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ac-impedance-spectroscopy
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PVDF/PU blend membrane separator for lithium-ion batteries via non-solvent-induced phase separation (NIPS)
, Article Journal of Solid State Electrochemistry ; Volume 25, Issue 8-9 , 2021 , Pages 2385-2394 ; 14328488 (ISSN) ; Fathollahi Zonouz, A ; Soltanieh, M ; Mousavi, S. A ; Sharif University of Technology
Springer Science and Business Media Deutschland GmbH
2021
Abstract
Membrane separator based on the polyvinylidene fluoride (PVDF) is prepared via the non-solvent-induced phase separation (NIPS) method with water and ethanol as non-solvent and a mixture of dimethylformamide (DMF) and acetone as solvent. The effect of various acetone/DMF ratios and non-solvent material on the physical and electrochemical properties of the separator is studied by FE-SEM, tensile strength, electrochemical AC-impedance spectroscopy (EIS), thermal stability, and linear sweep voltammetry (LSV). The charge-discharge studies are carried out by fabricating a lithium foil/polymer electrolyte membrane/LiFePO4 cell. The results show that with the change of solvent and non-solvent, the...
Al-doped Li7La3Zr2O12 garnet-type solid electrolytes for solid-state Li-Ion batteries
, Article Journal of Materials Science: Materials in Electronics ; Volume 32, Issue 5 , 2021 , Pages 6369-6378 ; 09574522 (ISSN) ; Golmohammad, M ; Soleimany Mehranjani, A. R ; Faghihi Sani, M ; Sharif University of Technology
Springer
2021
Abstract
Cubic phase Li7La3Zr2O12 (LLZO) is a promising solid electrolyte for next-generation Li-ion batteries. In this work, the combustion sol–gel technique is used to prepare an Al-doped LLZO solid electrolyte. The crystal structure is investigated, and the cubic phase is confirmed. Densification properties were investigated using SEM and optical dilatometry. The densification of the Al-doped sample takes place in two stages through two different shrinkage rates. Using 0.25 mol Al-dopant 94% relative density is achieved at 1100 °C. The effect of Al-doping on electrochemical properties is investigated in detail using AC impedance spectroscopy. The result indicates that the optimum concentration of...