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    Band-gap narrowing and electrochemical properties in N-doped and reduced anodic TiO2 nanotube arrays

    , Article Electrochimica Acta ; Volume 270 , 2018 , Pages 245-255 ; 00134686 (ISSN) Peighambardoust, N. S ; Khameneh Asl, S ; Mohammadpour, R ; Khameneh Asl, S ; Sharif University of Technology
    Elsevier Ltd  2018
    Abstract
    Electrochemical activity of TiO2 nanotube arrays (NTAs) is restricted by a wide band gap of TiO2. To overcome this restriction, we considered systematic research on two effective methods of doping of TiO2 NTAs such as the N-doping and electrochemical reductive doping and predicting the proper application of them. Band gap narrowing was occurred from 3.16 eV for undoped TiO2 NTAs to 2.9 and 2.7 eV at N-doped and self-doped TiO2 ones respectively. The electrochemical responses of the TiO2 NTAs before and after doping were examined by cyclic Voltammetry (CV) curve. To understand the electrochemical behavior of the undoped and doped TiO2 NTAs, electrochemical impedance spectroscopy (EIS) was... 

    Improved efficiency in front-side illuminated dye sensitized solar cells based on free-standing one-dimensional TiO2 nanotube array electrodes

    , Article Solar Energy ; Volume 184 , 2019 , Pages 115-126 ; 0038092X (ISSN) Peighambardoust, N. S ; Khameneh Asl, S ; Mohammadpour, R ; Khameneh Asl, S ; Sharif University of Technology
    Elsevier Ltd  2019
    Abstract
    Although morphological disorder of nanotube structure is further down than the nanoparticular electrode, its density of traps are the hindering effects in the charge transport. In this study, crack-free TiO2 nanotube membranes, which obtained through a re-anodizing process, are fixed on transparent fluorine–tin-oxide glass by applying a few drops of Titanium Isopropoxide without needing the TiO2 powder paste. Front-side illuminated dye sensitized solar cells fabricated by undoped, N-doped and blue TiO2 nanotube membranes are investigated. The electrical characteristics of TiO2 nanotube based dye sensitized solar cells are followed by theoretical analysis using simple one-diode model....