Sharif Digital Repository

Pulse-potential coelectrodeposition of reduced graphene oxide/zinc (rGO-Zn) nanocomposite coating is directly controlled upon a steel substrate from a one-pot aqueous mixture containing [GO-/Zn2+]δ+ nanoclusters. GO nanosheets are synthesized by modified Hummer's approach while Zn cations are produced in the solution and deposited on GO nanosheets using anodic dissolution technique. Eventually, nanoclusters are reduced to rGO-Zn film through an electrochemical process. Chemical composition, surface morphology, and corrosion resistance of the thin film are characterized. Results show that the corrosion resistance of rGO-Zn coating is approximately 10 times more than the bare steel. © 2018 S.... 

Corrosion and time–dependent oxide film growth on AA5052 Aluminum alloy in 0.25M Na2SO4 solution containing H2O2 was studied using electrochemical impedance spectroscopy, potentiodynamic polarization, chronoamperometric and open circuit potential monitoring. It was found that sequential addition of H2O2 provokes passivation of AA5052 which ultimately thickens the oxide film and brings slower corrosion rates for AA5052. H2O2 facilitates kinetics of oxide film growth on AA 5052 at 25° and 60 °C which is indicative of formation of a thick barrier film that leads to an increment in the charge transfer resistance. Pitting incubation time increases by introduction of H2O2 accompanied by lower... 

This study attempts to find an optimum combination of the welding tool rotation rate (ω) and traveling speed (υ), concerning the corrosion and mechanical properties of Friction Stir Welded (FSWed) AA5052 Aluminum alloy. The effect of the tool speeds on the FSWed AA5052 are investigated via potentiodynamic polarization, open circuit potential (OCP) monitoring, test of the susceptibility to intergranular corrosion, weight loss, tension and micro-hardness tests. Optical microscope and Scanning Electron Microscopy (SEM) were employed for studying the morphology and analyzing the probable intergranular attacks. It was found that by increasing υ up to 200. mm/min at ω=400 rpm, the microstructural... 

Surface active sites of pulse reverse electrodeposited graphene oxide (PREGO) coating is optimized by design of experiments approach (central composite design). Applied current density (i), cathodic (Tc) and anodic (Ta) pulse durations, and total electrodeposition time (Tt) are selected to interpret the hydrogen evolution reaction (HER). The analyses of variance (ANOVA) are carried out on the outcomes of the designed experiments. A definitive linear relationship without any significant interaction was introduced as the best prediction model. Moreover, the results indicating the Ta and Tc are the most significant model terms. The best desirable value of the exchange charge on the cyclic... 

In this study, linear polarization resistance (LPR) of pulse reverse electrodeposited graphene oxide (PREGO) coating is optimized by design of experiments approach (central composite design). Pulse current density (i), cathodic (Tc) and anodic (Ta) pulse durations, and total electrodeposition time (Tt) are selected as the substantial factors. The best prediction model proposes a definitive linear relation without any significant interaction of the LPR by analysis of variance. The desirable value of LPR was predicted equal to 5358 Ω cm2, obtaining at the pulse current density of 235.62 mA cm−2, Ta of 7.75 ms, Tc equal to 3.25 ms (f = 100 Hz), and Tt of approximately 225 s. Appearance of the... 

Over the last decades, several approaches have been proposed in the literature to incorporate users' perceptions of travel costs, their bounded rationality, and risk-taking behaviors into network equilibrium modeling for traffic assignment problem. While theoretically advanced, these models often suffer from high complexity and computational cost and often involve parameters that are difficult to estimate. This study proposes an alternative approach where users' imprecise perceptions of travel times are endogenously constructed as fuzzy sets based on the probability distributions of random link travel times. Two decision rules are proposed accordingly to account for users' heterogeneous... 

Zeolitic imidazole frameworks (ZIFs) provide an exciting platform to design and fabricate non-precious-metal carbon-based catalysts for oxygen reduction/evolution reaction (ORR/OER). Herein, we elaborately design a facile enzyme-assisted synthetic strategy that enables to tailor the ZIFs precursors into structural stable decussation shape, which derived Co nanoislands grafted on decussate N-doped carbon nanoleaves (D-Co@NC) can well retain the interpenetrating nanostructure. Benefiting from the combined advantages of compositions and interpenetrating nanostructures, D-Co@NC possesses 5.2 times higher exposed electrochemical active area than the conventional dodecahedral one, thus endowing... 

In this paper, the interaction between various window specifications and different climate conditions is investigated. For this purpose, simultaneous effects of several aspects including glazing system, glass type, filling gas, glass thickness, window frame fraction, and interior shading are considered under three different climatic conditions. To evaluate the energy performance of various considered alternatives, the energy simulation of a base case building is evaluated in a computer environment. Using the validated model, the energy analysis is quantitatively performed, and cost-benefit analyses from the viewpoints of both residents and government are carried out based on the domestic and... 

Some tetra substituted derivatives of 2,2′ and 4,4′ bithiazoles have been synthesized and characterized in various solvents  

A mathematical time-dependent and isothermal model based on the grain model has been developed to simulate the kinetic and thermal behaviors of a porous iron oxide pellet undergoing chemical reactions with a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. Its novelty consists in fact that it can deal with a multi-species reducing gas and oxide pellet. In spite of previous models in which the pure reductant was applied as reducing gas, this model can indicate an actual view of pellet reduction including the effects of reducing gas utility and reducing gas ratio. A finite volume fully implicit technique was applied for solving the governing equations. The model has been... 

In the present study, for the first time, a thermodynamically consistent large deformation theory is developed to model the multi physics problem of axonal swelling which is the hallmark of most of the brain diseases. To this end, the relevant axonal compartments are first explained and the corresponding model parts are introduced. Next, the problem is formulated as an open thermodynamic system and the corresponding constitutive and evolution equations are extracted utilizing the balance laws. Here, a multiplicative decomposition of the deformation gradient is used to capture the active behavior of the axonal actin cortex. Specific free energy functions are given for the model parts to... 

Rockfall is a significant hazard to sites that are located at the foot of rock slopes. In such sites, there is a notable need to evaluate the potential for rockfall, estimate the extent of areas at risk, and design retaining structures to reduce the risk of rockfall-induced. This paper presents a probabilistic framework for predicting the formation and progression of rockfalls and for evaluating the performance of retaining walls under rockfalls. To this end, first a probabilistic model for the rock projectile motion on a slope is presented. The model accounts for prevailing uncertainties, i.e., the trigger points, rock shape, projectile path, and slope material properties, which include... 

We report here a newly and facile synthesis of the phospholipids@gold nanoflowers (AuNFs) from intact cells as a new biomimetic organic-inorganic hybrid. The most appealing feature of this nanostructure is its dual-absorbing peak in near infrared (NIR) and visible region of spectra, which makes them a potential light-sensitive agent for reactive oxygen species (ROS)-induced apoptosis. Here, in contrast to previous studies, proposed nanostructures are synthesized in a one-pot reaction using phospholipids present in living cell membranes (as a donor cell) with detectable micro process of AuNF formation. The properties of the resulting AuNFs were evaluated through transmission electron... 

We study the asymmetric primordial fluctuations in a model of inflation in which translational invariance is broken by a domain wall. We calculate the corrections to the power spectrum of curvature perturbations; they are anisotropic and contain dipole, quadrupole, and higher multipoles with non-trivial scale-dependent amplitudes. Inspired by observations of these multipole asymmetries in terms of two-point correlations and variance in real space, we demonstrate that this model can explain the observed anomalous power asymmetry of the cosmic microwave background (CMB) sky, including its characteristic feature that the dipole dominates over higher multipoles. We test the viability of the... 

This paper presents an effective control scheme in dc microgrids to precisely share the load current oscillatory and dc components among distributed generation (DG) units. The proposed control strategy includes current and voltage control blocks. The current control block consists of oscillatory and dc current-sharing units. The main idea of the proposed method is to share the load current oscillatory and dc components among the DG units based on their rated power, by assigning appropriate output impedance values and droop coefficients to each DG unit. The voltage control block is a multiloop voltage control unit employed to control the microgrid voltage. The detailed model of the proposed... 

NiTi alloys have exhibited significant potential as a matrix of wear resistant composites. In this study, in order to examine the effect of starting materials on the wear performance of NiTi-based composites, both elemental Ni/Ti and prealloyed NiTi powders were used to fabricate NiTi-6wt% nano-Al2O3 composites using hot isostatic pressing (HIP). Nanoindentation and microhardness test results indicate that the composite samples produced from the elemental Ni/Ti powders exhibited higher hardness and lower pseudoelasticity properties than those of the samples fabricated from the prealloyed NiTi powders; this is attributed to the higher amount of... 

The adhesion and mechanical properties of hydrogels used for vascular wound repair often deteriorate dramatically on wet surfaces, resulting in ineffective repair. In this work, a poly(N-isopropyl acrylamide-co-dopamine methacrylamide) nanogel with dopamine groups was synthesized and introduced into a polyacrylamide (PAAm) hydrogel to produce temperature-responsive hydrogels, which greatly improved mechanical and adhesive properties of PAAm hydrogels. Nanogel-reinforced PAAm (NR-PAAm hydrogel) can adhere to the surface of various solid materials and biological tissues through special physical interactions, which exhibited different mechanical and adhesion properties as temperature changes... 

Deployment of low-power low-cost small access points such as femtocell access points (FAPs) constitute an attractive solution for improving the existing macrocell access points' (MAPs) capacity, reliability, and coverage. However, FAP deployment faces challenging problems such as interference management and the lack of flexible frameworks for deploying the FAPs by the service providers (SPs). In this paper, we propose a novel solution that jointly associates the user equipment (UE) to the APs, and allocates the FAPs to the SPs such that the the total satisfaction of the UEs in an uplink OFDMA network is maximized. We model the competitive behaviors among the UEs, FAPs, and SPs as a dynamic...