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    Optimization of some experimental parameters in the electro membrane extraction of chlorophenols from seawater

    , Article Journal of Chromatography A ; Volume 1216, Issue 45 , 2009 , Pages 7687-7693 ; 00219673 (ISSN) Lee, J ; Khalilian, F ; Bagheri, H ; Lee, H. K ; Sharif University of Technology
    2009
    Abstract
    An electro membrane extraction (EME) methodology was utilized to study the isolation of some environmentally important pollutants, such as chlorophenols, from aquatic media based upon the electrokinetic migration process. The analytes were transported by application of an electrical potential difference over a supported liquid membrane (SLM). A driving force of 10 V was applied to extract the analytes through 1-octanol, used as the SLM, into a strongly alkaline solution. The alkaline acceptor solution was subsequently analyzed by high performance liquid chromatography-ultraviolet (HPLC-UV) detection. The parameters influencing electromigration, including volumes and pH of the donor and...