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    Fabrication of 3D Graphene/Gold Porous Electrode for Biosensing Applications

    , M.Sc. Thesis Sharif University of Technology Rahmati, Reza (Author) ; Simchi, AbdolReza (Supervisor) ; Tamjid Shabestari, Elnaz (Supervisor)
    Abstract
    Today, the use of carbon nanostructures hybridized with noble metals has attracted considerable attention for the fabrication of bio-electrochemical sensors. Since the specific surface area has an immense effect on the sensing response, three-dimensional structures of graphene have a great capability to utilize in these sensors. In this research, three-dimensional graphene was provided on the porous nickel foam by chemical vapor deposition technique. By evaluation of raman spectroscopy, the time period of 20 minutes for solving of the carbon atoms into the nickel foam was selected as the main parameter of optimized conditions for the synthesis of graphene. Afterward, production of few-layer... 

    Sensitive Detection and Quantification of Nitrite Ions by Metal-organic Frameworks/Gold Nanocomposites

    , M.Sc. Thesis Sharif University of Technology Mahdavi, Hossein (Author) ; Simchi, Abdoolreza (Supervisor) ; Tamjid Shabestari, Elnaz (Supervisor)
    Abstract
    Nitrite (〖NO〗_2^-) anions are ubiquitous within the physiological, industrial, environmental, and food industries. The potential toxicity risk of these inorganic compounds has well been recognized; thus, the precise detection of these ions by developing reliable and high-throughput analytical methods is crucial for health and environment security. In this study, we present a reagentless electrochemical biosensor using cobalt-based metal-organic frameworks (ZIF-67) and gold nanoparticles (Au NPs) for determination of nitrite ions. The developed biosensor provides the advantages of MOF properties including high surface area, hierarchical porosity, and tunable functionalities along with high... 

    Bio-inspired nanostructured sensor for the detection of ultralow concentrations of explosives [electronic resource]

    , Article Journal of Angewandte Chemie International Edition ; 29 May 2012, Volume 51, Issue 22, P.5334-5338 Dourandish, M. (Mahdi) ; Simchi, A. (Abdolreza) ; Tamjid Shabestary, Elnaz ; Hartwig, Thomas ; Sharif University of Technology
    Abstract
    TNT: Silicon microcantilevers modified with a three-dimensional layer of vertical titanium dioxide nanotubes can be used in micromechanical sensors with optical signal detection to detect low levels of explosives such as 2,4,6-trinitrotoluene (TNT) in the gas phase, even in the presence of other volatile impurities such as n-heptane and ethanol