Sharif Digital Repository

A telescoped approach was developed for the efficient synthesis of methoxybenzene through the generation of an unstable intermediate reagent, based on the Br-Li exchange reaction of p-bromoanisole and n-BuLi, followed by its reaction with water. In the first stage, p-methoxyphenyllithium was synthesized and consumed immediately in the second stage. For this purpose, an integrated glass microfluidic device was fabricated using laser ablation followed by the thermal fusion bonding method. The impact of various parameters, including solvent, reaction time, molar ratio, concentration of reagents, and flow rates were investigated to achieve the highest yield of the desired product, leading to an... 

This paper simulates Al2O3-water nanofluid flow and forced convection around a rotating circular cylinder. The governing parameters are Reynolds number (1 ≤ Re ≤ 100), solid volume fraction of nanoparticles (0 ≤ φ ≤ 0.05) and non-dimensional rotation rate (0 ≤ α ≤ 3). The simulations are performed to study the effects of mentioned parameters on the heat transfer rate and fluid flow characteristics. The governing equations including the continuity, momentum, and energy equations are solved with a finite volume method. It is observed that the reduction of heat transfer with increase in rotation rate is in the vicinity of 6.9% and 32% for Re = 5 and 100, respectively at φ = 0.05. Furthermore,... 

In the present study, a theoretical model of a reaction–diffusion within an entrapped-cell photobioreactor packed with gel-granules containing immobilized photosynthetic bacterial cells is presented. The model is based on a system of two coupled nonlinear reaction–diffusion equations under steady-state condition for biochemical reactions occurring in the photobioreactor that describes the substrate and product concentration within the gel-granule. Simple analytical expressions for the concentration of substrate and product have been derived for all values of reaction–diffusion parameters, demonstrating competition between the diffusion and reaction in the gel-granule, using the homotopy... 

Learning a foreign language encompasses a process of trial and error that can lead to the progression of the learner's interlanguage, meaning that the learners make use of their language knowledge that receives feedback and brings about progress through diagnosis of the problems and being corrected by the teacher. Therefore, there exists a need to analyze the underlying reasons causing the students to remain taciturn with a low willingness to communicate (WTC) during a language class. There has been much work done investigating the role of the learner's stable personal characteristics (traits) along with their situational changes at a specific time (states) that influence the student's... 

Using 3-D scanned data to analyze and extract pore network plays a vital role in investigation of porous media's characteristics. In this paper, a new simple method is developed to detect pores and throats for analyzing the connectivity and permeability of the network. This automated method utilizes some of the common and well-known image processing functions which are widely accessible by researchers and this has led to an easy algorithm implementation. In this method, after polishing and quality control of images, using city-block distance function and watershed segmentation algorithm, pores and throats are detected and 3-D network is produced. This method can also be applied on 2-D images... 

In this paper, we try to recognize and distinguish different groups of arrhythmia using novel features which have been obtained from the heart rate's phase space in recent years. For this purpose, we used Triangular Phase Space Mapping (TPSM) and Parabolic Phase Space Mapping (PPSM). For recognition, we used three groups of 15 subjects using the Physionet database (Arrhythmia, Congestive Heart Failure (CHF), and Atrial Fibrillation (AF)) with Normal Sinus Rhythm (NSR). The obtained features discriminate arrhythmia from NSR by p