Sharif Digital Repository

Hydroxyurea is an anticancer drug that is commonly used to treat chronic myeloid leukemia (white blood cell cancer in bone marrow), polycythemia vera (red blood cell cancer), sickle cell anemia, solid tumors, and in particular leukemia. In this research, in addition to analyzing all available methods for synthesis of hydroxyurea, the most economical method for synthesis of hydroxyurea which is Hantzsch method was chosen; then we synthesized hydroxyurea crystals using a precipitation or crystallization process. To do so, two hydroxylamine hydrochloride and potassium cyanate reactants have been used in the semi batch reactor. Since the reaction efficiency and purity of the synthesized... 

Despite many advantages of granular sludge in anaerobic reactors (e.g. UASB), over the past few years research attention had turned towards developing aerobic granular sludge. Although much research is carried out on the formation of aerobic granules, less work is reported on how to enhance granules characteristics such as increasing in granule size, concentration, durability and stability. The aims of this study are to investigate the effects of cationic polymer on granule formation and the way to improve granule characteristics. For this purpose two SBR reactors (0.15 m diameter and 1.8 m height, R1 and R2) were used by feeding synthetic wastewater (diluted molasses, COD ranging from 1400... 

The aim of this project is to inventigate and synthesize CaO-based nanocatalysts with metal promoters of magnesium and lithium by wet impregnation and coprecipitation methods, which are used in the transesterification reaction of canola oil and methanol. Sections of thesis include review of before researches , synthesis of nanocatalysts, catalyst characterization tests,and investigation of reaction under optimal conditions. In wet impregnation method, nanocatalysts were made with 5% by weight of lithium-magnesium on the basis of CaO and with different weight percentages of these two elements. In the co-precipitation method , catalysts with a combined base of calcium oxide/magnesium oxide ... 

In the present study , operation of a laboratory scale sequencing batch reactor (SBR) was evaluated to treatment of synthetic wastewaters containing ethylene glycol. Studies carried out with a plexiglass bioreactor whith effective volume of 18 lit.Aeration was supplied via two air diffusers that set at the bottom of the reactor. Synthestic wastewater containing ethylene glycol and molasses as carbon source and other nutrient such as diammonium hydrogen phosphate as phosphor source and urea as nitrogen source for biological activities was composed at the laboratory. To optimization of this reactor three parameters – aeration time, chemical oxygen demand and sudden change in arganic loading... 

Almost all of the animal slaughter is done in slaughterhouses. Environment concerns about slaughterhouse industries have been increased as increase in their production. In this study, a DAF+SBR system was used for treatment of industrial slaughterhouse wastewater and efficiency of this system was evaluated.In DAF, we used anionic polymer and PAC as coagulant. We reached best composition in 2 ppm of AP and 200 ppm of PAC. After that DAF system run in different pressures to estimate the best operational pressure & A/S. Best operational pressure and A/S is 4 bar and 0.038. After pretreatment, biological treatment by using SBR reactor was carried out. The results of the SBR reactor showed that... 

Obtaining polymers with desired properties is very important from industrial point of view. Weight average molecular weight and polydispersity are two important polymer properties. It is also important to obtain a high monomer conversion. In this thesis production of polyvinyl acetate is considered. Under special conditions, the vinyl acetate reactor dynamics become oscillatory which makes the reactor control difficult. For obtaining polymer with desired properties, an objective function which includes weight average molecular weight, polydispersity and monomer conversion has been defined. Then by minimizing this objective function the optimal temperature trajectory is obtained. In this... 

consumption of which (especially azo dyes) have been increasing nowadays, causing the increase of textile wastewaters. Usually, these wastewaters contain an immense number of dyes, and if these dyes release in the environment especially in waters, they cause some problems, such as the change of watercolor as well as taste, and affect creatures' lives severely. Moreover, If the dyes are left untreated in aquatic ecosystems, they can remain in the environment for a very long time, resulting in harmful and irreversible effects. Azo dyes are classified as mono, di-, three, azo dyes due to their bonds. Because dyes are increasingly used, nowadays, different methods are developed for the treatment... 

In recent years, utilization of hybrid attached and suspended growth system for modification of conventional activated sludge systems has attracted a lot of attentions. Nowadays, with development of urban areas and also introducing new emerging contaminants and as a result an increase in the influent loading of wastewater treatment facilities, the importance of upgrading and retrofitting available facilities have been highlighted. Conversion of Sequencing Batch Reactors to Sequencing Batch Biofilm Reactors is a viable solution for overcoming these problems. Eventhough several researches have been conducted on removal of different contaminants through these systems, the information about the... 

Paper and cardboard waste pulping consume large volumes of water, so the discharge of this effluent without proper treatment can have far-reaching environmental consequences. The color and variable COD concentration of wastewater in this industry make treating this wastewater complicated. Therefore, this study aims to reduce the COD of the wastewater treatment plant of a pulp and paper mill under different laboratory conditions to achieve environmental standards in Iran.In this study, coagulation-flocculation and the Fenton process on the wastewater entering the treatment plant were investigated first. It was found that coagulation and flocculation by 750-1250 ppm of alum coagulant and ten...