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amine-catalysts
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Application of thionine-nafion supported on multi-walled carbon nanotube for preparation of a modified electrode in simultaneous voltammetric detection of dopamine and ascorbic acid
, Article Electrochimica Acta ; Volume 52, Issue 22 , 2007 , Pages 6310-6317 ; 00134686 (ISSN) ; Zare Mehrjardi, H. R ; Sharif University of Technology
2007
Abstract
A modified carbon-paste electrode (CPE) is prepared by incorporating thionine-nafion supported on multi-walled carbon nanotube (MWCNT). The electrochemical behavior of dopamine (DA) and ascorbic acid (AA) on the surface of the modified electrode is investigated by cyclic voltammetry (CV). The results show that thionine effectively immobilized in the matrix of the paste by using an appropriate mixture of nafion/MWCNT under the ultrasonic condition. On the other hand, presence of nafion enhances the stability of the thionine supported by MWCNT in the composite electrode and improves the reproducibility of the surface of the modified electrode under renewing process by polishing. The results of...
Highly efficient one-pot three-component mannich reaction under solvent-free conditions
, Article Scientia Iranica ; Volume 16, Issue 2 C , 2009 , Pages 94-98 ; 10263098 (ISSN) ; Ebrahimi, F ; Saidi, M. R ; Sharif University of Technology
2009
Abstract
A mild and practically-convenient one-pot procedure for the direct Mannich reaction has been developed using a condensation of amines, aldehydes and unmodified ketones under solvent free conditions in the presence of Znl 2 with good to excellent yields. The present methodology offers several advantages, such as excellent yields, simple procedures, short reaction times and milder conditions with very small amounts of catalyst. Furthermore, it is the first time that the catalytic activity of several catalysts under solvent free conditions has been studied. It was found that both the diastereoselectivity and the rate of reaction were improved with various Lewis acids and metal oxides. However,...
Investigation of the Performance and Properties of a New Generation Additives with Dual Purpose, Cell Opening and Delay Action Catalyst; in MDI and Polyester Polyol Based PU System
, M.Sc. Thesis Sharif University of Technology ; Shojaei, Akbar (Supervisor) ; Moghimi, Abolghasem (Co-Supervisor)
Abstract
Polyurethanes are polymers prepared by the reaction of polyols with isocyanates. Due to the wide range of raw materials from which polyurethanes are synthesized, as well as their various applications, they are classified into several groups, of which polyurethane foams are one of the most important products that have significant consumption. One of the most important diisocyanates is methylene diphenyl diisocyanate and also one of the most commonly used polyols in the polyurethane industry are polyesters.In addition, chain extenders, catalysts and suitable additives such as foaming agents, surfactants, fillers, etc., are all raw materials that participate in the production of polyurethane...
Morphological investigations of nanostructured V2O5 over graphene used for the ODHP reaction: From synthesis to physiochemical evaluations
, Article Catalysis Science and Technology ; Volume 5, Issue 2 , Sep , 2015 , Pages 910-924 ; 20444753 (ISSN) ; Kazemeini, M ; Khorasheh, F ; Rashidi, A. M ; Sharif University of Technology
Royal Society of Chemistry
2015
Abstract
Oxidative dehydrogenation of propane (ODHP) in a fixed-bed reactor over synthesized vanadia nanocatalysts was investigated physicochemically. Several vanadium pentoxide (V2O5) nanostructures including rod-, belt-, tube-, needle- and flower-like forms were successfully synthesized via reflux and hydrothermal processes utilizing different templates such as monoamines, diamines, aromatic and alcoholic amines. The morphologies of the obtained products were found to be sensitive to the types of templates used. Nanorods obtained were 1.4 μm in length and about 97 nm in width while the VO2(B) nanotubes were of about 76 nm average diameter and up to 1.2 μm long. The diameters of the V2O5 nanotubes...
A highly reactive and magnetic recyclable catalyst based on silver nanoparticles supported on ferrite for n-monoalkylation of amines with alcohols
, Article Applied Organometallic Chemistry ; Volume 31, Issue 10 , 2017 ; 02682605 (ISSN) ; Shakourian Fard, M ; Nouri, P ; Mahmoodi Hashemi, M ; Sharif University of Technology
Abstract
Fe3O4@SiO2-Ag catalyst was found to be highly active and selective in the N-alkylation of amines with a variety of aromatic and linear alcohols. The heterogeneous nature of the Fe3O4@SiO2-Ag catalyst allows easy recovery and regeneration by applying an external magnet for six subsequent reaction cycles. The prepared catalyst was characterized using electron microscopy techniques, X-ray diffraction, vibrating sample magnetometry and atomic absorption spectroscopy. Copyright © 2017 John Wiley & Sons, Ltd
Nano cobalt-copper ferrite catalyzed regioselective α-C(sp3)–H cyanation of amines: Secondary, tertiary, and drug molecules
, Article Catalysis Communications ; Volume 149 , 2021 ; 15667367 (ISSN) ; Pourkaveh, R ; Heidarian, M ; Sharif University of Technology
Elsevier B.V
2021
Abstract
Oxidative cyanation of sp3C–H bonds at the α position of amines was achieved using CoCuFe2O4 as a catalyst and NaCN as an inexpensive cyanide source at room temperature. CoCuFe2O4 was found to be an active catalyst for Csp [3]-Csp coupling, efficiently delivering valuable α-aminonitriles from tertiary/secondary amines in good yields. The corresponding products were obtained with high selectivity toward α position. In addition, functional group tolerance offered the opportunity for application in late-stage functionalization of biologically active molecules. This transformation proceeds convenient on a gram-scale, and the catalyst can be reused for several runs with consistent catalytic...
Catalytic activity of TiO 2 nanotubes modified with carbon and Pt nanoparticles for detection of dopamine
, Article ECS Transactions ; Volume 35, Issue 35 , 2011 , Pages 53-62 ; 19385862 (ISSN) ; 9781607682950 (ISBN) ; Mahshid, S. S ; Ghahremaninezhad, A ; Askari, M ; Dolati, A ; Yang, L ; Luo, Sh ; Cai, Q ; Sensor; Organic and Biological Electrochemistry ; Sharif University of Technology
2011
Abstract
Catalytic activity of carbon/Pt nanoparticles modified TiO 2 nanotubes electrode was studied by using dopamine contained solutions. The TiO 2 nanotubes electrode was prepared using anodizing method in aqueous solution. The electrochemical pulse method was then applied for electrodeposition of Pt nanoparticles onto the TiO 2 nanotubes. Further modification was achieved by decomposition of polyethylene glycol in a tube furnace to have a carbon/Pt nanoparticles modified TiO 2 nanotubes electrode. The final modified electrode could successfully detect the electro-oxidation of dopamine in a ImM contained solution using cyclic voltametry method. Also, a high sensitivity towards the oxidation of...