorated bridge maintenance strategy that ensures the safe operation of steel structures and minimizes the total risk. Five common failure modes are considered for the deteriorated bridge: flexure, shear, deflection, fatigue failure for girder, and chloride attack for the concrete deck. Time-dependent and system reliability analyses are carried out to find the probability of failure under these failure modes. Risk-cost optimization is then used to determine the maintenance strategy. This method was applied to a working example. It was found that the developed maintenance strategy can predict when, where, and what to maintain for a bridge to ensure its safe... 

This study tries to establish a powerful machine learning (ML) model for predicting the compressive strength of cement-based mortars by using dynamic elasticity data. The ML model was developed on the basis of Bayesian theorem, leading to a decrease in the overfitting problem compared with other conventional neural networks. Moreover, for the first time, the empirical equations were embedded in the ML model, enhancing the correlation between dynamic elasticity and compressive strength in the cement-based mortars. The results showed that the ML model efficiently predicted the compressive strength with determination coefficient (R2) of 95.2% and root mean square error (RMSE) of 0.0488 for... 

This paper analyzes the oligopolistic equilibria of multiple price-maker agents in performance-based regulation (PBR) markets. In these markets, there are price-maker agents representing some frequency regulation (FR) providers and a number of independent price-taker FR providers. A model of equilibrium problem with equilibrium constraints (EPECs) is employed in this paper to study the equilibria of a PBR market in the presence of price-maker agents and price-taker FR providers. Due to the incorporation of the FR providers' dynamics, the proposed model is reformulated as a mixed-integer linear programming (MILP) problem over innovative mathematical techniques. An optimal equilibrium point is... 

In process planning, determining feature's machining precedence is an essential step. The task becomes more difficult if features interact with each other, in which case the feature precedence information may suggest multiple machining sequences of the features. This paper considers interacting features in a feature-based model for process planning tasks. For each feature, precedence information is generated considering both roughing and finishing operations. A rule-based system is developed and implemented based on the information about machining precedence of the interacting features. The STEP-NC data model is used as the underlying data model. This model is object-oriented and compliant... 

This work deals with the robust D-stability test of linear time-invariant ( LTI ) general fractional order control systems in a closed loop where the system and - or the controller may be of fractional order. The concept of general implies that the characteristic equation of the LTI closed loop control system may be of both commensurate and non-commensurate orders, both the coefficients and the orders of the characteristic equation may be nonlinear functions of uncertain parameters, and the coefficients may be complex numbers. Some new specific areas for the roots of the characteristic equation are found so that they reduce the computational burden of testing the robust D-stability. Based on...