Sharif Digital Repository

Many regulations have been introduced over the world to urge the elimination of lead and lead containing solders, due to increasing pressure of the environmental and health concerns associated with lead-containing solders in the electronics industry. Therefore, efforts to develop and promote lead-free soldering have recently intensified. Conventional solder technology may not guarantee the required performance at such pitches due to problems such as higher diffusivity and the softening nature of the solder. To solve these problems, efforts have been made to develop solders with a low melting point, higher strength, better microstructure properties, and high creep resistance. Recently... 

Ethylene is considered as one of the key materials in the petrochemical industry and has a particular importance. Polymerized ethylene produces polyethylene, which is widely used in plastics and pipe-manufacturing industries. Ethylene is mainly produced by the processes of catalytic cracking or thermal cracking of heavier hydrocarbon compounds. In these processes, acetylene is produced as a by-product, which deactivates the Ziegler-Nata catalysts in the polymerization unit of ethylene. Therefore, there should be some considerations to reduce acetylene to its minimum value -around zero. For this purpose, the fixed bed catalytic reactor is used to hydrogenate acetylene to ethylene. Various... 

In this research, direct synthesis of dimethyl ether (DME) from CO2 hydrogenation in three phase slurry reactor was investigated. Bifunctional catalysts composed of Cu- ZnO-Al2O3-ZrO2 as hydrogenation component and zeolite Na-Mordenite as dehydration component, with different Al2O3 and ZrO2 contents were synthesized by coprecipitating sedimentation and influences of Al2O3 and ZrO2 on CO2 conversion and DME selectivity were evaluated. Results show, both Al2O3 and ZrO2 enhanced conversion, but Al2O3 markedly increase selectivity of DME. However, when the total contents of Al2O3 and ZrO2 was increased up to 16 wt% , CO2 conversion and DME selectivity remarkably decreased. BET and XRD analyzes... 

Sometimes, some ceramics and metals cannot be produced in an integrated manner; In addition, ceramics, like metals, do not fully benefit from the properties of melting and casting; Therefore, it is necessary to produce this group of parts with other methods such as joining to each other. By using joining methods and technologies, it is possible to make composite materials; Therefore, in this way, the applications of ceramic or metal composites have been increasingly expanded. In many researches, bonding of oxide ceramics such as aluminum oxide to itself as well as carbide ceramics such as silicon carbide to itself have been investigated. In this research, the bonding mechanisms of two types... 

An impedimetric human papilloma virus (HPV) DNA biosensor based on gold nanotubes (AuNTs) in label free detection was materialized. The AuNTs decorated nanoporous polycarbonate (AuNTs-PC) template as biosensor electrode was fabricated by electrodeposition method. The single strand DNA (ss-DNA) probe was covalently immobilized onto the AuNTs-PC electrode. The hybridization of target sequences with the ss-DNA probe was observed by the electrochemical impedance spectroscopy (EIS). The biosensor showed high selectivity and could differentiate between the complementary, mismatch and non-complementary DNA sequences. The EIS measurements were matched to Randle's equivalent circuit. The... 

In this study, Al6063-Al203 nanocomposite powders were synthesized by reaction mechanical milling method. Nanometric reinforcement particles were formed via high- energy ball milling under a controlled oxygen containing atmosphere. Morphological and microstructural evolutions of nanocomposite powders were investigated by using X-ray diffraction (XRD), thermal analysis (DTA), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) methods at different milling times. The results showed that mechanical milling stages were accelerated and the time for reaching steady- state condition was decreased by an increase in the oxygen content in the milling atmosphere. The in-situ... 

Al 5083 is a non-heat treatable alloy that widely used in the aerospace and automotive industry due to its low density and high strength. However, poor wearing behavior and low elastic modulus restrict its engineering applications. Metal matrix composites (MMCs) have advantages of high strength and modulus by reinforcement of second phase. Also, MMCs have excellent dimensional stability, damping capacity and wear, creep and fatigue resistances as compared with the corresponding monolithic alloys. Vast loss in ductility and toughness occurs by non- deformable ceramic reinforcements. For the surface engineering purposes, ceramic particles are added in the surface layers of components, whereas... 

In some concrete projects, the consolidation of concrete is quite challenging due to the congestion of rebar and the complex concrete placement. Self-compacting concrete (SCC) can overcome these problems. On the other hand, nanomaterials in concrete can be used to improve the engineering properties of concrete and adverse environmental effects. This study uses aluminum-nano oxide and carbon-nano tubes (by replacing 1, 3, and 5% by weight of cementitious materials) to enhance the physical and mechanical properties of SCC. Additionally, adverse environmental effects of SCC improve by replacing 35% of cement with combustion furnace slag. Experimental results showed that with increasing... 

The present work focuses on the sustainable development of an intelligent self-healing anticorrosion coating using nanocontainers based on the aluminium oxide nanostructure-pomegranate peel extract-Ce3+ (Ce-PPE@Cat). The Ce-PPE@Cat nanopigment was introduced into the epoxy film (Ep) to achieve a smart barrier/ self-healing anti-corrosive property. To this end, a couple of characterization tests, including FT-IR, TGA, and, BET have been carried out to investigate the Ce-PPE@Cat nanopigment structure/composition. The effectiveness of the anti-corrosion performance of the established coatings was confirmed by EIS, FE-SEM, and accelerated salt spray test. Furthermore, EIS studies revealed that...