Sharif Digital Repository

To enhance hydrophilicity and photocatalytic activity, N-doped and N–V-codoped TiO2films were coated on glass substrates by the sol–gel dip-coating method. The substrates were previously coated with SiO2using the same method. The coated samples, after annealing at 450 °C for 30 min in air, were analyzed by an X-ray diffractometer, scanning electron microscope, Fourier transform infrared spectroscope, X-ray photoelectron spectroscope, and UV–visible spectroscope. The SiO2/N–V-codoped TiO2photocatalyst showed a narrower band gap (2.93 eV) compared to the SiO2/N-doped. Degradation tests, methyl orange under UV light and stearic acid under visible light, were performed in order to evaluate... 

In this research, for the first time, the effect of air quenching on the microstructural and electrical properties of (In, Nb) co-doped TiO2 was investigated. The FE-SEM images showed that the air quenching has no effect on microstructure of co-doped TiO2. However, air quenching affected the electrical properties so that the dielectric constant in the frequency of 1 kHz at room temperature sharply enhanced from 21*103 to 26*104 and the dielectric loss surprisingly decreased from 0.6 to 0.1. This incredible improvement in the dielectric properties is attributed to the electron-pined defect dipoles which has been activated through air quenching. © 2020 Elsevier B.V  

In this research, the microstructure, dielectric, and non-Ohmic properties of (Cr, Nb) co-doped SnO2 ceramics, (Cr0.5, Nb0.5)xSn1-xO2 with x% = 0, 0.5, 1.0, 2.0, 5.0, and 10.0, as a colossal dielectric material and a prospective alternative to co-doped TiO2 ceramics were studied. The X-ray diffraction results indicated that in all compositions, the cassiterite phase was achieved without any secondary phases. Moreover, field-emission secondary electron microscopy showed that the microstructure of samples has different morphologies including typical grains, enlarged grains and prism-like grains microstructure for various sintered samples. The maximum dielectric constant (2737) accompanied by... 

Although hematite (i.e., α-Fe2O3) has been widely investigated in photoelectrochemical water oxidation studies due to its high theoretical photocurrent density, it still suffers from serious surface charge recombination and low photoelectrochemical stability. Here we report an in situ electrochemical method to form a uniform and ultrathin (i.e., 3-5 nm) passivation layer all over the pores of an optimized ∼3.2% Ti-doped α-Fe2O3 photoanode. We unveil the amorphous and defective nature of the in situ derived layer assigned to a high concentration of oxygen vacancies and intercalated potassium atoms there, i.e., the formation of Ti/K co-doped defective α-Fe2O3−x. Owing to the efficient... 

In this research, an attempt was made to improve TiO2 photo-catalyst properties, thus pure, N-Ce co-doped TiO2 thin films were prepared on glass-ceramic substrate using a sol-gel dip-coating technique. The samples were calcinated in air at 475 °C, 550°C, and 650°C for 2 h. The result of simultaneous thermal analysis (STA) and X-ray diffraction (XRD) showed that the presence of Ce in TiO2 could inhibit the phase transformation from anatase to rutile and enhance the thermal stability, and anatase was the dominant phase in N-Ce co-doped TiO2 samples. Also based on the results, the doping results in decreasing the size of TiO 2 crystallite. The results of ultra violet-visible light diffuse... 

To enhance hydrophilicity and photocatalytic activity, N-doped and N-V-codoped TiO2 films were coated on glass substrates by the sol-gel dip-coating method. The substrates were previously coated with SiO2 using the same method. The coated samples, after annealing at 450 °C for 30 min in air, were analyzed by an X-ray diffractometer, scanning electron microscope, Fourier transform infrared spectroscope, X-ray photoelectron spectroscope, and UV-visible spectroscope. The SiO2/N-V-codoped TiO2 photocatalyst showed a narrower band gap (2.93 eV) compared to the SiO2/N-doped. Degradation tests, methyl orange under UV light and stearic acid... 

The equilibrium crystal structure and electronic structure of BaFe2-x Cox As2 (x = 0,1, 2) superconductor have been investigated by using the pseudopotential Quantum Espresso code based on the ab initio density functional theory in the generalized gradient approximation. The equilibrium crystal structure for x = 1.0 has been determined by considering five different Fe/Co configurations. This study shows that the spin calculation is essential to obtain the experimental values at x = 0.0. The total and partial density of states, band structure, and Fermi surfaces of the three compounds has been calculated. Density of states calculation indicates the important... 

In this study, crumpled-shape nanocomposite of nitrogen and sulfur co-doped ZnO–CeO2 (NSZC) was deposited on FTO substrate using one-step ultrasonic spray pyrolysis. Zinc acetate, cerium nitrate, and thiourea were dissolved in deionized water and used as starting solution. The samples were characterized using FESEM, XRD, UV–vis spectroscopy, EIS, and PL. The as-prepared nitrogen and sulfur co-doped ZnO–CeO2 nanocomposites were evaluated as high photocatalysts for degradation of methyl orange. Nearly 100% photocatalytic degradation of methyl orange was achieved for 180 min. The photoluminescence and electrochemical impedance spectroscopy revealed that co-doping of nitrogen and sulfur could... 

To overcome the drawback of poor solar light utilization brought about by the narrow photoresponse range of TiO2, a silver and sulfur co-doped TiO2 was synthesized. Using the prepared catalyst, solar photocatalytic degradation of 2-nitrophenol (2-NP) by a TiO2-based catalyst was studied for the first time. Effects of the co-doping on the structural, optical and morphological properties of the synthesized nanoparticles were investigated by different characterization methods: X-ray diffraction, N2 adsorption-desorption measurements, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, UV-visible diffuse reflectance spectroscopy and Fourier...