Sharif Digital Repository

Titanium is a highly reactive metal, so that whenever it is exposed to air or other environments containing available oxygen, a thin layer of oxide is formed on the surface. This layer increases the corrosion resistance of titanium. The formation of the oxide film can be electrochemically performed by anodizing. In this research, anodizing of titanium was performed in phosphate-base solutions such as H3PO4, NaH2PO 4·2H2O and Na2HPO4 at 9.75 mA/cm2 and 35 °C under galvanostatic conditions. The potential-time curves in the above mentioned solutions show that the anodic films formed on Ti are compact and their thickness depends on the solution type and concentration. The SEM and XRD studies... 

Titanium is a highly reactive metal with an inclination to compose with oxygen. In order to increase its corrosion resistance and application, therefore, a thin layer of titanium oxide is produced on the surface by chemical and electrochemical methods. In the present research, titanium has been anodized in 20 M of NaOH solution under potentiostatic conditions at constant voltages of 25 and 35 V. The microstructure of the anodic layers has been studied by the use of a Scanning Electron Microscope (SEM) and X-Ray Diffraction (XRD). The results indicated that the structure of the anodic layers is amorphous with low porosity and that thickness increases with an increase in anodizing voltage. The... 

The process of self-color anodizing of titanium is done in acidic and alkaline solutions, and anodic films of different colors are formed. Results of this work show that the corrosion rate of titanium decreased after the application of an anodizing layer  

In copper electrorefining process, some additives are added to the electrolyte to improve the morphology of cathode deposits as well as the quality of products. In the present investigation, the effects of thiourea, glue and chloride ions (as additives) on the passivation of industrial copper anodes under high current densities have been reported. Experiments were conducted at 65 °C; using a synthetic electrolyte containing 40 g/l Cu2+ and 160 g/l H2SO4. Results obtained from chronopotentiometry experiments showed that increasing the concentration of chloride ion leads to increase in passivation time. The results also indicated that from a certain level on, namely 2 ppm, the increase in... 

The wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of Khangiran's sour gas wells. These valve bodies have been operating satisfactorily for 3 years in wet H2S environment before some pits and cracks were detected in all of them during the periodical technical inspections. One failed valve body was investigated by chemical and microstructural analytical techniques to find out the failure cause and provide preventive measures. The valve body alloy was A216-WCC cast carbon steel. During investigation many cracks were observed on the inner surface of the valve body grown from the surface pits. The results... 

Microbial fuel cells (MFCs) represent a new method for simultaneous wastewater treatment and biological electricity generation. In this study, petrochemical wastewater with 8000 mg/l of chemical oxygen demand was examined in a membrane-less single chamber MFC. Effects of wastewater concentration as substrate for microbial oxidation, and anode material (stainless steel or carbon brush) were investigated as designing parameters  

Degradation of Clindamycin phosphate (CMP) was studied in aqueous solutions by an anodic oxidation process under galvanostatic conditions. The electrolysis cell consisted of a Ti/SnO2-Sb anode, prepared by dip-coating technique, and a 316 stainless steel cathode, both of which had a surface area of 6 cm2. The effects of critical factors, including CMP concentration, current density, initial pH, and the supporting electrolyte were evaluated. The electrochemical oxidation of CMP was controlled by mass transport within the studied range. The kinetic analysis indicated that the degradation reactions followed pseudo-first-order equation. The rate of CMP decay, as well as that of COD removal,... 

In this work, a porous and flexible three-dimensional (3D) nickel/gold nanoparticle electrode (NiF/AuNPs) is presented as an efficient electrocatalyst for ethanol oxidation in alkaline media. The 3D nanocomposite electrode consists of interconnected porous nickel foam (NiF) with large pores (500±200 μm diameter) surrounded by interconnected struts (∼100 μm) that are decorated with gold nanoparticles (AuNPs, 37±8 nm) through in-situ electrochemical deposition. The catalytic performance of the 3D electrode was evaluated by different electrochemical methods. An enhancement in the performance (about 253 %) and a remarkable decline in onset potential (about ∼0.63 V) in comparison with pristine... 

Titanium type lithium ion-sieve nanotubes synthesized by the hydrothermal method were extensively explored over recent years due to its promising properties. However, on account of nanotubes′ tangled structure impeding the lithium adsorption in the interior nanotube walls, unalterable dimensions of the synthesized nanotubes, and a long period of annealing, the anodizing technique was proposed. It is shown that lithium uptake and adsorption capacity is improved because of easier mass transfer during the ion exchange process. This work focuses on a novel anodizing method for nanotube ion-sieve synthesis. The optimum anodizing condition was discovered by altering anodizing voltage, time, and... 

In this study, the influence of the sample position (anode) on the incorporation of nano/micro alumina particles on the AZ31B magnesium alloy substrate was investigated by plasma electrolytic oxidation (PEO) coating. For characterized this effect, Scanning electron microscopy (SEM), potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), and pin-on-disk test were used to the evolution of the microstructure, corrosion resistance, and the wear behavior of the films. Based on the obtained results, the effect of the anode position from vertical to horizontal is dependent on particle size and it can be influenced only on the incorporation of nanoparticles. The... 

In order to improve titanium corrosion behavior, we can increase the thickness of oxide layer on titanium surface during anodizing process and by electrochemistry. In this research, self-color anodizing of Ti in sulfuric acid was done, and anodizing layers were created in different colors. The highest value of chromaticity was 37.8 for the anodized sample in 10 V, and the lowest value was 8.6 at 15 V. The oxide layer thickness was calculated by optical method (light refraction). The anodic film thickness increased by increasing the anodizing voltage. The highest thickness of anodic film was 190 nm in sulfuric acid solution for the anodized sample in 80 V. Corrosion resistance of anodized Ti... 

In this work, a novel and facile synthesis process to fabricate single crystalline organometal halide perovskite nanowires has been successfully developed. Nanowires were grown in a high density ordered array from metal nanoclusters inside anodic aluminum oxide templates using a non-catalytic chemical vapor deposition method. Specifically, perovskite NWs were grown as a result of the reaction between methylammonium iodide (MAI) and the Pb/Sn (Pb or Sn) metal in anodic aluminum oxide templates under optimal conditions. The characterization results show that there is a reaction zone at the interface between the perovskite material and metal, at the bottom of the anodic aluminum oxide... 

Accumulative roll bonded (ARBed) AA1050 and Al-2 vol% SiCp (AMC) samples were anodized in an H2SO4 electrolyte to improve corrosion resistance. The SEM images revealed that the anodic oxide's morphology is significantly dependent on the microstructure of the ARBed bare samples, owing to high internal energy that accelerates Al consumption during anodizing process. Potentiodynamic polarization measurements and EIS evaluation showed that anodic oxide improves the corrosion resistance of both ARBed AA and AMC samples; however, the electrochemical behavior of the processed samples changed due to the formation of a complex oxide structure comprising of twisted pore channels and attack routes. ©... 

Anodic aluminum oxide (AAO) was used as a template to prepare highly ordered Ni-Fe-Co alloy nanowire arrays. This membrane was fabricated with two-step anodizing method. It is found that there is an optimum barrier thickness to obtain a successful electrodeposition in pores of AAO. The thickness of barrier layer can be modified by additional electrochemical process after completing the anodizing step. Barrier layer thinning can create a rooted structure at the bottom side of the AAO pores and the electrodeposited nanowire arrays. The triple Ni-Fe-Co alloy was deposited in AAO membrane by ac voltage in a simple sulfate bath. The composition of nanowires shows anomalous deposition features... 

Today, Li-ion batteries (LIBs) are the most common rechargeable batteries used in electronic devices. SnO2 with theoretical specific capacity of 782 mAh/g is among the best anode materials for LIBs. In this report, Threedimensional SnO2 nanowires (NWs) on carbon nanotube (CNT) thin film (SnO2 / CNT) is fabricated using a combination of vacuum filtration and thermal evaporation techniques. The resulting 3D heterostructure SnO2/CNT was characterized by X-ray diffraction, transmission electron microscopy (TEM) and scanning electron microscopy (SEM). This fabricated SnO2/CNT electrode has been tested as a flexible and binderfree anode for LIB, which exhibits high initial discharge/charge... 

Supercapacitors store charge by ion adsorption or fast redox reactions on the surface of porous materials. One of the bottlenecks in this field is the development of biocompatible and high-rate supercapacitor devices by scalable fabrication processes. Herein, a Ti-rich anatase TiO2 material that addresses the above-mentioned challenges is reported. Tubular nanolettuces were fabricated by a cost-effective and fast anodization process of Ti foil. They attained a large potential window of 2.5 V in a neutral electrolyte owing to the high activation energy for water splitting of the (1 0 1) facet. Aqueous and all-solid-state devices showed diffusion time constants of 46 and 1700 ms, as well as... 

This study aimed to prepare nanoporous anodic alumina on AA3003-H14 aluminum alloy using a mild anodization process with minimal working voltage and treatment time. The microstructural features, mechanical properties, and tribocorrosion behavior of the coatings were assessed to determine the optimum conditions for the fabrication of nanoporous anodic alumina on AA3003-H14 alloy. The microstructural analysis showed both uniform and nonuniform pore nucleations during anodization in H2SO4/C2H2O4, H2SO4/H2CrO4, and EG/H2O/NH4F electrolytes, where the optimal nanoporous structure with an average thickness, porosity, pore diameter, and interpore distance of 382 nm, 19%, 16 nm, and 35 nm,...