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    Application of 3D gold nanotube ensembles in electrochemical sensing of ultra-trace Hg (II) in drinkable water

    , Article Surfaces and Interfaces ; Volume 10 , 2018 , Pages 27-31 ; 24680230 (ISSN) Bahari Mollamahale, Y ; Ghorbani, M ; Dolati, A ; Ghalkhani, M ; Sharif University of Technology
    Elsevier B.V  2018
    Abstract
    As a novel and highly sensitive sensor, three-dimensional gold nanoelectrode ensembles (3D GNE) prepared by gold deposition inside the parallel pores of a porous template have been successfully applied in electrochemical determination experiments. In this study, we report on the fabrication of 3D gold nanotubes (GNT) and their application in determination of Hg (II) in water. The morphology and crystal structure of the 3D GNT were characterized by field emission scanning electron microscope (FE-SEM) and X-ray diffraction (XRD), respectively. The sensitivity of the fabricated electrode towards Hg (II) was examined using anodic stripping voltammetry (ASV) as a powerful technique in... 

    Highly sensitive 3D gold nanotube ensembles: Application to electrochemical determination of metronidazole

    , Article Electrochimica Acta ; Volume 106 , 2013 , Pages 288-292 ; 00134686 (ISSN) Mollamahale, Y. B ; Ghorbani, M ; Ghalkhani, M ; Vossoughi, M ; Dolati, A ; Sharif University of Technology
    2013
    Abstract
    Three-dimensional gold nanoelectrode ensembles (3D GNE) have proven to be promising nanoelectrodes by representing much higher sensitivity compared to both their 2D nanostructures and bulk counterparts. The sensitivity of 3D gold nanotubes (GNTs) fabricated through electrodeposition inside the pores of polycarbonate templates, was examined toward metronidazole (MTZ) as one of their pharmaceutical applications. The electrochemical behavior of MTZ at the 3D GNT-modified electrode was discussed in detail through cyclic voltammetry (CV) which suggested an irreversible reduction of nitro group to the corresponding hydroxylamine and a subsequently reversible redox peak for the corresponding...