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    Investigation on Effective Parameters in Ceramic Coating on Titanium Substrate by PEO Method in Galvano Static Condition

    , M.Sc. Thesis Sharif University of Technology Fazeli Tehrani, Alimohammad (Author) ; Faghihi Sani, Mohammad Ali (Supervisor)
    Abstract
    During this research, ceramic coatings on titanium substrate were prepared by plasma electrolytic oxidation process at a constant current density. Effect of different parameters such as frequency, current density, additives and time on the characteristics of the coated samples was studied. Composition, structure and elemental distribution of the coatings were studied by XRD, SEM and wave-length dispersive spectroscopy (WDS), respectively. Various tests were carried out to calculate the amount of coatings porosity. Pin-On-Disk method was used to evaluate erosion resistance of coatings. Corrosion and erosion-corrosion behaviors of the coatings were studied in 3.5wt% sodium chloride aqueous... 

    Characterization of Ceramic Coating Synthesized on Magnesium Alloy Substrate by Plasma Electrolytic Oxidation Process

    , M.Sc. Thesis Sharif University of Technology Rafizadeh, Ehsan (Author) ; Faghihi Sani, Mohammad Ali (Supervisor)
    Abstract
    Plasma electrolytic oxidation (PEO) is currently recognized as an effective coating method on active metals such as magnesium. In this method, through occurrence of strong electric discharges on the surface of the anode accompanied by electrochemical and thermo-chemical reactions at plasma environment, a relatively thick ceramic coating with complex compounds grows on the metal surface which significantly improves its properties. Regarding the influence of PEO electrical parameters on the morphology and other properties of the coating, the objective of the present study is to prepare a quality ceramic coating on AZ31 magnesium alloy substrate via setting the process parameters, such as... 

    Effects of APS Coating on Wear Characteristic of Internal Combustion Engine's Cylinder

    , M.Sc. Thesis Sharif University of Technology Ghorashi, Mir Siavash (Author) ; Farrahi, Gholamhossein (Supervisor) ; Yousefi, Reza (Supervisor)
    Abstract
    The quest for increasing the efficiency of internal combustion engines is going on since the invention of automobile in the world. Wear between cylinder and ring is one of the major parameters reducing the engine performance. So many parameters are affecting the wear losses. Temperature plays a key role on the severity of wear condition in internal combustion engines. In conventional cast iron cylinders, we are not able to increase the temperature from a defined level; one reason is that the wear rate on cylinder ring contact will increase excessively. One of the major benefits of using ceramic coating is their ability to withstand in higher temperatures, while having adequate hardness to... 

    The Investigation of Effective Parameters in Coating on Aluminized Steel by Plasma Electrolytic Oxidation Process

    , M.Sc. Thesis Sharif University of Technology Jafarniya, Vahid (Author) ; Faghihi Sani, Mohammad Ali (Supervisor)
    Abstract
    Plasma electrolytic oxidation process (PEO) is now recognized as a relatively new method in surface engineering. In this process, formation of micro arcs resulted from electric discharges on the surface of the specimen in the appropriate electrolyte, is used to ionize the gas layer which has enshrouded the specimen. In the present study, ceramic coating on aluminized steel was produced by PEO process and the effects of the influential parameters were comprehensively investigated. For this purpose, coating on the aluminized steel with dimension of 25×30 mm² was produced under different condition of processing time from 1 to 15 minutes, current density from 10 to 20 A/dm², frequency from 50 to... 

    Preparation of Composite Coating with ZrO2 Nanoparticles on Aluminum 5052 Alloy Using Plasma Electrolytic Oxidation

    , M.Sc. Thesis Sharif University of Technology Amiri Yarahmadi, Hossein (Author) ; Ghorbani, Mohammad (Supervisor)
    Abstract
    Plasma Electrolytic Oxidation (PEO) method was used for the preparation of ceramic coatings on Aluminum 5052 substrate in a silicate-based electrolyte containing different concentrations of ZrO2 nanoparticles. Before the addition of nanoparticles into the electrolyte, determining process parameters including current density, coating time, and frequency were examined carefully. After studying corrosion behavior, thickness, and coating morphology in different circumstances, the frequency of 50Hz, the current density of 150mA/cm2, and the coating time of 20 minutes were chosen as the optimum parameters. After that and with the usage of those parameters, ZrO2 nanoparticles were added to the... 

    AC Anodizing of Pure Titanium Grade 2 with HA Nano Particle

    , M.Sc. Thesis Sharif University of Technology Chambary, Ehsan (Author) ; Ghorbani, Mohammad (Supervisor)
    Abstract
    In this study, biocompatible ceramic coating, containing hydroxyapatite particles (HA), was successfully created by AC anodizing, on the surface of commercially pure titanium grades 2. Coating process basically consisted of three methods. In Method 1, samples were anodized in a salty electrolyte containing calcium – phosphate base and in method 2 samples were anodized as initial process, following cathodic polarisation deposition of HA particles. Finally in method 3, samples were anodized in an electrolyte containing of HA particles suspension.Parameters such as current density and time of anodizing process, in first procedure, and time of cathodic deposition process in second procedure, and... 

    The Comparison Between TiN and Hard Chromium Coatings

    , M.Sc. Thesis Sharif University of Technology Ghominejad , Hanieh (Author) ; Dolati, Abolghasem (Supervisor)
    Abstract
    This research focuses on finding an appropriate method for increasing wear and corrosion resistance of hard coating TiN PVD and chromium. The substrate was made up of 42CrMo4 (DIN) steel (used for marine industries) and coated by TiN Arc PVD process and hard chromium electro-deposition. The results of these two coatings are compared and the better coating which is TiN Arc PVD is suggested. To find the best method for coating, several test studies are organized such as: the mechanical and tribological properties of TiN PVD and hard chromium coatings for wear and corrosion resistance applications are organized. The potentiodynamic polarization technique was used to measure the corrosion rate... 

    Synthesis of Tin and Ti2n Nanostructured Coatings on Ti alloys Using Magnetron Sputtering System And Comparison of Their Biocompatibility Properties

    , M.Sc. Thesis Sharif University of Technology Kalantari Saghafi, Mahsa (Author) ; Nemati, Ali (Supervisor) ; Khamse, Sara (Supervisor)
    Abstract
    Considering the importance of biocompatibility of implantable prothesis’, metallic alloys have weaker corrosion resistance than ceramics. In order to extend usage of nanomaterials to improve the bio-properties of materials, Nano-structured ceramic coatings are being suggested to improve corrosion resistance and biocompatibility of prosthesis. Meanwhile, very good properties of TiN, such as corrosion resistance and mechanical properties as a thin film coating are undeniable. In this study, TiN and Ti2N thin film were deposited on Ti-based substrate, using PVD and Magnetron sputtering at different argon to nitrogen ratio. The crystal structure of the films was examined using Grazing XRD... 

    Effect of plasma electrolytic oxidation on joining of AA 5052 aluminium alloy to polypropylene using friction stir spot welding

    , Article Surface and Coatings Technology ; Volume 313 , 2017 , Pages 274-281 ; 02578972 (ISSN) Aliasghari, S ; Ghorbani, M ; Skeldon, P ; Karami, H ; Movahedi, M ; Sharif University of Technology
    Elsevier B.V  2017
    Abstract
    The effect of a plasma electrolytic oxidation (PEO) pre-treatment on joining of AA 5052 aluminium alloy and polypropylene by friction stir spot welding (FSSW) is investigated using lap tensile shear tests. Two surface conditions of the AA 5052 alloy are compared, one with a PEO pre-treatment in a silicate-based electrolyte, another without any pre-treatment. The resultant specimens are examined by high resolution scanning electron microscopy, thermogravimetric analysis and attenuated total reflectance-infrared spectroscopy. The PEO treatment generated a thermally-insulating, porous ceramic coating, which has a highly porous, rough surface that is favourable for incorporating polypropylene... 

    Effect of Sr and Ca dopants on oxidation and electrical properties of lanthanum chromite-coated AISI 430 stainless steel for solid oxide fuel cell interconnect application

    , Article Ceramics International ; Volume 39, Issue 7 , September , 2013 , Pages 8123-8131 ; 02728842 (ISSN) Rashtchi, H ; Sani, M. A. F ; Dayaghi, A. M ; Sharif University of Technology
    2013
    Abstract
    Lanthanum chromite coating occupies a noticeable position as a ceramic coating on metallic interconnects in solid oxide fuel cells because of its excellent electrical conductivity, high oxidation resistance and desirable chemical stability in both oxidizing and reducing atmospheres. In the present work, a sol-gel process based on the dip-coating technique was used to prepare dense and uniform coatings on metallic alloy for interconnect application (AISI 430 type). The effect of strontium and calcium doping into lanthanum chromite structure on electrical conductivity and oxidation behavior of the coated sample has been investigated. The oxidation behavior was evaluated by cyclic oxidation... 

    Effect of NaOH on the structure and corrosion performance of alumina and silica PEO coatings on aluminum

    , Article Journal of Materials Engineering and Performance ; Volume 21, Issue 10 , October , 2012 , Pages 2195-2202 ; 10599495 (ISSN) Salehi Doolabi, D ; Ehteshamzadeh, M ; Mirhosseini, S. M. M ; Sharif University of Technology
    Springer  2012
    Abstract
    The effect of NaOH content of electrolyte on the properties of ceramic coatings, produced in silicate solution, was studied. Morphology, chemical analysis, phase composition, and cross-section of the ceramic coatings were investigated by SEM, EDS, XRD, and OM, respectively. The corrosion resistance and corrosion mechanism were also studied using potentiodynamic polarization and electrochemical impedance spectroscopy in a 3.5% NaCl solution. To study the surface roughness, a brightness SEM image analysis method was used. Results suggested that increasing the NaOH concentration of sediment production size causes thickness and coating roughness to decrease. The lowest corrosion rate belonged to... 

    Effects of alumina nanoparticles concentration on microstructure and corrosion behavior of coatings formed on titanium substrate via PEO process

    , Article Ceramics International ; Volume 42, Issue 7 , May , 2016 , Pages 8789–8797 ; 02728842 (ISSN) Sarbishei, S ; Faghihi Sani, M. A ; Mohammadi, M. R ; Sharif University of Technology
    Elsevier Ltd  2016
    Abstract
    Plasma electrolytic oxidation (PEO) process was employed to create ceramic coatings on titanium substrate by using silicate-based electrolytes containing different concentrations of alumina nanoparticles (0, 3, 6, and 10. g/lit). The effect of alumina nanoparticles concentration on the morphology, chemical and phase composition of the PEO coatings was investigated by scanning electron microscope, energy dispersive spectrometer, and X-ray diffractometer, respectively.The corrosion behavior of samples was studied by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) tests. SEM, EDS, and XRD analyses illustrated that alumina nanoparticles incorporated into the... 

    The kinetics of Ni-Co/SiC composite coatings electrodeposition

    , Article Journal of Alloys and Compounds ; Volume 504, Issue 2 , 2010 , Pages 514-518 ; 09258388 (ISSN) Bahadormanesh, B ; Dolati, A ; Sharif University of Technology
    2010
    Abstract
    Ni-Co/SiC composite coatings with various contents of SiC particles were electrodeposited in a modified Watt's type of Ni-Co bath containing suspended 20 nm SiC particles. Deposition parameters including current density, bath SiC concentration and magnetic stirring rate were optimized for the highest amount of the SiC codeposition: the current density of 4 A/dm2, 40 g/dm 3 SiC concentration and 480 rpm stirring rate. In order to study the SiC particles codeposition, the Guglielmi's model of codeposition was modified for high volume percentages of the second phase and the modified model was employed to explain the effects of deposition parameters on the kinetics of the particles codeposition.... 

    Effects of temperature on wear behavior of a plasma sprayed diesel engine cylinder

    , Article SAE Technical Papers ; 2012 Ghorashi, M. S ; Farrahi, G. H ; Eftekhari, M. R ; Sharif University of Technology
    SAE  2012
    Abstract
    One of the main subjects in automotive industries is to enhance the efficiency of internal combustion engines. Wear between cylinder and ring is one of the major parameters reducing the engine performance. So many parameters are affecting the wear losses. Temperature plays a key role on the severity of wear condition in internal combustion engines. In conventional cast iron cylinders, it is not possible to increase the temperature from a defined level, as it causes excessive wear in contact area between cylinder liner and piston ring. One of the major benefits of using ceramic coating is their ability to withstand in higher temperatures, while having adequate hardness to improve wear rate... 

    Coating thickness and roughness effect on stress distribution of A356.0 under thermo-mechanical loadings

    , Article Procedia Engineering, 5 June 2011 through 9 June 2011 ; Volume 10 , June , 2011 , Pages 1372-1377 ; 18777058 (ISSN) Moridi, A ; Azadi, M ; Farrahi, G. H ; Sharif University of Technology
    2011
    Abstract
    Cast aluminium-silicon alloy, A356.0, is widely used in automotive components such as diesel engine cylinder heads and also in aerospace industries because of its outstanding mechanical, physical, and casting properties. Thermal barrier coatings are applied to combustion chamber in order to reduce fuel consumption and pollutions and also improve fatigue life of components. However, studies on behaviour of A356.0 with thermal barrier coating are still rare. The purpose of the present work is to simulate stress distribution of A356.0 under thermo-mechanical cyclic loadings, using a two-layer elastic-visco-plastic model of ABAQUS software. The results of stress-strain hysteresis loop are... 

    Recent progress in inorganic and composite coatings with bactericidal capability for orthopaedic applications

    , Article Nanomedicine: Nanotechnology, Biology, and Medicine ; Volume 7, Issue 1 , Feb , 2011 , Pages 22-39 ; 15499634 (ISSN) Simchi, A ; Tamjid, E ; Pishbin, F ; Boccaccini, A. R ; Sharif University of Technology
    Abstract
    This review covers the most recent developments of inorganic and organic-inorganic composite coatings for orthopedic implants, providing the interface with living tissue and with potential for drug delivery to combat infections. Conventional systemic delivery of drugs is an inefficient procedure that may cause toxicity and may require a patient's hospitalization for monitoring. Local delivery of antibiotics and other bioactive molecules maximizes their effect where they are required, reduces potential systemic toxicity and increases timeliness and cost efficiency. In addition, local delivery has broad applications in combating infection-related diseases. Polymeric coatings may present some...