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    The role of CO2 and ion type in the dynamic interfacial tension of acidic crude oil/carbonated brine

    , Article Petroleum Science ; Volume 16, Issue 4 , 2019 , Pages 850-858 ; 16725107 (ISSN) Lashkarbolooki, M ; Zeinolabedini Hezave, A ; Ayatollahi, S ; Sharif University of Technology
    China University of Petroleum Beijing  2019
    Abstract
    The effects of CO2 and salt type on the interfacial tension (IFT) between crude oil and carbonated brine (CB) have not been fully understood. This study focuses on measuring the dynamic IFT between acidic crude oil with a total acid number of 1.5 mg KOH/g and fully CO2-saturated aqueous solutions consisting of 15,000 ppm of KCl, NaCl, CaCl2 and MgCl2 at 30 °C and a wide range of pressures (500–4000 psi). The results of IFT measurements showed that solvation of CO2 into all the studied aqueous solutions led to an increase in IFT of acidic crude oil (i.e., comparison of IFT of crude oil/CB and crude oil/brine), while no significant effect was observed for pressure. In contrast, the obtained... 

    Swelling behavior of heavy crude oil during injection of carbonated brine containing chloride anion

    , Article Journal of Molecular Liquids ; Volume 276 , 2019 , Pages 7-14 ; 01677322 (ISSN) Lashkarbolooki, M ; Zeinolabedini Hezave, A ; Ayatollahi, S ; Sharif University of Technology
    Elsevier B.V  2019
    Abstract
    Carbonated brine (CB) injection, known as one of the effective enhanced oil recovery processes, is highly dependent on the reservoir conditions (i.e. temperature and pressure) as well as the type of dissolved salt in aqueous solution. This study is aimed to investigate the influential parameters on the swelling of crude oil as the most important mechanism during CB injection. The swelling of crude oil in the presence of different CB solutions consisted of different salts such as KCl, NaCl, CaCl2 and MgCl2 with constant concentration of 15,000 ppm is studied using a high-pressure, high-temperature visual cell which measures the volume of drop using image processing software based on...