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    Synthesis of tin oxide nanoparticles in order to study its properties

    , Article Digest Journal of Nanomaterials and Biostructures ; Volume 16, Issue 1 , 2021 , Pages 41-49 ; 18423582 (ISSN) Shahzad, N ; Ali, N ; Shahid, A ; Khan, S ; Alrobei, H ; Sharif University of Technology
    S.C. Virtual Company of Phisics S.R.L  2021
    Abstract
    Pure tin oxide nanoparticles ware synthesized via Co-precipitation method. The as-synthesized nanoparticles were characterized by Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), X-ray diffraction (XRD) and diffuse reflectance spectroscopy (DRS). X-ray diffraction shows that tetrahedral shaped nanoparticles of crystallite size 47.35nm were prepared successfully. The crystallinity was established due the reduction in distortion ratio and dislocation density. The value of strain showed that the nanoparticles fabricated were of high stability. The direct and indirect optical band gap of as-synthesized SnO2 nanoparticles were determined from the reflectance... 

    Synthesis of C-N-Y tri-doped TiO2 photo-catalyst for MO degradation and characterization

    , Article Materials Research Express ; Volume 2, Issue 10 , October , 2015 ; 20531591 (ISSN) Hoseinian Maleki, F ; Nemati, A ; Joya, Y. F ; Sharif University of Technology
    Institute of Physics Publishing  2015
    Abstract
    In this researchC-N-Y tri-doped TiO2 nanopowders were synthesized by the sol-gel method. TheC- N-Y Ti O2 photo-catalyst was prepared using hexamine and yttrium nitrate Hexahydrate as the dopant precursors. Methyl-orange (MO) was used to study the photocatalytic performance of the doped Ti O2 underUVirradiation. The synthesized samples were characterized by x-ray diffraction, x-ray photoelectron spectroscopy,UV-vis diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy, Transmission electron microscopy, Photoluminescence and Field emission scanning electron microscopy. The tri-doped sample with8%N, 0.4% Y and 1.5%Cexhibited enhanced photocatalytic efficiencies. After 100... 

    A Study on the Effect of Morphology and Sol-gel Process Parameters on Photocatalytic Properties of Tialite

    , M.Sc. Thesis Sharif University of Technology Bakhshandeh, Fatemeh (Author) ; Maddah Hosseini, Hamid Reza (Supervisor)
    Abstract
    Enhancement of photocatalytic characteristics of semiconductors have been always a challenge for the researchers. Doping semiconductors for adjusting their energy gap and changing their morphology in order to increase their effective surface area and reaction sites are examples of their endeavor to overcome the challenge. In this research, nanostructured Aluminum Titanate powder was synthesized with Sol-Gel process and by altering synthesis parameters, the best synthesis condition to get the best possible band gap was discovered. Moreover, we examined the photocatalytic properties of the recently developed material “tialite”, which were not studied before and also evaluated the effect... 

    Investigation of Vanadium Dopant and SiO2 Prelayer on the Self-Cleaning Property of TiO2 Coatings by Sol-Gel Dip Coating Method

    , M.Sc. Thesis Sharif University of Technology Namkhah, Yalda (Author) ; Faghihi Sani, Mohammad Ali (Supervisor)
    Abstract
    Because of limitation of titania coating that can act as self-cleaning surface under UV light irradiation, introduction of transition metal ions into titania lattice can decrease band gap energy of titania in order to activate the coating under visible light irradiation. In this research, by using vanadium element and silica prelayer, a titania coating was deposited on the soda-lime glass substarte to produce self-cleaning surface. The scope of coating was to increase the photocatalytic activity and hydrophilicity of vanadium doped titania coating on the soda-lime glass and silica coated glass by sol-gel dip coating method. XRD and FTIR analysis were done on the powders with different... 

    Multi-scale modeling of edge effect on band gap offset in polygonal cross-section silicon nanowires

    , Article Computational Materials Science ; Volume 79 , November , 2013 , PP. 262–275 Khoei, A. R. (Amir Reza) ; DorMohammadi, H ; Aramoon, A ; Sharif University of Technology
    Abstract
    The band gap offset is an effect of coordination numbers (CNs) of atom reduction at the edge of transversal cross-section of Silicon nanowires (SiNWs). In this paper, a hierarchical multi-scale technique is developed to model the edge effect on the band gap shift of SiNWs since the geometric effect is dominant in the energy gap due to the appearance of strain in the self-equilibrium state. The multi-scale model is performed based on the molecular dynamics approach and finite element method for the micro- (atomistic) and macro-scale levels, respectively. The Cauchy–Born (CB) hypothesis is used to relate the atomic positions to the continuum field through the deformation gradient. Finally, the... 

    A new low voltage precision CMOS current reference with no external components

    , Article IEEE Transactions on Circuits and Systems II: Analog and Digital Signal Processing ; Volume 50, Issue 12 , 2003 , Pages 928-932 ; 10577130 (ISSN) Dehghani, R ; Atarodi, S. M ; Sharif University of Technology
    2003
    Abstract
    A novel current reference with low temperature and supply sensitivity and without any external component has been developed in a 0.25 μm mixed-mode process. The circuit is based on a bandgap reference (BGR) voltage and a CMOS circuit similar to a beta multiplier. An NMOS transistor in triode region has been used in place of a resistor in conventional beta multiplier to achieve a current which has a negative temperature coefficient and only oxide thickness dependent. The BGR voltage has a positive temperature coefficient to cancel the negative temperature coefficient of the beta multiplier. The simulation results using Bsim3v3 model show max-to-min fluctuation of less than 1 % over a... 

    Multi-scale modeling of edge effect on band gap offset in polygonal cross-section Silicon nanowires

    , Article Computational Materials Science ; Volume 79 , 2013 , Pages 262-275 ; 09270256 (ISSN) Khoei, A. R ; Dormohammadi, H ; Aramoon, A ; Sharif University of Technology
    2013
    Abstract
    The band gap offset is an effect of coordination numbers (CNs) of atom reduction at the edge of transversal cross-section of Silicon nanowires (SiNWs). In this paper, a hierarchical multi-scale technique is developed to model the edge effect on the band gap shift of SiNWs since the geometric effect is dominant in the energy gap due to the appearance of strain in the self-equilibrium state. The multi-scale model is performed based on the molecular dynamics approach and finite element method for the micro- (atomistic) and macro-scale levels, respectively. The Cauchy-Born (CB) hypothesis is used to relate the atomic positions to the continuum field through the deformation gradient. Finally, the... 

    Investigation on Synthesis and Properties of TiO2-CNT Nanocomposites Coating on Al Substrate

    , M.Sc. Thesis Sharif University of Technology Shadravan, Aysan (Author) ; Nemati, Ali (Supervisor) ; Sadeghian, Zahra (Supervisor)
    Abstract
    The aim of this project is investigation on synthesis and characterization of the TiO2-CNT nanocomposite films on aluminum substrate by sol-gel dip coating method. The pure TiO2 and TiO2-CNT nanocomposite layers were coated on aluminum substrate and heat treated in 400 C. In this work Ti-tetra isopropxide and different amounts of CNTs (5,10,15 %wt), were used for obtain the composites. The coatings were characterized by X-Ray diffraction (XRD) and the crystallite size of TiO2 was calculated by Scherrer formula. The corrosion properties of coating were examined by polarization test, and corrosion resistance of pure TiO2 was compared with TiO2-CNT coatings, and It showed that the composite... 

    Physicochemical and Photocatalytic Properties of Fe, Gd and P Doped TiO2 Nanoparticles

    , M.Sc. Thesis Sharif University of Technology Adyani, Mohsen (Author) ; Ghorbani, Mohammad (Supervisor)
    Abstract
    Improving the photocatalytic activity of titania nanoparticles and Cognition the mechanisms governing this property, has received more attention in the recent few years. One of the main strategies for improving the photocatalytic activity and modifying the bandgap structure of titania nanoparticles, is incorporation different metallic and nonmetallic ions in the titania lattice. In this study, 1%Fe, 1%Gd and 2%P (molar ratio) doped titania nanoparticles were successfully prepared by a modified sol-gel method in room temperature. The products were characterized with various spectroscopic and analytical techniques to determine their structural, morphological, physicochemical and... 

    An investigation of ZGNR-based transistors

    , Article 2011 International Semiconductor Device Research Symposium, ISDRS 2011, 7 December 2011 through 9 December 2011 ; December , 2011 , Page(s): 1 - 2 ; 9781457717550 (ISBN) Karamitaheri, H ; Pourfath, M ; Faez, R ; Kosina, H ; Sharif University of Technology
    2011
    Abstract
    Graphene, a recently discovered form of carbon, has received much attention for possible applications in nanoelectronics, due to its excellent carrier transport properties [1]. Graphene nanoribbons (GNRs) are thin strips of graphene, where the electronic properties depend on the chirality of the edge and the width of the ribbon. Zigzag GNRs (ZGNRs) show metalic behavior, whereas armchair GNRs (AGNRs) are semiconductors and their band-gap is inversely proportional to their width [2]. Therefore, narrow AGNRs have been recently suggested as a material for transistor channels. However, line edge roughness and substrate impurities can significantly degrade the ballistic transport in AGNRs,... 

    Continuous Unitary Transformation and Quantum Phase Transition in Kondo-necklace Model

    , M.Sc. Thesis Sharif University of Technology Rahimi Movassagh, Mahsa (Author) ; Langari, Abdollah (Supervisor)
    Abstract
    Strongly correlated electron systems are an interesting topic among condensed matter systems. The electrons in such systems are strongly correlated to each other in a way that the behavior of the systems cannot be described by single particle theories. One of the most famous of these systems are heavy fermionic materials which are called so due to heavy quasi particles mass.
    This kind of materials have been investigated via different methods. The most im-portant model that can describe characteristics of these materials is Kondo lattice model. When we are only interested in magnetic properties of them, the model can be reduced to Kondo-necklace model which only involves with spin degrees... 

    A Study on the Effect of Planet and Disk Parameters on the Resulting Gap in Protoplanetary Disks

    , M.Sc. Thesis Sharif University of Technology Sadeghi Ardestani, Leila (Author) ; Abbasi, Shahram (Supervisor) ; Rahvar, Sohrab (Supervisor)
    Abstract
    The number of discovered extrasolar planetary systems has increased immensely during the past 15 years. The various outcomes of planetary formation are a result of the complicated interaction between gravitational, hydrodynamical and accretion processes a considerable amount of which is not yet understood. Thus far the effect of a planet embedded in a protoplanetary disk has been studied both analytically and using numerical simulations. These suggest that under suitable circumstances tidal effects result in the formation of a gap in the disk about the orbit of the planet. This result has been particularly used to detect massive extrasolar planets (massive enough to form gaps).In this study... 

    Systematic Design of Low Power Flash ADC

    , Ph.D. Dissertation Sharif University of Technology Chahardori, Mohammad (Author) ; Sadughi, Sirus (Supervisor) ; Sharifkhani, Mohamad (Co-Advisor) ; Atarodi, Mojtaba (Co-Advisor)
    Abstract
    Considering the drastical increasing of greenhouse gases in the atmosphere, especially carbon dioxide, reduction of these gases seems necessary to combat global warming. Fossil fuel power plants are one of the main sources of CO2 emission. In this thesis, CO2 capture from a natural gas fired combined cycle power plant using different oxygen percent in air feed is studied. Aspen Plus was used to evaluate the effect of this capture technology on the plant efficiency and energetic parameters of the system. Aspen Hysys is used to simulate Amine absorption tower and Air Separation cryogenic tower. Since the oxygen production plant, CO2 capture and transport are cost and energy intensive, the cost... 

    Numerical Study of Anisotropic Ferrimagnetic Chain and Ladder with Density Matrix Renormalization Group Method

    , M.Sc. Thesis Sharif University of Technology Asadzadeh, Mohammad Zhian (Author) ; Langari, Abdollah (Supervisor)
    Abstract
    According to Haldane Conjecture Antiferromagnetic Heisenberg Spin Chain with integer spin has an energy gap, and exponential decay of correlation functions , while half integer spin chains are gapless with algebraic decay of correlation functions. A spin chain with two types of spins and Heisenberg interaction shows a mixture of both types of behavior. A ferrimagnet which is composed of two spins (S, s) has two bands of energy, the lower band is gapless and ferromagnetic property while the upper one is gapful with antiferromagnetic behavior. In the present work we have studied the anisotropic ferrimagnet in the presence of a transverse magnetic field. We have shown that the spin wave theory... 

    Surface Passivation of PbS Colloidal Quantum Dots for Photovoltaic Applications

    , Ph.D. Dissertation Sharif University of Technology Tavakkoli, Mohammad Mahdi (Author) ; Simchi, Abdolreza (Supervisor) ; Ashuri, Hossein (Supervisor)
    Abstract
    Solution-processed quantum dots (QDs) have attracted significant attention for the low-cost fabrication of optoelectronic devices. Here, we synthesized PbS QDs via hot injection method and passivated the trap states by using short thiols and dopant elements for photovoltaic application. In order to study the effect of dopants on photovoltaic application, PbS QDs were doped by using three different cations: Cadmium, Calcium, and Zinc. The results showed that Cd dopant has a better improvement than Ca and Zn dopants in order to increase the efficiency of the PbS QDs solar cells. We achieved solar power conversion efficiencies of 5.81% using Cd therapy. Recently, hybrid nanocomposites... 

    Synthesis of Boron Nitride Quantum Dots Using a Mechanical Milling- Solvothermal Process

    , M.Sc. Thesis Sharif University of Technology Angizi, Shayan (Author) ; Simchi, Abdolreza (Supervisor)
    Abstract
    Boron Nitride Quantum Dots, as a new member of Heavy-metal-free Quantum dots has attracted many attention due to their unique properties. The hyroxylate functionalized BNQDs was synthesized with two steps fabrication approache which were contained mechanical milling and solvothermal process. It has been shown that 12 hours for mechanical milling and 24 hours for solvothermal process would be the most optimum time that produce well disperse functionalized BNQDs . The characterization results have proved that the as-prepared BNQDs have lateral size at around 5 nm with thickness in range of 4-6 layers. Also, it has been demonstrated that OH functional groups can attache into the surface of... 

    Construction of Dirac points using triangular supercrystals

    , Article Applied Physics A: Materials Science and Processing ; Volume 115, Issue 2 , May , 2014 , Pages 581-587 ; ISSN: 09478396 Aram, M. H ; Mohajeri, R ; Khorasani, S ; Sharif University of Technology
    Abstract
    We show a methodology for how to construct Dirac points that occur at the corners of Brillouin zone as the Photonic counterparts of graphene. We use a triangular lattice with circular holes on a silicon substrate to create a Coupled Photonic Crystal Resonator Array (CPCRA) which its cavity resonators play the role of carbon atoms in graphene. At first we draw the band structure of our CPCRA using the tight-binding method. For this purpose we first designed a cavity which its resonant frequency is approximately at the middle of the first H-polarization band gap of the basis triangular lattice. Then we obtained dipole modes and magnetic field distribution of this cavity using the Finite... 

    Spin dependent recombination in magnetic semiconductor

    , Article Applied Physics Letters ; Volume 94, Issue 24 , 2009 ; 00036951 (ISSN) Tashpour, H ; Vesaghi, M. A ; Sharif University of Technology
    2009
    Abstract
    The effect of spin dependent recombination on the transport properties of magnetic semiconductors is investigated theoretically. In particular, for p -type direct band gap semiconductors, a theory based on classic Shockley equations is formulated. In this theory the density of spin and charge has been evaluated analytically by solving the diffusive transport equation and it is shown that the difference between recombination rates affect the lifetimes of spin and charge significantly. It is also demonstrated that a considerable spin charge coupling occur. Application of this theory to pure band to band recombination process is discussed. © 2009 American Institute of Physics  

    Precision photonic band structure calculation of Abrikosov periodic lattice in type-II superconductors

    , Article Physica C: Superconductivity and its Applications ; Volume 460-462 II, Issue SPEC. ISS , 2007 , Pages 1222-1223 ; 09214534 (ISSN) Kokabi, A ; Zandi, H ; Khorasani, S ; Fardmanesh, M ; Sharif University of Technology
    2007
    Abstract
    We have performed a numerical solution for band structure of an Abrikosov vortex lattice in type-II superconductors forming a periodic array in two dimensions for applications of incorporating the photonic crystals concept into superconducting materials with possibilities for optical electronics. The implemented numerical method is based on the extensive numerical solution of the Ginzburg-Landau equation for calculating the parameters of the two-fluid model and obtaining the band structure from the permittivity, which depends on the above parameters and the frequency. This is while the characteristics of such crystals highly vary with an externally applied static normal magnetic field,... 

    The effect of target annealing temperature on optical and structural properties and composition of CdS thin films prepared by pulsed laser

    , Article Optical Materials ; Volume 27, Issue 10 , 2005 , Pages 1583-1586 ; 09253467 (ISSN) Mahdavi, S. M ; Iraji Zad, A ; Tilaki, R. M ; Sharif University of Technology
    Elsevier  2005
    Abstract
    We studied the effect of target annealing temperature on optical and structural properties and composition of CdS thin films prepared by pulsed Nd:YAG laser. Deposited samples from annealed targets at 300 °C showed a mixed cubic and hexagonal structure, a band gap of about 2.56 eV and Cd/S ratio equal 1. This ratio increased to 2.40 and its band gap decreased to 2.46 eV when the sample was annealed at 500 °C for 1 h in air. However, films prepared from annealed targets at 500 °C became dark due to existence of polymorphous phase of CdO. Films changed to transparent yellow color with a hexagonal CdS structure and some peaks related to CdO after annealing above 250 °C in air. Its band gap...