Sharif Digital Repository

This study evaluates the effectiveness of adsorption process by Granular Activated Carbon (GAC) compared with a novel formulation of coagulation - flocculation process for dye removal from textile wastewater. In this regard, acidic, reactive, disperse and direct red dye are used to prepare the synthetic dye. Dominant wave length for each dye is determined by spectrophotometeric method. Using GAC as adsorbent, equilibrium time and adsorption isotherm of each dye are determined with aid of spectrophotometric method. The results show that GAC can not remove dispersed red dye. Acidic red, direct red and reactive red of 5 mg/L concentration are removed by GAC up to %90, %88 and %43 in 30, 60 and... 

In this study, the effect of adding walnut shell-based powdered activated carbon (WS) to a bench-scale dissolved air flotation (DAF) column on oil removal was investigated. All experiments were conducted using synthetically prepared wastewater containing low but stable concentrations of heavy fuel oil. After comparing the effect of different WS doses from 0 (blank) to 40 mg/L at the saturator pressure of 5 bar and 10 min flotation time, 20 mg/L WS was chosen as the optimal concentration. In order to find the best flotation time for efficient use of WS capacity, experiments were repeated with and without 20 mg/L WS at longer flotation times. According to the obtained results, by adding WS,... 

An efficient, novel functionalized supported magnetic nanoparticle (AC@Fe3O4-NH2-COOH) has been synthesized by co-precipitation method for removal of mercury ions from saline solutions. High dispersed supported magnetic nanoparticles with particle sizes less than 30 nm were formed over activated carbon derived from local walnut shell. Surface characterizations of supported magnetic nanoparticles were evaluated by Boehm test, Brunauer- Emmett-Teller (BET) surface area, X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and X-ray fluorescence (XRF). A three-layer artificial neural network (ANN) code... 

Activated carbon beds are extensively used in sweetening units of natural gas refineries for the purification of contaminated amine solutions. Correlation of experimental adsorption data using an analytical isotherm equation is need to design an accurate activated carbon bed. In the present study, the adsorption of BTEX from Diethanolamine (DEA) solution by commercial and granular activated carbon (AC) were performed. The Langmuir, Freundlich and Sips isotherm models were used to describe the equilibrium data. The accuracy of the results obtained from the adsorption isotherm models was compared and the values for the regressed parameters were reported. The results show that the Freundlich... 

Adsorption and desorption of methane by activated carbon (AC) at constant temperature and at various pressures were investigated. The effect of moisture was also studied. A volumetric method was used, up to 40 bar, at a temperature of 273.5 K. Results of a dry AC sample were compared with those obtained from a moist sample and two different ACs with different physical and surface properties were used. As expected, the results showed that the existence of moisture, trapped in the AC pores, could lead to a decrease in the amount of methane adsorbed and a decrease in the amount of methane delivered during desorption. To model the experimental results, a large variety of adsorption isotherms... 

A theoretical and experimental study was conducted to accurately determine the amount of adsorption and desorption of methane by various Granular Activated Carbon (GAC) under different physical conditions. To carry out the experiments, the volumetric method was used up to 500 psia at constant temperature of 25 °C. In these experiments, adsorption as well as desorption capacities of four different GAC in the adsorption of methane, the major constituent of natural gas, at various equilibrium pressures and a constant temperature were studied. Also, various adsorption isotherm models were used to model the experimental data collected from the experiments. The accuracy of the results obtained... 

Owning to interesting properties of biosurfactants such as biodegradability and lower toxicity, they have broad application in the food industry, healthy products, and bioremediation as well as for oil recovery. The present study was aimed to develop a GA-ANFIS model for predicting the breakthrough curves for rhamnolipid adsorption over activated carbon. To that end, a set of 296 adsorption data points were utilized to train the proposed FIS structure. Different graphical and statistical methods were also used to evaluate the model's accuracy and reliability. Results were then compared to those of the previously reported Artificial Neural Network (ANN) and Group Method Data Handling (GMDH)... 

Adsorption ability of prepared magnetic nanoparticles supported on activated carbon (AC-MNPs) was evaluated to synthesize an efficient and a low cost adsorbent for removal of Pb(II) and Cr(VI) ions from single and binary component aqueous solutions in the presence of salinity. Magnetic adsorbent was prepared by co-precipitation over activated carbon derived from almond shell by physical activation method. AC-MNPs was modified by oxygen containing functional groups to enhance the adsorption capacity of adsorbent. XRD, XPS, BET, Boehm, TEM, FT-IR, DLS and XRF were used to characterize the AC@Fe3O4@SiO2-NH2-COOH. Characterization analyses indicated the high dispersion of Fe3O4 crystallites on... 

The synthesis of cheap and environmental friendly adsorbent from residual sugarcane bagasse was done for the removal of naphthalene from aqueous solution. The activated carbon dot was obtained by KOH chemical activation of carbon dots. The characteristics of carbon dots and activated carbon dots were determined using field emission scanning electron microscopy, Fourier transform infrared spectroscopy, Raman spectroscopy, and thermogravimetric analysis. A series of experiments were conducted in a batch system to assess the effect of the system variables, i.e., initial pH, initial naphthalene concentration, adsorbent dosage, and contact time. The kinetic data showed better fit to the... 

The chitosan/poly vinyl alcohol membrane was modified by addition of some amine group to the membrane structure utilizing polyethyleneimine (PEI) in order to increase ionic metals adsorbent properties of the membrane. The removal percentage of the modified membranes was compared with the pristine membrane and activated carbon as common adsorbents. The membranes were characterized by FTIR, SEM, swelling degree and porosity measurement. The removal percentage of the membrane containing 0.5 wt.% PEI was more than 60% higher than the activated carbon and more than 40% higher than the pristine membrane. The modified membrane showed excellent adsorption capacity of 112.13, 86.08, and 75.5 mg/g for... 

Volatile organic compounds are a major cause of air pollution; therefore, VOCs are a serious fulmination for the environment. According to studies, adsorption processes have a high performance for the removal of pollutants that by selecting the proper absorbent, efficiency will be improved. In this work performance of two metal organic frameworks are studied so porous materials named MIL-101(Cr) and MIL-53(Fe) as an adsorbent for the removal of ethylbenzene have been synthesized hydrothermally. The materials were characterized by Fourier-transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) analysis, adsorption of ethylbenzene, field emission scanning electron microscopy (FESEM),...