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    Template-based electrodeposition of Pt/Ni nanowires and its catalytic activity towards glucose oxidation

    , Article Electrochimica Acta ; Volume 58, Issue 1 , 2011 , Pages 551-555 ; 00134686 (ISSN) Mahshid, S. S ; Mahshid, S ; Dolati, A ; Ghorbani, M ; Yang, L ; Luo, S ; Cai, Q ; Sharif University of Technology
    An electro-catalysis non-enzymatic electrode is proposed based on alloyed Pt/Ni nanowire arrays (NWAs) for the detection of glucose. The Pt/Ni NWAs were prepared by pulse electrodeposition of Pt and Ni within a nano-pore polycarbonate (PC) membrane followed by a chemical etching of the membrane. The electrode structure is characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The resulting Pt/Ni NWAs electrode shows high electrocatalytic activities towards the oxidation of glucose in alkaline solution. Consequently, a sensitive amperometric detection of glucose is achieved under 0.45 V vs. SCE with a low detection limit of 1.5 μM within a wide linear... 

    Bimetallic CoZn-MOFs easily derived from CoZn-LDHs, as a suitable platform in fabrication of a non-enzymatic electrochemical sensor for detecting glucose in human fluids

    , Article Sensors and Actuators B: Chemical ; Volume 344 , 2021 ; 09254005 (ISSN) Ataei Kachouei, M ; Shahrokhian, S ; Ezzati, M ; Sharif University of Technology
    Elsevier B.V  2021
    In the present study, an in-situ, two-step, highly controllable, fast, green, and facile strategy for fabricating the bimetallic cobalt-zinc-based metal-organic frameworks (MOFs) is employed for designing a non-enzymatic glucose sensing platform. The structural characterization, as well as the phase investigation of materials in each step, are assessed by X-ray diffraction, energy-dispersive X-ray spectroscopy, elemental mapping, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy. Furthermore, the electrocatalytic activity of the CoZn-BTC/GC fabricated electrode toward the electro-oxidation of glucose is examined by various electrochemical techniques,... 

    Microwave-assisted decoration of cotton fabrics with Nickel-Cobalt sulfide as a wearable glucose sensing platform

    , Article Journal of Electroanalytical Chemistry ; Volume 890 , 2021 ; 15726657 (ISSN) Hekmat, F ; Ezzati, M ; Shahrokhian, S ; Unalan, H. E ; Sharif University of Technology
    Elsevier B.V  2021
    Flexibility and human-body compatibility have been emerged through the use of commercial fabrics (CFs) in designing wearable non-enzymatic glucose sensing platforms. In this work, electrodes fabricated through direct synthesis of ternary nickel–cobalt sulfide nanostructures (Ni-Co-S NSs) on the CFs (Ni-Co-S@CFs) using a fast and facile one-step microwave-assisted method for this purpose. Fabrication was followed by the structural and electrochemical characterization of the electrodes. The glucose-sensing ability of the prepared wearable electrodes was investigated via cyclic voltammetry (CV) and amperometry techniques in alkaline media. Two linear-responses in wide detection ranges of... 

    Amine functionalized TiO2 coated on carbon nanotube as a nanomaterial for direct electrochemistry of glucose oxidase and glucose biosensing

    , Article Journal of Molecular Catalysis B: Enzymatic ; Volume 68, Issue 2 , 2011 , Pages 206-210 ; 13811177 (ISSN) Tasviri, M ; Rafiee Pour, H. A ; Ghourchian, H ; Gholami, M. R ; Sharif University of Technology
    A nano-composite material consisting of amine functionalized TiO 2-coated carbon nanotubes was prepared and used for glucose oxidase (GOx) absorption. The GOx bearing nanomaterial was fixed on a glassy carbon electrode to construct a novel biosensor for glucose determination. The direct electrochemistry of immobilized GOx and its electron transfer parameters at the modified glassy carbon electrode were reported. The apparent heterogeneous electron transfer rate constant (ks) of GOx was estimated to be 3.5 s-1, which is higher than those reported previously. Amperometric detection of glucose resulted in a rapid (3 s) and stable response in the linear concentration range from 1.8 to 266 μM.... 

    In situ two-step preparation of 3D NiCo-BTC MOFs on a glassy carbon electrode and a graphitic screen printed electrode as nonenzymatic glucose-sensing platforms

    , Article ACS Sustainable Chemistry and Engineering ; Volume 8, Issue 38 , 2020 , Pages 14340-14352 Ezzati, M ; Shahrokhian, S ; Hosseini, H ; Sharif University of Technology
    American Chemical Society  2020
    In the present study, a rational two-step strategy is employed for the green, fast, very simple, and highly controllable synthesis of the bimetallic nickel-cobalt-based metal-organic frameworks (MOFs) on glassy carbon substrates by in situ transformation of nickel-cobalt-layered double hydroxide nanosheet (NiCo-LDHs NSs) intermediates into nickel-cobalt-benzene tricarboxylic acid MOFs (E-NiCo-BTC MOFs). The structural characteristics of the electrode materials in each step were investigated via Fourier transform infrared spectroscopy, X-ray diffraction, energy dispersive X-ray spectroscopy, elemental mapping, field emission scanning electron microscopy, and transmittance electron microscopy.... 

    Fabrication of a sensitive and fast response electrochemical glucose sensing platform based on co-based metal-organic frameworks obtained from rapid in situ conversion of electrodeposited cobalt hydroxide intermediates

    , Article Talanta ; Volume 210 , 2020 Shahrokhian, S ; Ezzati, M ; Hosseini, H ; Sharif University of Technology
    Elsevier B.V  2020
    In this study, for the first time, we reported a fast and facile three-step in situ strategy for direct controllable growth of the Co3(BTC)2 MOFs thin films on the GCE, through the rapid conversion of the electrodeposited Co(OH)2 nano-flakes on rGO/GCE, to crystalline rectangular bar-shape structures of MOFs. X-ray diffraction spectroscopy, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy dispersive X-ray spectroscopy and elemental mapping analysis used to the structural and morphological characterization of the well-synthesized MOFs. The as-prepared Co3(BTC)2 MOFs were used to construct a non-enzymatic sensing platform for determining the glucose...