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    Reaction kinetics determination and neural networks modeling of methanol dehydration over nano γ-Al 2O 3 catalyst

    , Article Journal of Industrial and Engineering Chemistry ; Volume 18, Issue 6 , 2012 , Pages 2059-2068 ; 1226086X (ISSN) Alamolhoda, S ; Kazemeini, M ; Zaherian, A ; Zakerinasab, M. R ; Sharif University of Technology
    2012
    Abstract
    In this research nano γ-Al 2O 3 catalyst was synthesized through precipitation process then characterized and utilized for methanol dehydration reaction in a slurry batch reactor in route to the indirect synthesis of the dimethyl ether (DME). In this venue, effects of the key parameters on methanol conversion and catalyst stability were investigated. Moreover, the internal and external mass transfer resistances were eliminated; hence the intrinsic kinetics controlled the reaction. Therefore, the optimum conditions for temperature, methanol concentration, catalyst mass and stirrer speed were determined to be 300°C, 1.18mol/l, 1.5g and 1100rpm, respectively. Next, different reaction rate...