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Synthesis, Characterization and Properties of Ternary Copper(II) Complexes Having Heterocyclic Ligand and α-Amino Acid Salicylaldiminates as Models for the Type-2 Sites in Copper Oxidases
, M.Sc. Thesis Sharif University of Technology ; Mohammadi Boghaei, Davar (Supervisor)
Abstract
Ternary copper (II) complexes having heterocyclic bases and α-amino acid salicylaldiminates
as models for the type-2 sites in copper oxidases are of great biological importance. Considerable attention has given to mixed ligand complexes due to their antitumore, antimicrobial , inflammatpry , ascorbate oxidase (AO) and dopamine β-hydroxylase(DβH) and radio- imaging properties. With this in mind, new copper (II) complexes including amino acid Schiff base and heterocyclic bases (1,10 phenanthroline and 2, 2 biprydine ) have been synthesized, investigated and characterized by IR, UV-Vis and CHN. In the case of amino acid Schiff-base complexes, the tridentate ONO Schiff base ligand...
as models for the type-2 sites in copper oxidases are of great biological importance. Considerable attention has given to mixed ligand complexes due to their antitumore, antimicrobial , inflammatpry , ascorbate oxidase (AO) and dopamine β-hydroxylase(DβH) and radio- imaging properties. With this in mind, new copper (II) complexes including amino acid Schiff base and heterocyclic bases (1,10 phenanthroline and 2, 2 biprydine ) have been synthesized, investigated and characterized by IR, UV-Vis and CHN. In the case of amino acid Schiff-base complexes, the tridentate ONO Schiff base ligand...