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    Experimental study of the effect of water to cement ratio on mechanical and durability properties of Nano-silica concretes with Polypropylene fibers

    , Article Scientia Iranica ; Volume 26, Issue 5 A , 2019 , Pages 1-18 ; 10263098 (ISSN) Rahmani, K ; Ghaemian, M ; Hosseini, S. A ; Sharif University of Technology
    Sharif University of Technology  2019
    Abstract
    In the present paper, the effect of Nano silica on mechanical properties and durability of concrete containing polypropylene fibers has been investigated. Here, the length and length to diameter ratio of used polypropylene fibers were considered to be fixed and equal to 18 mm and 600 respectively and the cement content was 479 kg/m3. The effect of fibers and Nano silica in four different percentages for each one at 0.1, 0.2, 0.3 and 0.4 percent by volume for fibers and 3 percent for Nano silica in concrete with water to cement ratio of 0.33, 0.36, 0.4, 0.44 and 0.5 have been compared and evaluated. In total, more than 425 cubic and cylindrical specimens were made according to ASTM standards.... 

    Phosphomolybdic acid/graphene oxide as novel green catalyst using for biodiesel production from waste cooking oil via electrolysis method: Optimization using with response surface methodology (RSM)

    , Article Fuel ; Volume 287 , 2021 ; 00162361 (ISSN) Helmi, M ; Tahvildari, K ; Hemmati, A ; Aberoomand azar, P ; Safekordi, A ; Sharif University of Technology
    Elsevier Ltd  2021
    Abstract
    In this study, biodiesel (FAME) was prepared using a novel heterogeneous catalyst of phosphomolybdic acid (H3PMo12O40, HPMo)/support graphene oxide (GO). The characterization of the catalyst was evaluated by SEM, EDX, Map analysis, TEM, FT-IR, and Raman analyses. The production of biodiesel from waste cooking oil (WCO) was carried out by the electrolysis method. The process of the trans-esterification reaction was optimized by applying the response surface methodology (RSM) based on the central composite design (CCD) approach. The effects of four independent variables of methanol to oil molar ratio (6–12 mol:mol), catalyst weight (0.5–1.5 wt%), time (8–24 h), and voltage (30–70 V) were... 

    Converting waste cooking oil into biodiesel using phosphomolybdic acid/clinoptilolite as an innovative green catalyst via electrolysis procedure; optimization by response surface methodology (RSM)

    , Article Fuel Processing Technology ; Volume 225 , 2022 ; 03783820 (ISSN) Helmi, M ; Tahvildari, K ; Hemmati, A ; Azar, P. A ; Safekordi, A ; Sharif University of Technology
    Elsevier B.V  2022
    Abstract
    The present study aims to convert waste cooking oil (WCO) into biodiesel via phosphomolybdic acid (H3PMo12O40, PMA) supported on Clinoptilolite as a novel green acid catalyst through an electrolysis procedure. The prepared catalysts were characterized by XRD, FTIR, FESEM, EDS, Elemental map, and TEM analyses. The effect of four independent variables on biodiesel yield including methanol to oil molar ratio (6:1–14:1), catalyst weight (2–5 wt%), time (3–5 h), and voltage (15–35 V) was optimized and evaluated by the response surface methodology (RSM) employing central composite design (CCD). The maximum value of biodiesel yield was 96% under the optimal conditions, including the methanol to oil... 

    Phosphomolybdic acid/graphene oxide as novel green catalyst using for biodiesel production from waste cooking oil via electrolysis method: optimization using with response surface methodology (RSM)

    , Article Fuel ; Volume 287 , March , 2021 Helmi, M ; Tahvildari, K ; Hemmati, A ; Aberoomand azar, P ; Safekordi, A ; Sharif University of Technology
    Elsevier Ltd  2020
    Abstract
    In this study, biodiesel (FAME) was prepared using a novel heterogeneous catalyst of phosphomolybdic acid (H3PMo12O40, HPMo)/support graphene oxide (GO). The characterization of the catalyst was evaluated by SEM, EDX, Map analysis, TEM, FT-IR, and Raman analyses. The production of biodiesel from waste cooking oil (WCO) was carried out by the electrolysis method. The process of the trans-esterification reaction was optimized by applying the response surface methodology (RSM) based on the central composite design (CCD) approach. The effects of four independent variables of methanol to oil molar ratio (6–12 mol:mol), catalyst weight (0.5–1.5 wt%), time (8–24 h), and voltage (30–70 V) were...