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Hexyltriphenylphosphonium bromide as an absolutely chemoselective ionic liquid catalyst in the three-component reaction of aryl aldehydes, acetophenones and malononitrile
, Article ChemistrySelect ; Volume 4, Issue 20 , 2019 , Pages 6190-6193 ; 23656549 (ISSN) ; Khodaei, M. M ; Batooie, N ; Hosseinzadeh, N ; Foroumadi, A ; Sharif University of Technology
Wiley-Blackwell
2019
Abstract
Hexyltriphenylphosphonium bromide (HTPB) is used as an efficient ionic liquid catalyst in the chemoselective addition of malononitrile to carbonyl group moiety of chalcones through the three-component reaction of aryl aldehydes, acetophenone derivatves, and malononitrile to produce (E)-2-(1,3-diarylallylidene)malononitriles at ambient temperature. The method is simple, solvent-free, environmentally friendly, and gives excellent yields in a short reaction times. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim