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amperometric-response
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Electrodeposition and electrocatalytic properties of Pt/Ni-Co nanowires for non-enzymatic glucose detection
, Article Journal of Alloys and Compounds ; Volume 554 , 2013 , Pages 169-176 ; 09258388 (ISSN) ; Mahshid, S ; Dolati, A ; Ghorbani, M ; Yang, L ; Luo, S ; Cai, Q ; Sharif University of Technology
2013
Abstract
A nanowire arrays system consisting of an ordered configuration of Pt, Ni and Co was constructed in single-bath solution through pulse electrodeposition. This structure was evaluated as a potential amperometric non-enzymatic sensor to detect glucose in alkaline solution. We observed a strong and fast amperometric response at low applied potential of 0.4 V vs. SCE over linear ranges of 0-0.2 mM and 0.2-8 mM glucose with sensitivities of 1125 and 333 μA mM-1 cm-2, respectively. We also observed a low detection limit for glucose of 1 μM. Correlation of the electronic and geometric modifications with the electrochemical performance characteristics enhanced catalytic activity of the electrode by...
Two nanostructured polymers: Polyaniline nanofibers and new linear-dendritic matrix of poly(citric acid)-block-poly(ethylene glycol) copolymers for environmental monitoring in novel biosensors
, Article International Journal of Polymeric Materials and Polymeric Biomaterials ; Volume 62, Issue 7 , Jul , 2013 , Pages 377-383 ; 00914037 (ISSN) ; Vossoughi, M ; Alemzadeh, I ; Naeini, A. T ; Darvish, M ; Sharif University of Technology
2013
Abstract
In this work two phenol biosensors, one based on polyaniline nanofibers (PNFs) and the other based on the newly created and introduced linear-dendritic matrix of poly(citric acid)-block-poly(ethylene glycol) copolymers (PCA-PEG-PCA), were chemically modified with horseradish peroxidase (HRP) enzyme. These phenol biosensors showed an oxidation peak at 0.55 V. The amperometric response for biosensors based on PNFs showed a linear response range from 2.5 × 10-6 to 2.5 × 10-5 mol/L, with a detection limit of 2.5 M phenol. Also, the amperometric response for a biosensor based on PCA-PEG-PCA showed a linear response range from 2.5 × 10-6 to 4 × 10-5 mol/L, with a detection limit of 1.5 M phenol
Synthesis, first-principle simulation, and application of three-dimensional ceria nanoparticles/graphene nanocomposite for non-enzymatic hydrogen peroxide detection
, Article Journal of the Electrochemical Society ; Volume 166, Issue 5 , 2019 , Pages H3167-H3174 ; 00134651 (ISSN) ; Hatamie, A ; Berahman, M ; Simchi, M ; Angizi, S ; Rahmati, R ; Kennedy, J ; Simchi, A ; Sharif University of Technology
Electrochemical Society Inc
2019
Abstract
Owing to the exceptional properties of graphene and the crucial role of substrate on the performance of electrochemical biosensors, several graphene-based hybrid structures have recently emerged, yielding improved selectivity and sensitivity. To date, most of the reported biosensors utilize solution-driven graphene flakes with drawbacks of low conductivity (due to high inter-junction contact resistant) and structural fragility. Herein, we present a conductive three-dimensional CeO2 semiconductor nanoparticles/graphene nanocomposite, as a platform for sensitive detection of hydrogen peroxide, an important molecule in fundamental biological processes. The 3D conductive graphene architecture is...
Synthesis, first-principle simulation, and application of three-dimensional ceria nanoparticles/graphene nanocomposite for non-enzymatic hydrogen peroxide detection
, Article Journal of the Electrochemical Society ; Volume 166, Issue 5 , 2019 , Pages H3167-H3174 ; 00134651 (ISSN) ; Hatamie, A ; Berahman, M ; Simchi, M ; Angizi, S ; Rahmati, R ; Kennedy, J ; Simchi, A ; Sharif University of Technology
Electrochemical Society Inc
2019
Abstract
Owing to the exceptional properties of graphene and the crucial role of substrate on the performance of electrochemical biosensors, several graphene-based hybrid structures have recently emerged, yielding improved selectivity and sensitivity. To date, most of the reported biosensors utilize solution-driven graphene flakes with drawbacks of low conductivity (due to high inter-junction contact resistant) and structural fragility. Herein, we present a conductive three-dimensional CeO2 semiconductor nanoparticles/graphene nanocomposite, as a platform for sensitive detection of hydrogen peroxide, an important molecule in fundamental biological processes. The 3D conductive graphene architecture is...
Highly sensitive nonenzymetic glucose sensing platform based on MOF-derived NiCo LDH nanosheets/graphene nanoribbons composite
, Article Journal of Electroanalytical Chemistry ; Volume 808 , 2018 , Pages 114-123 ; 15726657 (ISSN) ; Shahrokhian, S ; Iraji Zad, A ; Sharif University of Technology
Elsevier B.V
2018
Abstract
Herein, a novel sensing platform based on NiCo layered double hydroxide (LDH) nanosheets/graphene nanoribbons (GNRs) modified glassy carbon electrode is presented for sensitive non-enzymetic determination of glucose. In the first step, nanoflower-like NiCo LDH nanosheets were grown on the surface of ZIF-67 dodecahedron nanocrystals which used as sacrificial template and were further characterized by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), X-ray powder diffraction (XRD) and FTIR. In the next step, in order to fabricate a mechanically stable modified electrode, the as-prepared nanosheets were mixed with...